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A high-temperature hydrothermal method for increasing biogas generated from garden waste

A garden waste, high-temperature hydrothermal technology, applied in the high-temperature hydrothermal field, can solve the problem of low biomass biochemical conversion efficiency, and achieve the effects of good sustainability, improved fermentation efficiency, and high-efficiency energy conversion.

Active Publication Date: 2022-02-25
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a high-temperature hydrothermal method for increasing the gas produced by garden waste, which can remove lignin to the greatest extent while retaining fermentable sugars such as cellulose and hemicellulose, and does not require detoxification And other follow-up treatment, significantly improve the fermentation efficiency of its biogas, and then realize the efficient energy conversion of garden waste, solve the problem of low biochemical conversion efficiency of biomass in the existing technology, and the problem of detoxification in follow-up treatment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] 1) Using water as the reaction medium, add the branches and leaves of Safflower safflower as the substrate in the high-pressure reactor, so that the substrate mass concentration is 5%, react at 180°C for 30min, and then follow the water mass ratio of 2:1 Add choline chloride to prepare a new reaction solution, continue to react at 180°C for 40 minutes to obtain a solid-liquid mixture, wherein the lignin removal rate of the substrate raw material is 70%, the cellulose retention rate is 95%, and the hemicellulose derivative Sugar yield was 85%.

[0019] 2) The solid-liquid mixture obtained in step 1) was directly inserted into the anaerobic fermentation strain according to the method reported in the literature (Bioresour.Technol.2018, 55, 205-212), and fermented for 30 days to obtain biogas. Compared to untreated feedstock, its total biogas production is increased by about 380%;

Embodiment 2

[0021] 1) Using water as the reaction medium, add the mixed garden waste of Phyllostachys pubescens and Taiwan grass as the substrate in the high-pressure reactor, so that the substrate mass concentration is 10%, react at 180°C for 60min, and then according to the mass ratio with water Add choline chloride at a ratio of 1:1 to obtain a new reaction solution, continue to react at 160°C for 60 minutes to obtain a solid-liquid mixture, wherein the lignin removal rate of the substrate raw material is 65%, the cellulose retention rate is 90%, half The cellulose-derived sugar yield was 80%.

[0022] 2) The solid-liquid mixture obtained in step 1) was directly inserted into the anaerobic fermentation strain according to the method reported in the literature (Bioresour.Technol.2018, 55, 205-212), and fermented for 30 days to obtain biogas. Compared with untreated feedstock, its total biogas production is increased by about 400%.

Embodiment 3

[0024] 1) water and choline chloride are mixed according to the mass ratio of 4:1 to prepare a reaction liquid, and mixed garden wastes such as sunflower leaves, eucalyptus branches, and safflower safflower branches are added in the autoclave as substrates, The raw materials make the substrate mass concentration 20%, react at 220°C for 30min, pour off the liquid, add the same amount of pure water, and continue to react at 200°C for 30min to obtain a solid-liquid mixture, wherein the lignin removal rate of the substrate raw material It is 80%, the cellulose retention rate is 80%, and the hemicellulose-derived sugar yield is 75%.

[0025] 2) The solid-liquid mixture obtained in step 1) was directly inserted into the anaerobic fermentation strain according to the method reported in the literature (Bioresour.Technol.2018, 55, 205-212), and fermented for 30 days to obtain biogas. Compared with the untreated raw material, its total biogas production is increased by about 450%.

[0...

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Abstract

The invention discloses a high-temperature hydrothermal method for increasing biomass gas produced by garden waste. The method comprises the following steps: adding water and choline chloride in sequence in a reactor, mixing to obtain a reaction solution, and then adding garden waste Raw material or / with other lignocellulosic biomass mixture as substrate, react at 160-220 ℃ for 1-2h to obtain solid-liquid mixture; the solid-liquid mixture is directly connected to anaerobic fermentation bacteria for biogas fermentation to obtain biogas . The present invention removes lignin to the greatest extent while retaining fermentable sugars such as cellulose and hemicellulose, and does not require subsequent treatment such as detoxification, thereby significantly improving the fermentation efficiency of its biogas, thereby realizing high efficiency of garden waste. The energy conversion solves the problems of low biomass biochemical conversion efficiency and detoxification in subsequent treatment in the prior art. Compared with other pretreatment methods, this method has better sustainability and greater application potential.

Description

Technical field: [0001] The invention relates to the technical field of biomass conversion, in particular to a high-temperature hydrothermal method for increasing gas produced by garden waste. Background technique: [0002] Garden waste refers to green waste such as branches and leaves produced by artificial pruning and natural effects such as seasonal changes and typhoons. With the continuous advancement of my country's urbanization and urban greening construction, landscaping waste is gradually increasing. According to statistics, only Guangdong Province produces 12 million tons per year. Common treatment and reuse methods include making soil improvement substrates (CN102585836A, CN106365824A), composting (CN102295478A, CN105820011A), fiberboard (CN107323059A), biochar (CN107555414A) and the like. Garden waste has a typical lignocellulosic biomass structure, and its main components are cellulose, hemicellulose and lignin, so it can be used as a raw material for bioenergy ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C12P5/02
CPCC12P5/023Y02E50/30
Inventor 余强孔晓英孙永明李连华
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI