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275results about How to "Excellent discoloration resistance" patented technology

Cyanide-free silver plating electroplating solution and preparation method and electroplating method thereof

ActiveCN102168290AGood stabilityStrong dispersion abilityIonChemistry
The invention discloses a cyanide-free silver plating electroplating solution and a preparation method and an electroplating method thereof, belonging to the field of electrosilvering. The invention aims at solving the technical problems of poor stability and narrow current density scope of an electroplating solution in the traditional cyanide-free silver plating system. The cyanide-free silver plating electroplating solution is prepared from glycolyurea derivatives, pyridine substances, silver nitrate, potassium carbonate, potassium hydroxide and deionized water. The cyanide-free silver plating electroplating solution is prepared by adopting a mixing method. Silver plating is performed according to the electroplating method. The electroplating solution of the invention has the dispersibility ranging from 65% to 75% and good stability so that the newly-prepared electroplating solution and the electroplating solution subsequent to electroplating are free from deposition, color change and other situations after being placed for 2 months and can still be continuously used to acquire an excellent plating layer. A copper replacement experiment finds that the cyanide-free silver plating electroplating solution in the embodiment can withstand the replacement time up to more than 5 minutes. The acquired plating layer is bright and consistent in appearance, compact and flat, small in crystalline grains and strong in color change resistance. Electroplating can be performed when the current density is 0.8 to 2.0A/dm<2>.
Owner:HARBIN INST OF TECH

Method for double-pulse electrodeposition of nanocrystalline nickel-cobalt alloy

The invention relates to a method for electrodepositing a nanocrystalline nickel-cobalt alloy by double-pulse. The method for electrodepositing the nanocrystalline nickel-cobalt alloy by double-pulse is characterized by comprising the following processing steps: in a plating solution with a pH value of 5-6, a nickel ion concentration of 0.68-0.95 mol / L and a cobalt ion concentration of 1.9*10<-2>to 3.8*10<-2> mol / L, taking a soluble nickel plate after the soluble nickel plate is subjected to surface treating as a anode, taking an iron sheet after the iron sheet is subjected to surface treating as a cathode and electroplating a nanocrystalline nickel-cobalt alloy layer by using double-pulse electrodepositing technology, wherein the time for electrodepositing is 15-20 min, the positive-going pulse current density is 1.0-2.0 A / dm<2>, the positive-going duty ratio is 60-80%, the working time of the positive-going pulse is 50-100 ms and the positive-going cycle is 40-60 ms; and the negative-going pulse current density is 0.1-0.2 A / dm<2>, the negative-going duty ratio is 60-80%, the working time of the negative-going pulse is 10-20 ms, the negative-going cycle is 1-2 ms and the workingtime of the positive-going pulse is 5-10 times of that of the negative-going pulse. The nickel-cobalt alloy coating prepared by the method has the advantages of smooth surface, compact structure, fine and even crystal, good smoothness, no crack and excellent corrosion resistance.
Owner:CHINA UNIV OF GEOSCIENCES (WUHAN)

Novel cyanide-free silver plating electroplating liquid and electroplating technology

The invention provides novel cyanide-free silver plating electroplating liquid and an electroplating technology. The cyanide-free silver plating electroplating liquid comprises, by mass concentration, 1.5-4 g/L of silver nitrate, 2-50 g/L of potassium carbonate, 2-100 g/L of hydantoin, 0.1-100 g/L of potassium gluconate, 0.1-100 g/L of potassium malate, 0.1-150 g/L of citric acid, 0.1-280 g/L of hydantoin, 0.1-280 g/L of butynediol and 0.001-20 g/L of alkyl sulfonic acid surface active agent. The electroplating technology comprises the steps of pretreatment, washing, activating, washing, beforehand silver plating, silver plating, recycling, washing, adjusting treatment, washing, hot water washing (80 DEG C), washing and silver protective agent treatment. The novel silver plating technology has the main beneficial effects that firstly, the plating liquid is very stable and easy to control, the current efficiency of the plating liquid is high, and the dispersing capability and covering capability are good; secondly, a cyanide-free formula is adopted in the electroplating liquid, potential danger of cyanide is eliminated, and pollution to the environment is greatly reduced; and thirdly, the various properties of a plating layer are not lower than those of cyaniding silver plating, and a functional cyaniding silver plating technology can be thoroughly replaced.
Owner:CHONGQING LIDAO SURFACE TECH

Method for preparing cationic poly(urethane-dimethyldiallylammonium chloride) color fixing agent

