Coating method for coating composite ceramic coating layers on surfaces of refractory metal parts

A composite ceramic and refractory metal technology, applied in the field of coating, can solve the problems of inability to achieve uniform coating of refractory metal substrates, difficult preparation of surface coatings of refractory metal parts, and inability to ensure the quality and reliability of coatings, etc. Achieve the effect of not easy to peel and crack, improve uniform coating, and improve adhesion

Active Publication Date: 2019-04-02
长沙微纳坤宸新材料有限公司
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The adhesion of ceramic coatings to refractory metals is poor, and it is difficult for directly coated ceramic coatings to adhere to the surface of refractory metals, resulting in peeling and cracking of ceramic coatings during coating and sintering, especially in large areas 1. When preparing ceramic coatings on the surface of refractory metal parts with complex shapes, due to the mismatch between the particle size of the ceramic coating powder, the solid content concentration of the slurry, the viscosity of the slurry and the adhesion of the refractory metal substrate coated with a large area, the material The slurry cannot achieve uniform coating on large-sized refractory metal substrates, and at the same time, the coated coating is prone to peeling and cracking during post-sintering, thus making the surface coating of large-sized, multi-dimensional, and complex-shaped refractory metal parts The layer is difficult to prepare, and the quality and reliability of the coating cannot be guaranteed

Method used

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Embodiment 1

[0025] A method for coating the surface of a refractory metal cylindrical part with an outer diameter of 400mm, a height of 500mm, and a wall thickness of 10mm with an anti-ablation coating, comprising the following steps:

[0026] (a) Clean the base material of the refractory metal parts, and chemically etch the surface of the refractory metal parts. First, use 5~10% NaOH solution to carry out alkali cleaning on the refractory metal parts for 25 minutes, and then use 45ml HCl, 45ml H 2 SO 4 , 10ml HF and 900ml H 2 The mixed pickling solution composed of O is used to pickle the refractory metal parts, the pickling time is 10min, and the surface roughness of the base material of the refractory metal parts after treatment is not higher than Ra3.2;

[0027] (b) Add nitrocellulose and methyl cellulose to ethyl acetate, and then add composite ceramic coating powder to ethyl acetate dissolved in nitrocellulose and methyl cellulose. The composite ceramic coating powder is selected ...

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PUM

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Abstract

The invention discloses a coating method for coating composite ceramic coating layers on the surfaces of refractory metal parts. Firstly, the surfaces of the refractory metal parts are modified; then,a thickening agent and a dispersing agent are added in organic solvent, and composite ceramic coating layer powder is added for ball milling to prepare suspension pulp; the solid content of compositeceramic coating layer powder in the suspension pulp is controlled within 40-65%; the viscosity of the suspension pulp is 10-30 mm2/s; then, the suspension pulp is uniformly sprayed on the modified surfaces of the refractory metal parts to obtain coating layer blanks; and finally, the coating layer blanks are sintered to form the composite ceramic coating layers on the surfaces of the refractory metal parts. The coating method improves the bonding performances between the composite ceramic coating layers and refractory metal, improves the uniform coating property of the composite ceramic coating layers, and realizes uniform coating of the composite ceramic coating layers on the surfaces of the refractory metal parts with large sizes, multiple dimensions and complicated shapes.

Description

technical field [0001] The invention belongs to the technical field of coatings, in particular to a coating method for coating a composite ceramic coating on the surface of a refractory metal piece. Background technique [0002] Refractory metals have a series of excellent properties such as high melting point, good mechanical properties and electrical properties, good thermal conductivity and low thermal expansion coefficient. They are very important in many industries. However, some specific properties of refractory metals are poor. , restricting its further application. In order to meet the requirements of the application field, it is necessary to prepare ceramic coatings with different functions on the surface of refractory metal parts to improve the properties of refractory metals such as oxidation resistance, ablation resistance, erosion resistance, corrosion resistance and wear resistance, so as to make them To meet the needs of the corresponding application fields a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/08
Inventor 范景莲李威范衍成创功雷左明刘涛
Owner 长沙微纳坤宸新材料有限公司
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