Sulfur concrete with sublimation corrosion resistance and preparation method thereof

A sulphur concrete and sulphur technology, applied in the field of polymer materials, can solve the problems of not meeting the long-term use of lunar sulphur concrete, high sublimation rate of sulphur concrete, affecting service time, etc. Efficient effect

Inactive Publication Date: 2019-04-19
LOGISTICAL ENGINEERING UNIVERSITY OF PLA
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Problems solved by technology

The surface of the moon is a high vacuum environment (about 1×10 -12 torr, which is 1.33×10 -12 Pa), the sublimation solid-gas phase transition temperature of sulfur will be lower, and the ambient temperature near the lunar equator is -180°C to 123°C, and the ambient temperature near the pole is -60°C to -220°C, which will accelerate the decomposition of sulfur Sublimation, the sublimation of sulfur will cause the deterioration of the structure and bring new problems to the long-term use of sulfur concrete
[0003] To sum up, the problems existing in the existing technology ar

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  • Sulfur concrete with sublimation corrosion resistance and preparation method thereof
  • Sulfur concrete with sublimation corrosion resistance and preparation method thereof

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[0024] Aiming at the problem that the existing sulfur concrete has a high sublimation rate and cannot meet the long-term use of lunar sulfur concrete; the invention provides a kind of anti-sublimation corrosion sulfur concrete for a lunar base and a preparation method thereof; It can increase the transition temperature of sulfur cementitious materials directly from solid to gas in high vacuum environment, and reduce the sublimation rate of sulfur concrete.

[0025] The application principle of the present invention will be described in detail below in conjunction with the accompanying drawings.

[0026] The anti-sublimation corrosion sulfur concrete provided by the embodiments of the present invention consists of 15% to 20% of sulfur, 0.2% to 0.6% of admixture, 55% to 65% of lunar rock coarse aggregate and 14% to 26% of lunar soil filler according to the mass percentage composition.

[0027] The admixture is a modified component of sulfur, including magnesium stearate, fluori...

Embodiment 1

[0036] The anti-sublimation corrosion sulfur concrete provided by the embodiment of the present invention is calculated by mass percentage, sulfur is 18.5% of the total mass, admixture is 0.5%, lunar rock coarse aggregate is 61%, and lunar soil filler is 20%. The admixture is magnesium stearate: fluorinated polystyrene: carbon tetrafluoride = 1:5:20 by mass ratio, and the amount of admixture is about 2.7% of the mass of sulfur. The coarse aggregate of lunar rock is basalt on the ground, with a particle size of 15-45 mm; the raw material of lunar soil filler is low-titanium simulated lunar soil (CLRS-1) jointly developed by Guiyang Institute of Geochemistry, Chinese Academy of Sciences and the National Astronomical Observatory. Lunar soil filler with a particle size of 0.1-1mm.

[0037] The preparation method of the anti-sublimation corrosion sulfur concrete provided by the embodiment of the present invention comprises the following steps:

[0038] Step 1: Weigh each component...

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Abstract

The invention belongs to the technical field of macromolecule materials, and discloses sulfur concrete with sublimation corrosion resistance and a preparation method thereof. The sulfur concrete is prepared from, by mass, 15-20% of sulfur, 0.2-0.6 % of an additive, 55-65% of lunar rock coarse aggregate and 14-26% of lunar soil filler. The additive is prepared by mixing magnesium stearate, polystyrene fluoride and carbon tetrafluoride at the mass ratio of 1:5:20, and the addition amount of the additive is 1-4% of sulfur. The additive is used for pre-modifying sulfur, the sublimation rate of sulfur components in sulfur concrete under high vacuum conditions is effectively reduced, the durability of sulfur concrete under high vacuum conditions is improved, and the preparation technology is simple and easy to operate, the construction efficiency is high, and the sulfur concrete is easy to produce and use under high vacuum conditions such as the moon.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a sublimation-corrosion-resistant sulfur concrete and a preparation method thereof. Background technique [0002] At present, the existing technologies commonly used in the industry are as follows: the mineral resources, energy resources and special resources of the moon will play a long-term and stable supporting role in the sustainable development of human society. The first goal of layer space development. In the 2006-2020 "National Medium- and Long-Term Science and Technology Development Plan", China listed the lunar exploration project as one of the 16 major special projects, and initially formulated the goal of manned moon landing and the establishment of a lunar base in 2030. Other countries and regions in the world such as the United States, the European Union, Japan, Israel, etc. have also released plans to establish moon bases. In order to build ...

Claims

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Application Information

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IPC IPC(8): C04B28/36
CPCC04B28/36C04B2111/00982C04B2201/50C04B24/085C04B24/2682C04B24/005C04B14/14C04B14/00
Inventor 周凌唐军务邓智平王健琪雍子豪曹岩
Owner LOGISTICAL ENGINEERING UNIVERSITY OF PLA
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