Polyester resin for aluminum coil ceiling board and preparation method thereof

A polyester resin and ceiling technology, which is applied in the field of polymer materials, can solve the problems of difficulty in promotion and high cost, and achieve the effects of improving machinability, flexibility and processability.

Inactive Publication Date: 2019-01-25
江苏三木化工股份有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the resin formula, about 32 to 40% of the formula amount is used for m-benzene, and 27 to 35% of the form

Method used

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  • Polyester resin for aluminum coil ceiling board and preparation method thereof
  • Polyester resin for aluminum coil ceiling board and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0028] Example 1

[0029] 1. A saturated polyester resin for aluminum ceiling paint, which is made of the following weight percentages of raw materials: 5% neopentyl glycol, 20% methyl propylene glycol, 15% adipic acid, 5% intermediate Phthalic acid, 25% dimethyl terephthalate, 0.05% n-butyl titanate, 3% xylene, 30% S150, 7% butyl acetate.

[0030] 2. The preparation method of saturated polyester resin for aluminum coil finish includes the following steps:

[0031] (1) Put 5% neopentyl glycol, 20% methyl propylene glycol, 25% dimethyl terephthalate, and 0.05% n-butyl titanate into the reactor according to weight percentages, stir to make the materials evenly mixed;

[0032] (2) Then pass in nitrogen, remove the oxygen in the reactor, and start heating; increase the temperature to 240℃, keep it for 0.5 hours, (during the heating process, the temperature of the distillation is controlled not higher than 68℃), then cool to 160℃ and wait use.

[0033] (3) Then add 15% adipic acid and 5% i...

Example Embodiment

[0040] Example 2

[0041] 1. A saturated polyester resin for aluminum ceiling paint, which is made of the following raw materials in weight percentage:

[0042] Dimethyl terephthalate 30%, methyl propylene glycol 25%, neopentyl glycol 10%, adipic acid 20%, isophthalic acid 10%, n-butyl titanate 0.05%, xylene 3%, S150 Aromatics 35%, butyl acetate 10%.

[0043] 2. The preparation method of saturated polyester resin for aluminum coil finish includes the following steps:

[0044] (1) Put 10% neopentyl glycol, 25% methyl propylene glycol, 30% dimethyl terephthalate, and 0.05% n-butyl titanate into the reactor according to weight percentage, stir to make the materials evenly mixed;

[0045] (2) Then pass in nitrogen, remove the oxygen in the reactor, and start heating; increase the temperature to 240℃, keep it for 0.5 hours, (during the heating process, the temperature of the distillation is controlled not higher than 68℃), then cool to 160℃ and wait use.

[0046] (3) Then add 20% adipic aci...

Example Embodiment

[0058] Example 4 Performance test

[0059]

[0060]

[0061] The above performance test results show that the present invention, through a large number of experimental screenings, adopts preferred raw materials to prepare saturated polyester resin for aluminum ceiling paint. Its hardness and processability are equivalent to those of the prior art polyester resin, but its weather resistance is better than There are now technical saturated polyesters that are superior. And the cost is lower than the existing technology, the environmental protection is better, and very good technical effects have been achieved.

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PUM

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Abstract

The invention discloses polyester resin for an aluminum coil ceiling board and a preparation method thereof. The polyester resin is prepared from dimethyl terephthalate, methylpropanediol, neopentyl glycol, hexanedioic acid, isophthalic acid, tetrabutyl titanate, triphenyl phosphite, xylene, S150 arene and n-butyl acetate. The polyester resin for the aluminum coil ceiling board prepared by a novelingredient system provided by the invention passes the performance detection; the hardness and the weather resistance performance of the polyester resin prepared by the method are identical to thoseof polyester resin in the prior art; the processing performance is better than that of the polyester in the prior art; the cost is lower than that in the prior art; the popularization and the use areeasy; good technical effects are obtained.

Description

technical field [0001] The invention relates to a resin, in particular to a polyester resin for rolled aluminum ceilings with strong environmental protection, low cost, superior performance and easy popularization and application, and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] The topcoat for coiled aluminum ceilings is usually a baking varnish system combined with highly flexible saturated polyester resin and methylated amino resin, which requires the paint film to have good hardness, flexibility and processability. Generally, saturated polyester is used for ceiling paints by using isobenzene, adipic acid, diols without β hydrogen atoms, etc. It has been proved that this polyester topcoat formula has good retort resistance, hardness, and processability. It is a classic saturated polyester resin for coil aluminum topcoat. However, in the resin formula, about 32 to 40% of the formula is used for m-benzen...

Claims

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Application Information

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IPC IPC(8): C08G63/78C08G63/183C08G63/181C08G63/85
CPCC08G63/181C08G63/183C08G63/78C08G63/85
Inventor 蒋文杰
Owner 江苏三木化工股份有限公司
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