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Stainless steel super-hydrophobic and super-hydrophilic surface and preparation method and application thereof

A super-hydrophobic surface and super-hydrophilic technology, applied in welding equipment, manufacturing tools, laser welding equipment, etc., can solve problems such as limited condensation efficiency of condensation equipment, unstable quality of laser cladding, and condensate droplets detached from the surface, etc., to achieve Speed ​​up condensation heat transfer efficiency, easy control of process parameters, and improve condensation efficiency

Inactive Publication Date: 2019-05-03
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For example: Patent CN201710134468 discloses a method of laser selective melting of metal nanoparticles solution additively manufacturing hydrophobic surfaces in an air environment. The improved method requires chemical assistance, and the spread of metal nanoparticles is difficult to uniform, resulting in unstable laser cladding quality. The processing efficiency is not high; the patent CN201710017934 discloses laser preparation of metal biomimetic super-hydrophobic surfaces. After the sample is laser-treated once, the plane is rotated 90° and then processed for the second time, which is similar to grid processing. The rotation in the processing step is not rigorous, making the sample There is no uniform standard
However, the super-hydrophobic surface prepared by the above methods can only prevent the condensation of droplets on the surface, but cannot make the condensed droplets leave the surface quickly, which has very limited improvement in the condensation efficiency of condensation equipment.

Method used

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  • Stainless steel super-hydrophobic and super-hydrophilic surface and preparation method and application thereof
  • Stainless steel super-hydrophobic and super-hydrophilic surface and preparation method and application thereof
  • Stainless steel super-hydrophobic and super-hydrophilic surface and preparation method and application thereof

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preparation example Construction

[0028] Embodiments of the present invention also provide a method for preparing a stainless steel superhydrophobic-superhydrophilic surface, comprising the following steps:

[0029] (1) Using pulsed laser scanning to process the pretreated stainless steel surface into a super-hydrophilic surface;

[0030] (2) baking the super-hydrophilic surface treated in step (1) to obtain a super-hydrophobic surface;

[0031] (3) Use pulsed laser to scan the superhydrophobic surface in step (2) to process multiple superhydrophobic regions and multiple superhydrophilic regions alternately arranged in wedge-shaped or triangular sub-arrays, and each sub-array is distributed with superhydrophobic Hydrophilic pooling area, that is, a super-hydrophobic-super-hydrophilic surface.

[0032] In the present invention, the required structural pattern can be compiled on the surface of the superhydrophobic region in step (2), and then the structural pattern can be processed by pulsed laser scanning, so ...

Embodiment 1

[0054] This embodiment provides a method for preparing a stainless steel super-hydrophobic-super-hydrophilic surface, comprising the steps of:

[0055] (1) Use a metallographic sample pre-grinder with a power of 370W, a grinding disc speed of 450 rpm, and a grinding disc diameter of 230 mm to polish the surface of the 304 stainless steel to be treated. During the polishing process, the auxiliary diameter is 200 mm, 1000 Purpose SiC water sandpaper is used to polish the surface of stainless steel, and the polishing range is 100cm 2 , the polishing time was 10 minutes, and the stainless steel after surface polishing was obtained; then, the stainless steel after surface polishing was cleaned with an ultrasonic cleaner, and the ultrasonic frequency of the ultrasonic cleaner was 40kHz, and the surface of the stainless steel was flooded with deionized water with a resistivity of 18.25 megohms , wash continuously at room temperature for 30 minutes, and dry naturally or with cold air ...

Embodiment 2

[0061] This embodiment provides a method for preparing a stainless steel super-hydrophobic-super-hydrophilic surface, comprising the steps of:

[0062] (1) adopt the method identical with embodiment 1 to carry out pretreatment to 304 stainless steel surface, obtain clean stainless steel sample;

[0063] (2) Use a short-pulse laser to perform laser scanning processing on the clean stainless steel sample in step (1), and process a super-hydrophilic surface with numerous microstructures on the surface of the stainless steel sample. The laser wavelength is 1064nm, and the laser pulse width is 220ns. Single pulse The energy is 0.60mJ, and the repetition frequency is 150kHz; the moving platform device is used for laser scanning, the clean stainless steel sample obtained in step (1) is fixed on the moving working platform, and the laser beam is focused on the sample by using a lens to make the stainless steel sample Relative to the focused etching spot of the ultrafast laser beam, th...

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Abstract

The invention discloses a stainless steel super-hydrophobic and super-hydrophilic surface. Multiple sub arrays are distributed on the surface of stainless steel. Multiple super-hydrophobic areas and multiple super-hydrophilic areas in each sub array are arranged alternately in wedge shapes or triangular shapes. Super-hydrophilic gathering areas are districted among the sub arrays. The super-hydrophobic surface is excellent in super-hydrophobic performance; liquid drops are quite small in adhesion and can fall off quite easily; the super-hydrophilic areas can adsorb the liquid drops, the liquiddrops at the top ends of the wedge shapes or the triangular shapes can be driven by the plus force generated by the wedge shapes or the triangular shapes to move automatically and rapidly toward thebottoms of the wedge shapes or the triangular shapes; the super-hydrophobic areas which are alternate with the super-hydrophilic areas can repel oriented output of the liquid drops; the super-hydrophilic areas and the super-hydrophobic areas achieve the synergistic effect, so that the condensed small liquid drops are continuously gathered to a hydrophilic gathering area, and high-concentration self-drive water collection is achieved; falling of the liquid drops is accelerated, and thus, the condensation heat transfer efficiency is improved. The invention further provides a preparation method and application of the stainless steel super-hydrophobic and super-hydrophilic surface.

Description

technical field [0001] The invention relates to the technical field of surface modification of metal substrates, in particular to a superhydrophobic-superhydrophilic surface of stainless steel and a preparation method and application thereof. Background technique [0002] In many important applications, such as heat transfer, seawater desalination, water harvesting, etc., the condensation of water vapor is a very important process. On a solid surface, the condensation process includes droplet condensation and film condensation, and the condensation method depends on the wettability of the condensation surface. Droplet condensation can greatly improve the efficiency of heat transfer. Studies have shown that compared with film condensation, the heat transfer efficiency of droplet condensation can be increased by more than 10 times. [0003] Condensing equipment is a device used to promote condensation, which mainly uses the principle of heat exchange to cool and condense stea...

Claims

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Application Information

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IPC IPC(8): B23K26/352
Inventor 娄德元刘庆梅胜曹剑锋杨少坤刘顿杨奇彪成健
Owner HUBEI UNIV OF TECH
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