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Highly-color-change-resistant golden brass alloy and preparation method

A technology of discoloration gold and brass alloy, applied in commemorative coins and various decorative materials, high anti-discoloration golden brass alloy and preparation, artwork, bookmark fields, can solve the problems of high preparation cost, poor anti-discoloration ability, etc. To achieve the effect of reasonable alloy composition, low production cost and good machining performance

Active Publication Date: 2019-07-19
CENT SOUTH UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the problem of poor anti-tarnish ability of the existing golden copper alloy, and the high cost of preparation of the material due to the high price of alloy elements such as indium and silver, and provide an alloy with reasonable composition, low raw material price, The production process is simple, the production cost is low, the processing performance is good, the gold degree is high, the anti-discoloration performance is excellent in the environment such as salt spray, high humidity, artificial sweat, the environment-friendly high anti-discoloration golden copper alloy and its preparation method, to meet various Demand for high tarnish-resistant, golden copper alloys for decorative materials and handicrafts

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] The composition is Mn: 2.0wt%, Sn: 1.3wt%, Ni: 1.0wt%, Zn: 13%, Sr: 0.05wt%, Ce: 0.1wt%, B: 0.1wt%, Si: 0.15wt%, The proportion of gold-colored copper alloy components with the balance of copper is pure zinc, pure nickel, copper-manganese, copper-silicon, copper-strontium, copper-cerium, nickel-boron intermediate alloy and electrolytic copper; first, the electrolytic copper is baked Dry, add nickel, heat and melt, cryolite, calcium fluoride and coke borax are used as covering agents in the melting process, the volume percentage is 1:1:1. Then, copper-manganese, copper-silicon, copper-strontium, copper-cerium, nickel-boron intermediate alloys are added to the electrolytic copper melt to obtain an alloy melt. The temperature of the furnace is controlled at 1210°C. ℃ for semi-continuous casting, with an average casting speed of 6.0m / h. Heat the copper alloy ingot at 690°C for 6 hours, then heat it to 800°C for 3 hours, and perform 9 passes of hot rolling. The deformation ...

Embodiment 2

[0062] The composition is Mn: 3.0wt%, Sn: 0.7wt%, Ni: 0.7wt%, Zn: 14%, Sr: 0.05wt%, Ce: 0.1wt%, B: 0.1wt%, Si: 0.2wt%, The proportion of gold-colored copper alloy components with the balance of copper is pure zinc, pure nickel, copper-manganese, copper-silicon, copper-strontium, copper-cerium, nickel-boron intermediate alloy and electrolytic copper; first, the electrolytic copper is baked Dry, add nickel, heat and melt, cryolite, calcium fluoride and coke borax are used as covering agents in the melting process, the volume percentage is 1:1:1. Then, copper-manganese, copper-silicon, copper-strontium, copper-cerium, nickel-boron intermediate alloys are added to the electrolytic copper melt to obtain an alloy melt. The temperature of the furnace is controlled at 1220° C. ℃ for semi-continuous casting, with an average casting speed of 5.5m / h. Heat the copper alloy ingot at 690°C for 6 hours, then heat it to 825°C for 3 hours, and perform 9 passes of hot rolling. The deformation ...

Embodiment 3

[0064] The composition is Mn: 4.0wt%, Sn: 1.0wt%, Ni: 2.0wt%, Zn: 14%, Sr: 0.05wt%, Ce: 0.1wt%, B: 0.1wt%, Si: 0.1wt%, The proportion of gold-colored copper alloy components with the balance of copper is pure zinc, pure nickel, copper-manganese, copper-silicon, copper-strontium, copper-cerium, nickel-boron intermediate alloy and electrolytic copper; first, the electrolytic copper is baked Dry, add nickel, heat and melt, cryolite, calcium fluoride and coke borax are used as covering agents in the melting process, the volume percentage is 1:1:1. Then, copper-manganese, copper-silicon, copper-strontium, copper-cerium, nickel-boron intermediate alloys are added to the electrolytic copper melt to obtain an alloy melt. The temperature of the furnace is controlled at 1230° C. ℃ for semi-continuous casting, with an average casting speed of 5.0m / h. Heat the copper alloy ingot at 690°C for 6 hours, then heat it to 850°C for 3 hours, and perform 9 passes of hot rolling. The deformation ...

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PUM

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Abstract

The invention discloses a highly-color-change-resistant golden brass alloy and preparation method. The highly-color-change-resistant golden brass alloy comprises the following components of Mn, Sn, Ni, Zn, Sr, Ce, B, Si and the balance Cu and inevitable impurities. The preparation process comprises the following steps of casting, hot rolling, cold rolling, intermediate annealing, cold finish roughrolling, cold finish rolling and finished product annealing. The alloy produced by the method is high in golden degree, good in color-change resistance, excellent in hot and cold machining performance, small in deformation resistance, free of precious metal elements and relatively low in cost; the alloy produced by the method is reasonable in component, the golden degree of the alloy is improvedthrough reasonable matching of cheap manganese, nickel, zinc and tin, the zinc content is lower than 20% so that dezincification corrosion can be avoided, through the reasonable combination strontium,cerium, boron and silicon, the process performance can be improved, and the color-change resistance can be improved; according to the alloy, the production process is simple, the production cost is low, the machining performance is good, the golden degree is high, the color-change resistance is excellent in the environment of salt mist, high humidity, synthetic perspiration and the like, and thealloy is suitable for industrial production.

Description

technical field [0001] The invention relates to a gold brass alloy with high discoloration resistance and a preparation method, which are mainly used in artworks, bookmarks, commemorative coins (chapters) and various decorative materials. It belongs to the field of new material technology. Background technique [0002] Gold has a dazzling golden yellow color and very stable chemical properties. In addition to being widely used as a functional material in electronic information and other fields, gold has always been the preferred material for artworks, handicrafts and other products. However, due to its low reserves and high price, as a large art market, a large number of applications are restricted. Therefore, high-quality and cheap imitation gold alloy products are getting more and more attention. [0003] The commonly used imitation gold products at home and abroad are mainly copper-based imitation gold products. Domestic research is mainly to add aluminum, zinc, tin, ni...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/04C22C1/03C22F1/08C22F1/02
CPCC22C1/03C22C9/04C22F1/02C22F1/08
Inventor 李周邱文婷王檬孙艳于翔宇
Owner CENT SOUTH UNIV
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