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A kind of high-strength electronic protective clothing TPU film material and preparation method thereof

A film material and electronic technology, applied in the field of polymer material synthesis, can solve the problems of low temperature resistance, elongation, hydrolysis resistance, unsatisfactory heat resistance, product side reactions, many crystal points, moisture permeability, poor air permeability, etc. , to achieve good antistatic performance, improve antistatic performance, and strengthen the effect of mixing effect

Active Publication Date: 2021-04-16
SHANDONG INOV POLYURETHANE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Antistatic protective clothing is a special protective clothing with dust-free and antistatic properties suitable for electronics, optical instruments, pharmaceuticals, microbial engineering, precision instruments, oil fields, petrochemicals, electric power, coal and other industries. Or synthetic fiber fabrics blended with conductive fibers, but the current antistatic chemical protective clothing of fiber fabrics has poor moisture permeability, air permeability, and insufficient comfort, while TPU film has excellent waterproof, air permeability, flexibility and aging resistance. It is gradually applied in the field of antistatic protective clothing, but at present, the domestic TPU film products are mainly low-end and low-end. Low temperature, elongation, hydrolysis resistance, and heat resistance are not ideal

Method used

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  • A kind of high-strength electronic protective clothing TPU film material and preparation method thereof
  • A kind of high-strength electronic protective clothing TPU film material and preparation method thereof
  • A kind of high-strength electronic protective clothing TPU film material and preparation method thereof

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preparation example Construction

[0036] The preparation method of the modified graphene that adopts in the embodiment is as follows:

[0037] Graphene oxide, silane coupling agent (KH-570), absolute ethanol and deionized water were mixed and ultrasonically dispersed, then heated for silanization reaction, and N 2 , and finally washed with absolute ethanol and suction filtered to obtain silanized graphene oxide.

Embodiment 1

[0039] A high-strength electronic protective clothing TPU film material is made of the following raw materials in weight percentage:

[0040]

[0041] Described polyester polyol is polybutylene adipate, and polyester polyol number-average molecular weight is 2000; Polyether type polyol is PTMEG, and number-average molecular weight is 1000, and reaction hard segment 50%, r value (NCO / OH molar ratio) 0.98, synthesized by proportioning A and proportioning B respectively.

[0042] Preparation Process:

[0043] 1. Mix polyester and polyether polyol, control the material temperature at 110°C, pull vacuum to remove moisture, control the moisture below 0.03%, then add light stabilizer, antioxidant, mold release agent, and modified graphene in sequence , Resistant to hydrolysis agent, the material kettle is stirred and circulated;

[0044] 2. Quantitative premixing of polyester polyol, polyether polyol and 1,4-butanediol at 120°C by means of a metering pump, heating the diisocyan...

Embodiment 2

[0047] A high-strength electronic protective clothing TPU film material is made of the following raw materials in weight percentage:

[0048]

[0049]

[0050]Described polyester polyol is polybutylene adipate, and polyester polyol number-average molecular weight is 2000; Polyether type polyol is PTMEG, and number-average molecular weight is 1000, and reaction hard segment 50%, r value (NCO / OH molar ratio) 0.98, synthesized by proportioning A and proportioning B respectively.

[0051] Preparation Process:

[0052] 1. Mix polyester and polyether polyol, control the material temperature at 110°C, pull vacuum to remove moisture, control the moisture below 0.03%, then add light stabilizer, antioxidant, mold release agent, and modified graphene in sequence , Resistant to hydrolysis agent, the material kettle is stirred and circulated;

[0053] 2. Quantitative premixing of polyester polyol, polyether polyol and 1,4-butanediol at 120°C is achieved through a metering pump, an...

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Abstract

The invention belongs to the technical field of polymer material synthesis, and in particular relates to a TPU film material for high-strength electronic protective clothing and a preparation method thereof. The material is made of the following raw materials in percentage by weight: polyester polyol 40%-60%; polyether polyol 5%-25%; diisocyanate 20%-45%; chain extender 5%-15% ; Release agent 0.1%-0.5%; Hydrolysis resistance agent 0.1%-0.8%; Antioxidant 0.1%-0.5%; Light stabilizer 0.1%-0.9%; Modified graphene 0.1%-0.5%; %‑0.05%. The high-strength electronic protective clothing TPU film material prepared by the present invention has stable quality, few crystal points, environmental protection, hydrolysis resistance, good heat resistance, good low temperature performance and excellent resilience, and extremely stable performance in the production process. Good; its preparation method has simple process and high production efficiency.

Description

technical field [0001] The invention belongs to the technical field of polymer material synthesis, and in particular relates to a TPU film material for high-strength electronic protective clothing and a preparation method thereof. Background technique [0002] Antistatic protective clothing is a special protective clothing with dust-free and antistatic properties suitable for electronics, optical instruments, pharmaceuticals, microbial engineering, precision instruments, oil fields, petrochemicals, electric power, coal and other industries. Or synthetic fiber fabrics blended with conductive fibers, but the current antistatic chemical protective clothing of fiber fabrics has poor moisture permeability, air permeability, and insufficient comfort, while TPU film has excellent waterproof, air permeability, flexibility and aging resistance. It is gradually applied in the field of antistatic protective clothing, but at present, domestic TPU film products are mainly low-end and low...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/66C08G18/42C08G18/48C08G18/32C08G18/22C08G18/76C08J5/18C08K9/06C08K9/04C08K3/04
CPCC08G18/227C08G18/3206C08G18/4018C08G18/4238C08G18/4854C08G18/6607C08G18/7671C08J5/18C08J2375/06C08J2375/08C08K9/04C08K9/06C08K2201/017C08K3/042
Inventor 徐军李龙飞陈海良肖培栋刘扬
Owner SHANDONG INOV POLYURETHANE
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