Preparation method of inorganic-organic hybrid antibacterial agent with antibacterial and hydrophobic functions and application of antibacterial agent
A technology of organic hybridization and antibacterial agent, applied in the field of antibacterial materials, can solve the problems of unsatisfactory antibacterial effect of bacteria and mold, achieve excellent antibacterial and mold performance, improve easy cleaning, and good surface hydrophobicity.
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Embodiment 1
[0035] Inorganic-organic hybrid antibacterial agent: (1) Dissolve 3-aminopropyltrimethoxysilane in 150mL of ethanol and water in an aqueous ethanol solution with a volume ratio of 1:9, add nano-titanium dioxide, ultrasonically disperse for 30min, stir for 2h, and After filtering and washing, dry at 60°C for 24 hours to obtain coupled titanium dioxide; wherein the ratio of 3-aminopropyltrimethoxysilane and nano-titanium dioxide to the total mass of the two is 0.5wt%: 99.5wt% (2) Dissolve coupled titanium dioxide in 150 mL of ethanol, add cinnamaldehyde, stir for 4 hours, filter and wash, then dry at 60°C for 24 hours to obtain cinnamaldehyde-titanium dioxide hybrid antibacterial agent; wherein the coupling The ratio of the percentages of titanium dioxide and cinnamaldehyde to the total mass of the two is 95wt%: 5wt%.
Embodiment 2
[0039] Inorganic-organic hybrid antibacterial agent: (1) Dissolve 3-aminopropyltriethoxysilane in 150mL ethanol and water ethanol aqueous solution with a volume ratio of 5:5, add nano titanium dioxide, ultrasonically disperse for 30min, stir for 2h, After filtering and washing, dry at 60°C for 24 hours to obtain coupled titanium dioxide; wherein the ratio of 3-aminopropyltriethoxysilane and nano-titanium dioxide to the total mass of the two is 5wt%: 95wt% (2) dissolving 93wt% coupled titanium dioxide in 150mL ethanol, adding 7wt% citral, stirring for 4h, filtering and washing, drying at 60°C for 24h to obtain citral-titanium dioxide hybrid antibacterial agent; The ratio of the percentages of the coupled titanium dioxide and citral to the total mass of the two is 93wt%: 7wt%.
Embodiment 3
[0043] Inorganic-organic hybrid antibacterial agent: (1) Dissolve 3-aminopropylmethyldiethoxysilane in 150mL ethanol and water ethanol aqueous solution with a volume ratio of 7:3, add nano titanium dioxide, ultrasonically disperse for 30min, stir 2h, after filtering and washing, dry at 60°C for 24h to obtain coupled titanium dioxide; wherein the ratio of 3-aminopropylmethyldiethoxysilane and nano-titanium dioxide to the total mass of the two is 7wt %: 93wt%; (2) Dissolve 93wt% coupled titanium dioxide in 150mL ethanol, add 7wt% citral, stir for 4h, filter, wash, and dry at 60°C for 24h to obtain an inorganic-organic hybrid antibacterial agent ; Wherein the ratio of the percentage of coupled titanium dioxide and citral to the total mass of the two is 93wt%: 7wt%.
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