Nickel colloidal catalyst solution for electroless nickel or nickel alloy plating, and method for electroless nickel or nickel alloy plating

A technology of electroless nickel plating and nickel alloy, which is applied in the direction of liquid chemical plating, metal material coating process, coating, etc., can solve the problems such as inability to electroless nickel plating, achieve good appearance uniformity, excellent stability, and prevent mixing Effect

Active Publication Date: 2019-04-16
ISHIHARA CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, electroless nickel plating cannot be performed on precious metals such as gold because palladium catalyst nuclei are not replaced and precipitated (paragraph 4)

Method used

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  • Nickel colloidal catalyst solution for electroless nickel or nickel alloy plating, and method for electroless nickel or nickel alloy plating
  • Nickel colloidal catalyst solution for electroless nickel or nickel alloy plating, and method for electroless nickel or nickel alloy plating
  • Nickel colloidal catalyst solution for electroless nickel or nickel alloy plating, and method for electroless nickel or nickel alloy plating

Examples

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Effect test

Embodiment

[0141] Below, the embodiment of the electroless nickel plating or the nickel alloy method including the preparation of the liquid containing the adsorption accelerator of the present invention, the nickel colloid catalyst liquid, and the electroless nickel plating or the nickel alloy liquid is described, and it is explained in sequence: preparation Test example of initial nickel colloidal catalyst solution over time, test example of appearance evaluation of nickel (or nickel alloy) film precipitated by electroless plating using the catalyst solution, test example of repeated use resistance when nickel colloidal catalyst solution is used repeatedly An evaluation test example and an appearance evaluation test example of a nickel (or nickel alloy) film deposited by electroless plating using the repeatedly used catalyst solution.

[0142] It should be noted that the present invention is not limited to the following examples and test examples, and it is of course possible to arbitra...

Embodiment 4-5

[0147] Embodiment 4-5: the example of changing the content of soluble nickel salt (A)

Embodiment 10-12

[0148] Embodiment 10-12: change the example of colloid stabilizer (C)

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Abstract

In the present invention, a non-conductive substrate is submerged in a liquid containing a surfactant for an adsorption enhancement processing; next, a catalyst is imparted to the non-conductive substrate in a nickel colloidal catalyst solution for electroless nickel plating, the solution containing a colloidal stabilizer (C) comprising a soluble nickel salt (A), a reducing agent (B), and a specific sugar such as glucose, fructose, sorbitol, xylitol, maltitol, or mannitol; and subsequently the electroless nickel plating is performed. After the catalytic activity is enhanced by the adsorption enhancement processing, a catalyst is imparted to the nickel colloidal catalyst solution that is highly stable over time and over repeated uses, and the electroless nickel plating is performed. As a result, a uniform nickel coating without uneven precipitation can be obtained. Even if this nickel plating method is replaced with a nickel alloy plating method, a highly uniform nickel alloy coating can be obtained.

Description

technical field [0001] The present invention relates to a nickel colloid catalyst solution for imparting a catalyst when electroless nickel or nickel alloy plating is performed on a non-conductive substrate, and an electroless plating method using the catalyst solution, which provides excellent stability over time and can form a uniform appearance It is a catalyst solution that has no streaky nickel or nickel alloy film, and can improve the effectiveness of repeated use of the nickel colloid catalyst solution by inserting a predetermined treatment before catalyst application. Background technique [0002] In order to represent resin substrates such as glass-epoxy resin, glass-polyimide resin, epoxy resin, polyimide resin, polycarbonate resin, ABS resin, PET resin, etc., including glass substrates, ceramic substrates, etc. Electroless nickel or nickel alloy plating is carried out on the non-conductive substrate inside. The conventional method is: firstly, metals such as palla...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/18C23C18/34
CPCC23C18/18C23C18/34C23C18/1837C23C18/2073C23C18/50
Inventor 吉泽章央田中雄也内田卫田中薰
Owner ISHIHARA CHEM
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