The invention discloses a method for preparing a cationic poly(urethane-dimethyldiallylammonium chloride) color fixing agent, which comprises: synthesizing vinyl terminated cationic polyurethane prepolymer by using isocyanate, polyol, N-methyldiethanolamine and acrylate functional monomers as polymerization monomers; hydrating and dispersing the vinyl terminated cationic polyurethane prepolymer, and performing reversed emulsion polymerization of the vinyl terminated cationic polyurethane prepolymer and dimethyl diallyl ammonium chloride in a water soluble initiator to obtain the formaldehyde-free poly(urethane-dimethyldiallylammonium chloride) color fixing agent. The cationic poly(urethane-dimethyldiallylammonium chloride) color fixing agent contains no formaldehyde, retains the property of a polyurethane material, realizes the organic combination of the high performance of the two kinds of resins due to the high positive charge density of a poly(dimethyl diallyl ammonium chloride) chain segment and can effectively improve the color fastness of the dyed fabrics. When the color fixing agent is used, the color fastness of the fabrics dyed with direct dye and active dye is as follows: the dry friction fastness is grade 5, the wet friction fastness is grade 3 to 4, and the brushing fastness is 4 to 5.
Owner:ANHUI UNIVERSITY

Method for preparing nano-silver antibacterial agent by utilizing microcapsule embedding technology

The invention discloses a method for preparing a nano-silver antibacterial agent by utilizing a microcapsule embedding technology and application thereof. In the preparation method, an oily nano-silver material is used as the core material of the nano-silver microcapsule particle, and the beta-cyclodextrin is used as a wall material; and in the reaction process, the nano-silver microcapsules of a core-shell structure, an inlaid structure, a shell-core structure, a shell-core-shell structure and other structures are prepared by a conjugate ultrasonic method. A supercritical drying method is adopted in the drying process, the shrinkage and collapse of the microcapsule in the drying process are avoided, the problem of agglomeration during the nano-powder drying process is improved, and the performance of sustained release, lasting and color change resistance of the nano-silver microcapsule is improved. The prepared nano-silver particle can be independently used as an antibacterial liquid, or be compounded with a high molecular material to prepare various antibacterial materials such as antibacterial plastic, an antibacterial PVA (Polyvinyle Acetate) film and antibacterial rubber, or be compounded with natural or chemosynthetic textile fabrics to prepare antibacterial fabric, or be compounded with ceramics to prepare various antibacterial ceramics. The method disclosed by the invention is simple; and the prepared nano-silver has the characteristics of small particle size, good dispersity, sustained-release bacteriostasis, wide application and the like.
Owner:HUNAN UNIV OF TECH

Wood bamboo material corrosion and discoloration prevention triazole composition and preparation method thereof

The invention relates to a wood bamboo material corrosion and discoloration prevention triazole composition and a preparation method thereof. The preparation method comprises the following steps: preparing a triazole concentrate comprising 4.1-15.6wt% of a triazole compound, 33.6-67wt% of an ethanol and N,N-dimethyl formamide (DMF) combination, 20.7-26.5wt% of an amine oxide and quaternary ammonium salt combination or a calcium dodecyl benzene sulfonate and fatty alcohol polyoxyethylene ether (MOA-15) combination, and the balance of water, wherein the triazole compound is hexaconazole, cyproconazole, epoxiconazole, triadimenol, or a propiconazole/tebuconazole combination with the ratio of propiconazole/tebuconazole of 1:0.68-0.95; and adding parts of water to the triazole concentrate, adding 5-chloro-2-methyl-1-isothiazoline-3-one/2-methyl-1-isothiazoline-3-one (CMIT-MIT), and diluting the above obtained solution to obtain a triazole composition operating fluid. When the triazole composition operating fluid is used to carry out vacuum pressurizing treatment on a wood bamboo material, the wood bamboo material is dried until the water content of 20-25%, 5-9% low-molecular weight (the molecular weight is smaller than 1000) phenolic resin (PF) is used to carry out secondary vacuum pressurizing treatment, and the two-stage treated wood bamboo material has excellent corrosion, mildew and discoloration resistance and excellent triazole anti-loss performance after being dried.
Owner:INST OF WOOD INDUDTRY CHINESE ACAD OF FORESTRY

Normal-temperature alkaline chromium-free passivation solution and passivation method for aluminum alloy

The invention belongs to the technical field of surface treatment on metal materials, and discloses normal-temperature alkaline chromium-free passivation solution and a passivation method for aluminum alloy. PH (potential of hydrogen) of chromium-free passivation solution is regulated by the aid of acid-alkali regulators until the chromium-free passivation solution is alkaline; the chromium-free passivation solution comprises molybdate, complexing agents, oxidizing agents, film-forming accelerators, surfactants and water. The passivation method includes carrying out alkali washing on the aluminum alloy and removing oil and dirt from the aluminum alloy; cleaning the aluminum alloy, then carrying out acid washing on the aluminum alloy and activating the aluminum alloy; cleaning the aluminum alloy, carrying out normal-temperature passivation treatment on the aluminum alloy, washing the aluminum alloy by the aid of water, drying the aluminum alloy by means of blowing or drying the aluminum alloy by the aid of ovens to obtain aluminum alloy passivation films. The normal-temperature alkaline chromium-free passivation solution and the passivation method have the advantages that the passivation films can grow fast and are excellent in discoloration resistance and corrosion resistance; various components of the normal-temperature alkaline chromium-free passivation solution are stable in chemical properties, accordingly, the normal-temperature alkaline chromium-free passivation solution is convenient to store and transport, low in cost and high in efficiency, processes are easy and convenient to implement, the aluminum alloy can be treated at the normal temperature, energy can be saved, and industrialization is easy to implement.
Owner:SOUTH CHINA UNIV OF TECH

