Foaming agent comprising polyamine and alcohol amine salt and use in polyurethane continuous sheet foam material

A technology of foaming agent and alcohol amine salt, which is applied in the field of polyurethane foaming agent, which can solve the problems of uneven cell size, uneven cell distribution, affecting the strength performance and thermal insulation properties of foaming materials, etc.

Active Publication Date: 2019-03-05
BUTIAN NEW MATERIAL TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In short, the foaming agent in the prior art cannot be dispersed into the foaming composition at the molecular level, resulting in uneven distribution of cells and uneven cell size, which ultimately affects the strength performance and thermal insulation of the foamed material nature

Method used

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  • Foaming agent comprising polyamine and alcohol amine salt and use in polyurethane continuous sheet foam material

Examples

Experimental program
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Effect test

preparation example 1

[0070] Add 3kg of 40% ethylenediamine aqueous solution (molecular weight 60) into a transparent quartz glass reactor, stir to dissolve, seal the reactor, then, under constant stirring, control the temperature between 40-65°C, and pass carbon dioxide into In the reactor, control the pressure not to be higher than 0.3MPa, control the temperature and react for 10 hours, release the pressure and release the product after the temperature is lowered to below 40°C. Compound 1 was obtained. pH≥7.5, decomposition temperature is 42°C-70°C.

preparation example 2

[0072] The 50% diethylenetriamine aqueous solution (molecular weight 103) of 3kg is joined in the transparent quartz glass reactor, stirs to dissolve, seals the reactor, then under constant stirring, controls the temperature between 40-65 ℃, will Pass carbon dioxide into the reactor, control the pressure not to be higher than 0.3 MPa, and control the temperature for 10 hours to react. After cooling down to below 40°C, release the pressure and release the product. Compound 2 was obtained. pH≥7.5, decomposition temperature is 42°C-70°C.

preparation example 3

[0074] Add 3kg of triethylenetetramine (molecular weight 146) and 1.8kg of water into a transparent quartz glass reactor, stir to dissolve, seal the reactor, and then control the temperature between 40-65°C under constant stirring, Pass carbon dioxide into the reactor, control the pressure not higher than 0.3MPa, control the temperature and react for 10 hours, release the pressure and release the product after cooling down to below 40°C. Compound 3 was obtained. pH≥7.5, decomposition temperature is 42°C-70°C.

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Abstract

The invention discloses a foaming agent comprising a polyamine and an alcohol amine salt and use in a polyurethane continuous sheet foam material. The foaming agent is a polyurethane foaming agent comprising a polyamine salt and an alcohol amine salt. The foaming agent comprises: 1) a first compound mixture (M1) comprising organopolyamine salt compounds of a following general formula (I): A<->B<+>(I), wherein B<+> is a cation of an organic polyamine B, and A<-> is CO<3><2->, HCO<3><->, or a combination of CO<3><2-> and HCO<3><->; and 2) a second compound mixture (M2) containing N-monohydroxypropyl / monohydroxyethyl-ammonium carbonate compounds having a general formula (II) and N,N'-di(hydroxypropyl / hydroxyethyl)-ammonium carbonate compounds having a general formula (III): (RN<+>H<3>)(N<+>H<4>)CO<3><2-> (II), or (RN<+>H<3>)<2>CO<3><2->(III), wherein R is a combination of hydroxypropyl and hydroxyethyl, and the molar ratio of the monoolamine compound of the formula (II) to the diolaminecompound of the formula (III) is 1:0 to 1:2.5. The foaming agent is suitable for use in preparation of the polyurethane continuous sheet foam material.

Description

technical field [0001] The present invention relates to an organic polyamine salt compound having an anion as a CO2 donor, a process for its preparation and its use as a blowing agent, more specifically, providing an organic polyamine having not only an anion as a CO2 donor but also an organic polyamine as a catalytic group Novel organic ammonium salt compound with solubilizing group, its preparation method and its application in the preparation of polyurethane continuous board foam material. The present invention relates to polyurethane blowing agents comprising polyamine salts and alcoholamine salts and their use for (preparing) polyurethane continuous board foam materials. technical background [0002] As a new polymer material, polyurethane rigid foam is light in weight, high in strength and has extremely low thermal conductivity. Automobiles, refrigerators and freezers and other household appliances and other industries. The most important raw material in the producti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/08C08J9/14C08G18/66C08G18/48C08G18/42C08G18/32C08G18/18C07C209/00C07C211/10C07C211/14C07C213/00C07C215/08C08G101/00
CPCC07C209/00C07C213/00C08G18/1808C08G18/4018C08G18/6622C08J9/08C08J9/144C08J2203/02C08J2203/142C08J2203/204C08J2375/04C08J2375/06C08J2375/08C08G2110/005C07C211/10C07C211/14C07C215/08
Inventor 毕戈华毕玉遂
Owner BUTIAN NEW MATERIAL TECH CO LTD
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