A method for preparing a novel W doped slag based binding material with different CeO2 loads

A technology of steel slag-based rubber and loading capacity, which is applied in chemical instruments and methods, hydrogen production, inorganic chemistry, etc., and can solve the problems of high cost of photocatalyst preparation, low quantum yield, and dispersion of photocatalyst powder.

Inactive Publication Date: 2019-04-02
XIAN UNIV OF SCI & TECH
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Problems solved by technology

Although this kind of catalytic oxidation technology using semiconductors as catalysts has many advantages over other oxidation technologies, there are still several key technical problems in this kind of research, which greatly restricts its industrial application.
These problems include: low quantum yield (about 4%); low utilization rate of solar energy; loading technology of photocatalyst; dispersion

Method used

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  • A method for preparing a novel W doped slag based binding material with different CeO2 loads
  • A method for preparing a novel W doped slag based binding material with different CeO2 loads
  • A method for preparing a novel W doped slag based binding material with different CeO2 loads

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Embodiment

[0032] W-doped CeO 2 Preparation of Supported Alkali Excited Steel Slag-Based Catalyst

[0033] 1. Preparation of alkali-activated steel slag-based cementitious materials

[0034] The steel slag from Hanchenglong Steel was used in this embodiment, which was ground by a ball mill and sieved by a 0.08mm square hole sieve. Density measured by Lee bottle is 3.03g / cm 3 , the specific surface area is 490m by Blaine's specific area meter 2 / kg. The chemical composition of steel slag raw materials is shown in Table 1.

[0035] Table 1 Chemical composition of steel slag raw materials

[0036]

[0037]Dry the silica fume for later use, dry mix the silica fume and steel slag evenly, dissolve 60g NaOH with 100ml water, let the alkali solution stand to cool and add the aqueous solution dispersed with acrylic resin to the SJ-160 plastic sand mixer. Weigh 1500g of the mixture (steel slag and silica fume in a mass ratio of 9:1) and pour it into the mixture for stirring. Stir slowly f...

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Abstract

A method for preparing a novel W doped slag based binding material with different CeO2 loads is disclosed. Slag, as a raw material, sodium hydroxide as an activator and silica fume as a toughening agent are utilized to prepare an alkali activated slag based binding material; the prepared binding material as a carrier is utilized to synthesize a W-doped alkali activated slag based binding materialcatalyst loaded with CeO2 through an incipient wetness impregnation process, with the mechanical performance being adopted as an evaluation index. On the one hand, a novel route of high-added-value utilization of industrial solid waste is provided, and on the other hand, the prepared catalyst can be used for photocatalytic oxidation degradation of dye wastewater, and can also be used for photocatalytic reduction and decomposition of water to prepare hydrogen, thus providing a novel idea for basic research of application of solid waste based binding materials of this type. The method is of great significance for sustained development of the steel industry, wastewater treatment in the dyeing and printing industry and the field of new energy and will generate important resource, economic, environment and social benefits.

Description

technical field [0001] The invention relates to the field of high value-added utilization of solid waste resources and the preparation of new catalysts, in particular to a W-doped CeO 2 Preparation methods of new steel slag-based cementitious materials with different loads. Background technique [0002] Steel slag is the main solid waste produced by the iron and steel industry, and the output rate is about 15-20% of the crude steel output. With the rapid development of the national economy, the discharge of steel slag has also increased sharply. According to statistics, in 2016, the discharge of steel slag in my country was about 121 million tons. These steel slags have been piled up as waste for a long time, which not only occupies a large amount of land resources, but also causes serious pollution to the ecological environment. Therefore, it is imminent to improve the resource utilization of this kind of solid waste, and explore new ways of large-scale application of stee...

Claims

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Application Information

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IPC IPC(8): B01J23/30B01J23/889C02F1/30C01B3/04
CPCB01J23/002B01J23/30B01J23/8892B01J35/004C01B3/042C01B2203/0277C01B2203/1082C02F1/30C02F2101/308C02F2305/10Y02E60/36
Inventor 康乐杜慧玲张耀君杜娴张森王明亮刘跃
Owner XIAN UNIV OF SCI & TECH
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