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A 3D cold printing self-propagating method for preparing tic-based steel-bonded cemented carbide

A steel-bonded hard alloy, self-propagating technology, applied in metal processing equipment, transportation and packaging, additive processing, etc., can solve the problem that powder and hard phase particles are difficult to mix evenly, and the bonding strength between reinforcing particles and steel matrix is ​​not high , Steel-bonded carbide can not be formed in one piece, etc., to achieve the effect of reducing processing costs, low processing costs, and short time consumption

Active Publication Date: 2020-11-20
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the powder metallurgy method is a commonly used method for the production of steel-bonded cemented carbide, but this method has limitations, such as the difficulty of mixing the steel matrix powder and the hard phase particles evenly, the uneven distribution of the hard phase, and the interface between the reinforcing particles and the steel matrix. The bonding strength is not high, and the product has structural defects such as pores, segregation, looseness, and bridging
In addition, the steel-bonded cemented carbide produced by powder metallurgy cannot be integrally formed, and the efficiency is low and the cycle is long

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment example 1

[0025] (1) Configure the premix solution: mix the organic monomer hydroxyethyl methylendenoate (HEMA) and the solvent toluene in a certain proportion, and the concentration of the organic monomer hydroxyethyl methylendenoate (HEMA) is 40% , and add 2.5vol.% polytetrafluoroethylene (PTFE) to configure a premix;

[0026] (2) Preparation of metal slurry: take by weight 28wt.% of Ti powder, 5wt.% of graphite powder, and the balance is CrMo low-alloy steel powder, and add it to the premixed solution in step (1) to prepare metal material Slurry, solid content is 60vol.%, then add the oleic acid of powder mass 0.1wt% to improve slurry fluidity;

[0027] (3) Data modeling: Use 3D modeling software to design part models of the required structural shape, especially large-scale part models with closed cavities and complex inner cavities. The part models are sliced ​​in layers, and the thickness of the layers is 0.05mm, get the 3D model data of the part;

[0028] (4) 3D printing: import...

Embodiment example 2

[0032] (1) Configure the premix solution: mix the organic monomer hydroxyethyl methylendenoate (HEMA) and the solvent toluene in a certain proportion, and the concentration of the organic monomer hydroxyethyl methylendenoate (HEMA) is 30% , and add 3vol.% polytetrafluoroethylene (PTFE) to configure a premix;

[0033] (2) Preparation of metal slurry: take by weight 36wt.% of Ti powder, 8wt.% of graphite powder, and the balance is high manganese steel powder, and add it to the premixed solution in step (1) to prepare metal slurry , solid content is 55vol.%, then add the oleic acid of powder quality 0.15wt% to improve slurry fluidity;

[0034] (3) Data modeling: Use 3D modeling software to design part models of the required structural shape, especially large-scale part models with closed cavities and complex inner cavities. The part models are sliced ​​in layers, and the thickness of the layers is 0.05mm, get the 3D model data of the part;

[0035] (4) 3D printing: import the 3...

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Abstract

A method for preparing TiC-based steel-bonded hard alloy by self-propagating 3D cold printing belongs to the technical field of composite material preparation. The invention adopts 3D cold printing technology to print out the metal body layer by layer, utilizes the SHS powder system existing in the green body to undergo self-propagation reaction at high temperature in the sintering process, and synthesizes fine dispersed hard phase TiC in situ to prepare TiC Base steel bonded carbide. 3D cold printing technology can be integrated to form TiC-based steel-bonded carbide with any complex spatial structure, greatly reducing processing costs, high production efficiency and short production cycle, and the hard phase TiC generated by SHS in situ, the particles are dispersed Small, good wettability with the substrate; in addition, polytetrafluoroethylene (PTFE) activates sintering during the sintering self-spreading process, effectively reducing the sintering temperature, and the highly active C produced by its thermal decomposition acts as a C source. . The invention has strong operability, short time consumption, high efficiency, low processing cost and high product precision.

Description

technical field [0001] The invention belongs to the technical field of composite material preparation, and relates to a method for preparing TiC-based steel-bonded hard alloy by 3D cold printing self-propagation. Background technique [0002] Steel-bonded cemented carbide is a composite material with steel as the binder phase and insoluble metal carbides (mainly WC, TiC, etc.) as the hard phase. The mechanical properties of the alloy are between cemented carbide and steel. Compared with steel, it has higher hardness, better wear resistance, higher elastic modulus and compressive strength; compared with cemented carbide, It has good bending strength and impact toughness, showing excellent comprehensive performance. In addition, steel-bonded carbide has a wide range of process characteristics, such as machinability, heat treatability and forgeability. Steel-bonded cemented carbide has a wide range of uses, mainly in the fields of molds and cutting tools, and also plays an im...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C33/02C22C38/28C22C38/22C22C38/04C22C38/14B22F3/23B22F1/00B33Y10/00B33Y70/10
CPCC22C33/0278C22C38/04C22C38/14C22C38/22C22C38/28B22F3/23B33Y10/00B33Y70/00B22F1/107
Inventor 杨芳秦乾郭志猛隋延力张策芦博昕邵艳茹李沛陆天行
Owner UNIV OF SCI & TECH BEIJING