Conductive coating before electrostatic spraying of thermosensitive base material and preparation method and device for conductive coating

A conductive coating and electrostatic spraying technology, applied in conductive coatings, devices for coating liquid on surfaces, coatings, etc., can solve problems such as poor adhesion between conductive substances and substrates, pinholes, complex processes, etc. Drying and baking process, preventing uneven spraying, improving the effect of coating quality

Pending Publication Date: 2019-03-26
南通南京大学材料工程技术研究院
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (1) Preheating treatment: bake the board at a temperature range of 70°C-80°C for 15min-20min, so that the internal moisture and other solvents evaporate to the surface, in order to reduce the surface resistance and control the evaporation of water, but the above method is practical The process is difficult to control, and pinholes, bubbling and difficulty in powdering will still occur locally, which cannot meet the actual production needs;
[0005] (2) Brushing conductive liquid: spray or paint the solid conductive polymer dispersed in water or organic solvents to the wood surface, dry naturally or bake at 70°C-80°C to remove water and organic solvents, the above method can Reduce the surface resistance to 10 4 Ω and evenly distributed, but the adhesion between the conductive substance and the substrate is poor, and the subsequent film layer is easy to fall off. If the introduced water and organic solvent are not completely removed, pinholes and bubbling will also appear; in addition, the conductive substance is chemically active , may react with subsequent powder coating components and affect the coating film

Method used

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  • Conductive coating before electrostatic spraying of thermosensitive base material and preparation method and device for conductive coating
  • Conductive coating before electrostatic spraying of thermosensitive base material and preparation method and device for conductive coating
  • Conductive coating before electrostatic spraying of thermosensitive base material and preparation method and device for conductive coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Such as figure 1 As shown, the pressure spin coater of the present invention includes a feeding device 1 with a feed port and a discharge port, a spin coating grinding head 4 communicated with the feeding port of the feeding device 1 through a pipeline, and a grinding head 4 connected with the spin coating grinding head 4. Grinding head speed controller 9; the discharge port of feeding device 1 is provided with feed rate regulator 2 and flow rate regulator; spin coating grinding head 4 is provided with grinding head height regulator 3 and pressure sensor 8, through the grinding head height adjustment The device 3 and the pressure sensor 8 adjust the pressure of the spin-coating grinding head 4 on the substrate being spin-coated.

[0057] The feeding device 1 is used to hold the solid conductive particles to be used, and a container with a certain volume, preferably an inverted cone container, is more conducive to the outflow of solid conductive particles to ensure the f...

Embodiment 2

[0068] The preparation of embodiment 2 conductive coating

[0069] A solid wood board substrate with a flat appearance was cleaned, blown with a high-pressure air gun, and then baked in an oven at 100°C for 30 minutes to remove moisture from it to obtain a pretreated solid wood board substrate. Graphite is selected as the conductive material, and it is refined by a high-energy ball mill. The ball milling speed is 450rpm, the ball-to-material ratio is 80:1, and the ball-milling time is 8h. The refined graphite particles are obtained. The size of the refined graphite particles is 2μm-3μm. Add the above-mentioned refined graphite particles into the pressure spin coater in Example 1, place the pretreated solid wood substrate horizontally under the spin coater 4, control the feeding rate to be 30g / min, and the air flow rate to be 30L / min. min, spin coating pressure is 3kgf / cm 2 , Spin-coat graphite particles with a particle size of 2 μm-3 μm on the surface of the pretreated solid...

Embodiment 3

[0070] The preparation of embodiment 3 conductive coatings

[0071] A rough-looking solid wood board substrate was smoothed with sandpaper, blown with a high-pressure air gun, and then baked in an oven at 120°C for 15 minutes to remove moisture to obtain a pretreated solid wood board substrate. Commercially available carbon black was selected as the conductive material, and it was refined by using a high-energy ball mill. The ball milling speed was 450rpm, the ball-to-material ratio was 80:1, and the ball-milling time was 8h to obtain refined carbon black particles. The size of the black particles is 0.05 μm-1 μm. Add the above-mentioned refined carbon black particles into the pressure spin coater in Example 1, place the pretreated solid wood substrate horizontally under the spin coater grinding head 4, control the feeding rate to 25g / min, and the air flow to 35L / min, spin coating pressure is 3kgf / cm 2 , Spin-coat carbon black particles with a particle size of 0.05 μm-1 μm ...

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Abstract

The invention discloses a conductive coating before electrostatic spraying of a thermosensitive base material and a preparation method and device for the conductive coating. The conductive coating isformed in the mode that the surface of the thermosensitive base material is composed of solid conductive particles with the particle size being micro-nanometer grade, and the thickness of the conductive coating is 5-25 [mu]m. The conductive coating enables the non-conductive or poor-conductivity thermosensitive base material to obtain even sheet resistance, and the adverse effect on subsequent electrostatic spraying is avoided. The conductive coating can be prepared through a pressure spin coating method and/or a pressure spin coater, simpleness and the easy-to-do effects are achieved, the efficiency is high, the using amount of a conductive material is less, the obtained conductive coating is even, the sheet resistance is 10<4> omega to 10<6> omega, the conductive coating is suitable forelectrostatic spraying, scattered conductive particles can be recycled, the cost is low, a solvent is not adopted, and environmental protection is achieved.

Description

technical field [0001] The invention relates to the field of powder coatings and coatings, in particular to a conductive coating before electrostatic spraying of a heat-sensitive substrate and its preparation and device. Background technique [0002] Under the background of vigorously advocating energy conservation and environmental protection in the country, powder coatings have become a rapidly developing popular coating material due to their advantages such as low volatile organic compound (VOC) emissions, high film quality, and convenient recycling. For a long time, traditional powder coatings have been aimed at metal substrates, which are easy to conduct electricity. Through electrostatic attraction with oppositely charged powder particles, adsorption accumulation, and high-temperature melting-curing (180°C-200°C) film formation. With the rapid development of powder coatings, the curing of powder coatings presents a trend of low-temperature and rapid response. Researche...

Claims

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Application Information

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IPC IPC(8): C09D1/00C09D5/24B05D5/12B05C19/04B05C19/06
CPCC09D1/00C09D5/24B05C19/04B05C19/06B05D5/12
Inventor 顾坚任华杨花安
Owner 南通南京大学材料工程技术研究院
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