Metal element-doped molybdenum disulfide film material and preparation method thereof
A metal element, molybdenum disulfide technology, applied in the fields of molybdenum sulfide, chemical instruments and methods, oxidized water/sewage treatment, etc., can solve the problems of high process requirements, long time-consuming and complicated molybdenum disulfide nanosheets, and achieve process time The effect of shortening, low cost and simple process
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0036] As an example, the preparation method of the doped molybdenum disulfide film is further described, including: cleaning the titanium or titanium alloy and placing it in the reactor, using (a) sulfur source, (b) molybdenum source, (c) The mixed aqueous solution or hydrosol of metal element or corresponding metal soluble salt is used as hydrothermal medium to carry out hydrothermal treatment on titanium or titanium alloy. Wherein the reaction temperature is 180-220° C., the reaction time is 4-8 hours, and it is best to keep the filling degree of the reactor at 50-75% during the whole process.
[0037] In the present invention, the metal element-doped molybdenum disulfide thin film grows in situ on the surface of the metal substrate (titanium or titanium alloy) through a hydrothermal reaction, wherein the metal element is evenly doped in the layered molybdenum disulfide nanosheets . The synthesis method (one-step hydrothermal process) of the present invention has the advanta...
Embodiment 1
[0040] Treat a pure titanium sheet with a thickness of 1mm and a length and width of 10mm with 10% oxalic acid solution at 80°C for 2 hours, then rinse it with a large amount of deionized water, and then use alcohol and deionized water to clean it ultrasonically. 15min. Then carry out hydrothermal treatment, add 0.6g CS(NH 2 ) 2 , 0.3g (NH 4 ) 6 Mo 7 o 24 ·6H 2 O, after ultrasonic dissolution, transferred to a 100mL PPL hydrothermal reaction kettle, and then placed an aluminum foil (0.035g) with a length of 100mm and a width of 10mm on the inner wall of the reaction kettle, and the hydrothermal temperature was 200°C for 5h. Rinse with plenty of deionized water and sonicate after hydrothermal treatment.
[0041] figure 1 (o-Ti-MoS 2 -Al) is the low magnification ( figure 1 middle b) and high power ( figure 1 Middle a) Scanning electron microscope picture, as can be seen from the figure, the surface after treatment presents a sheet-like nanostructure, the length of th...
Embodiment 2
[0043] A pure titanium sheet with a thickness of 1 mm and a length and width of 10 mm was ultrasonically cleaned with alcohol and deionized water in sequence, each time for 15 minutes. Then carry out hydrothermal treatment, add 0.6g CS(NH 2 ) 2 , 0.28g (NH 4 ) 6 Mo 7 o 24 ·6H 2 O, after ultrasonic dissolution, transferred to a 100mL PPL hydrothermal reaction kettle, and then placed an aluminum foil (0.035g) with a length of 100mm and a width of 10mm on the inner wall of the reaction kettle, and the hydrothermal temperature was 200°C for 4h. Rinse with plenty of deionized water and sonicate after hydrothermal treatment. The molar ratio of aluminum and molybdenum disulfide is 0.23:1.
[0044] Figure 4 (Ti-MoS 2 -Al 2 ) is a low magnification ( Figure 4 middle b) and high power ( Figure 4 Middle a) Scanning electron microscope picture, as can be seen from the figure, the surface after treatment presents a sheet-like nanostructure, the length of the nanosheets is ab...
PUM
| Property | Measurement | Unit |
|---|---|---|
| Thickness | aaaaa | aaaaa |
| Length | aaaaa | aaaaa |
| Thickness | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More