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Water-based crosslinked epoxy anticorrosive coating based on wax modification and preparing method thereof

A technology of epoxy anti-corrosion coatings and waxy materials, which is applied in the direction of anti-corrosion coatings, epoxy resin coatings, coatings, etc., and can solve the problem of recovery, flammable characteristics, safety hazards, anti-rust oils that cannot achieve long-term anti-corrosion, and cannot achieve Anti-corrosion cycle and other issues, to achieve the effect of increasing anti-corrosion effect, good coloring effect, and improving anti-corrosion effect

Pending Publication Date: 2019-05-24
JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Brushing anti-rust oil on the surface of metal materials can only play a temporary protective role, and the recovery and flammability of oil have potential safety hazards; the coating of paint is mainly carried out by the adsorption force between molecules, because the coating layer is thin , the corrosion resistance is limited, the service life is short, and the purpose of long-term corrosion protection cannot be achieved
[0003] Adding a gas phase corrosion inhibitor to the existing anti-rust oil can play a certain anti-rust effect on the metal inner wall of the cavity structure through the volatilization and adsorption of the gas phase corrosion inhibitor. However, this kind of anti-rust oil will still volatilize the solvent, And the anti-rust oil itself cannot achieve the long-term anti-corrosion effect; the existing emulsified anti-corrosion wax has little safety hazard, but it is easy to cause reverse emulsification at the place where water accumulates, and the film is easy to be washed away, thus failing to achieve a long-term anti-corrosion cycle

Method used

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  • Water-based crosslinked epoxy anticorrosive coating based on wax modification and preparing method thereof
  • Water-based crosslinked epoxy anticorrosive coating based on wax modification and preparing method thereof
  • Water-based crosslinked epoxy anticorrosive coating based on wax modification and preparing method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0050] A water-based cross-linked epoxy anti-corrosion coating based on wax modification, including 18 parts of epoxy resin, 3 parts of methyl ether, 4 parts of isooctyl alcohol, 12 parts of perbasic sulfonate, 6 parts of polyethylene wax, 5 parts of surfactant, 4 parts of diethanolamine, 5 parts of polyamine resin and crosslinking agent, fully mix the above materials, add 2 parts of carboxylic acid for neutralization reaction, and disperse the mixed material in 50 parts of water, The above parts are all by weight.

[0051] Specifically, the high alkali value sulfonate is shown in the following formula:

[0052]

[0053] Where: n=2;

[0054] R3 is calcium ion;

[0055] R4 is C8-C30 isomeric branched chain alkyl;

[0056] The molecular weight of the overbasic sulfonate is 752, and the total base number of the overbasic sulfonate is 260 mgKOH / g.

[0057] Specifically, the waxy material is paraffin.

[0058] Specifically, the surfactant is fatty acid containing C8-C28 isome...

Embodiment 2

[0072] Compared with Example 1, the difference of Example 2 is that the crosslinking agent production process adopted is as follows:

[0073] A kind of production technology of linking agent I, comprises the following steps:

[0074] S1: Check the cleanliness of the reactor, the position of each pipeline and valve;

[0075] S2: 260 parts of toluene diisocyanate are vacuum pumped in, and 2.6 parts of organotin liquid are added while stirring;

[0076] S3: Pump 280 parts of ethylene glycol butyl ether into the metering tank, and when the material temperature rises to 60°C, add ethylene glycol butyl ether dropwise, and control the temperature at 60°C during the dropping process;

[0077] S4: After the dropwise addition of ethylene glycol butyl ether, react at a temperature of 68° C. for 1 hour, and add 180 parts of polyether;

[0078] S5: react at 90°C for 3.5 hours, add 280 parts of propylene glycol methyl ether at 65°C, stir evenly, discharge into a clean and dry airtight con...

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Abstract

The invention provides a water-based crosslinked epoxy anticorrosive coating based on wax modification and a preparing method thereof, and relates to the technical field of anticorrosive coatings. Thewater-based crosslinked epoxy anticorrosive coating is prepared from, by weight, 13-21 parts of epoxy resin, 2-5 parts of methyl ether, 2-5 parts of isooctanol, 10-15 parts of high-alkali-value sulfonate, 5-8 parts of a waxiness material, 3-8 parts of a surfactant, 2-5 parts of diethanol amine, 3-6 parts of polyamine resin and a cross-linking agent; the materials are fully mixed, 1.5-3 parts by weight of carboxylic acid are added for a neutral reaction, and the mixture is dispersed in 38-60 parts by weight of water. According to the water-based crosslinked epoxy anticorrosive coating and thepreparing method, the bondability is improved through the internally-added waxiness material, the dispersion state of the water-based crosslinked epoxy anticorrosive coating is stabilized in cooperation with the surfactant, the long-term anti-corrosion capacity can be improved, and the production cost can be reduced.

Description

technical field [0001] The invention belongs to the technical field of anti-corrosion coatings, in particular to a wax-based modified water-based cross-linked epoxy anti-corrosion coating and a preparation method thereof. Background technique [0002] At present, steel frame structures are widely used in the fields of ships, aerospace, road and bridge construction, etc. Due to the harsh use environment, the requirements for the corrosion resistance of the steel frame surface are getting higher and higher, and metal alloys are prone to rust and surface corrosion in actual environments. Therefore, it is urgent to deal with the surface corrosion and rust of metal materials. Brushing anti-rust oil on the surface of metal materials can only play a temporary protective role, and the recovery and flammability of oil have potential safety hazards; the coating of paint is mainly carried out by the adsorption force between molecules, because the coating layer is thin , the corrosion ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/08C09D7/63C09D7/20
Inventor 胡明谢海戴国绪
Owner JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD
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