Preparation method of nano-grade layered silver-carrying-amino acid complex antibacterial agent

InactiveCN102599164BImprove stabilitySolve technical problems that are prone to discolorationBiocideDisinfectantsSalt resistanceWater baths
The invention discloses a preparation method of a nano-grade layered silver-carrying-amino acid complex antibacterial agent. The method comprises the steps that: (1) silver salt, amino acid, and water are mixed according to a molar ratio of 1:1:2.7; the mixture is stirred for 30min under room temperature, and is stirred for 15min in a water bath with a temperature of 50 DEG C, wherein a stirring speed is 800r / min, such that a solution is prepared; (2) under a condition with a 50 DEG C water bath and a stirring speed of 800r / min, montmorillonite is added to the solution, and the mixture is stirred overnight under a hydro-thermal condition with a temperature of 50 DEG C, such that a material liquid is obtained; (3) solid-liquid separation is carried out; an obtained solid is dried under room temperature, such that a finished product antibacterial agent powder is obtained. The nano-grade layered silver-carrying-amino acid complex antibacterial agent is milk-white fluffy powder with excellent anti-tarnishing performance. With the method, the releasing-retardance and salt resistance of the antibacterial agent are improved. The antibacterial agent has a silver load of 18%. The antibacterial activity of the antibacterial agent is greatly improved. The method is suitable to be used in the technical field of chemical functional materials.
Owner:XIAN UNVERSITY OF ARTS & SCI

Alkaline cyanide-free silver plating electroplating liquid and silver plating method

The invention relates to alkaline cyanide-free silver plating electroplating liquid and a silver plating method. The electroplating liquid is composed of the following components including 20 g/L-50 g/L of silver nitrate, 40 g/L-100 g/L of 5,5-dimethyl hydantoin, 70 g/L-100 g/L of potassium pyrophosphate, 0.8 g/L-1.2 g/L of 3,3'-dithiobis-1-propanesulfonic acid disodium salt, 0.10 g/L-0.15 g/L of benzotriazole, 10 mg/L-15 mg/L of N,N'-bi-oleoyl-Ethylenediamine-Sodium Diethyl sulfonate, 0.10 g/L-0.30 g/L of polyethylene glycol and the balance water, wherein due to a pH adjusting agent, the pH value of the system ranges from 8 to 12. By means of the alkaline cyanide-free silver plating electroplating liquid, all the components are matched and work collaboratively, stability is good, the copper replacement resisting performance is high, and the scattering capability of the plating liquid is high; crystal grains of a silver plated layer are fine, the crystal grains are densely and neatly arranged, the surface is flat and bright, glossiness is good, and the color changing resisting capability is high; and the hardness of the plated layer is high, the combining force with a base body is high, and the alkaline cyanide-free silver plating electroplating liquid is suitable for application and popularization.
Owner:佛山市南博旺环保科技有限公司

Composite galvanized army green steel pipe for refrigeration and manufacturing method of composite galvanized army green steel pipe

The invention discloses a composite galvanized army green steel pipe for refrigeration and a manufacturing method of the composite galvanized army green steel pipe. The composite galvanized army green steel pipe comprises a steel pipe positioned on the innermost layer and is characterized in that a zinc-iron alloy layer is arranged on the outer surface of the steel pipe; a pure zinc layer is arranged on the outer surface of the zinc-iron alloy layer; an army green passivation layer is arranged on the outer surface of the pure zinc layer; a first closing layer and a second closing layer are separately arranged outside the army green passivation layer; and a product is obtained by the steps of carrying out deoiling, thermal treatment, composite galvanization, preheating, burnishing, washing with water, colored passivation, drying, closing for two time and drying. The composite galvanized army green steel pipe has a good binding force; a passivation bonding force among layers is high and weather fastness of the passivation layer is high; a finished product of the steel pipe has excellent wear resistance; the composite galvanized army green steel pipe has the advantages of good bright line, smoothness, anti-tarnishing property, rigorous process and high stability of the finished product; and when a condenser and a dew removable tube are manufactured, a protective heat shrink tube does not need to be added, so the working procedure is simple.
Owner:ZHEJIANG KANGSHENG CO LTD
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