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A method for comprehensive utilization of vanadium-titanium magnetite by deep reduction short-process smelting

A vanadium-titanium magnetite and short-process technology, which is applied in the field of metallurgy, can solve the problems of low comprehensive resource utilization, high energy consumption in the smelting process, and strong dependence on coke, achieving significant economic benefits, alleviating the shortage of coke resources, and reducing production cost effect

Active Publication Date: 2020-11-17
NORTHEASTERN UNIV LIAONING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at the current technical problems such as low comprehensive utilization rate of vanadium-titanium magnetite resources, high energy consumption in the smelting process, strong dependence on coke, and heavy pollution, the present invention provides a method for comprehensive utilization of vanadium-titanium magnetite in deep reduction short-process smelting, using vanadium Titanium magnetite is used as raw material, preheating and pre-reduction in rotary kiln - deep reduction smelting in smelting furnace, to obtain high-quality vanadium-containing molten iron with a recovery rate of more than 90% for iron and vanadium

Method used

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  • A method for comprehensive utilization of vanadium-titanium magnetite by deep reduction short-process smelting

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Process such as figure 1 shown;

[0031] The main components of vanadium-titanium magnetite are: TFe 55.88%, FeO 13.03%, V 2 o 5 0.55%, TiO 2 9.28%, SiO 2 6.14%, Al 2 o 3 2.37%, CaO 1.08%, MgO 1.52%, P 0.13%, S<0.004%;

[0032] Crush the vanadium-titanium magnetite to a particle size of ≤15mm to make vanadium-titanium magnetite powder; crush the reducing agent to a particle size of ≤10mm to obtain a reducing agent powder; crush the solvent limestone to a particle size of ≤20mm to obtain limestone powder ; The reducing agent is blue carbon; the mass percentage of fixed carbon in the reducing agent is ≥ 80%; the mass percentage of calcium oxide in limestone is ≥ 40%;

[0033] Mix vanadium-titanium magnetite powder, reducing agent powder and limestone powder evenly to make mixed powder; in the mixed powder, the mass ratio of vanadium-titanium magnetite powder and reducing agent powder is 1:0.34, vanadium-titanium magnetite powder The mass ratio with limestone po...

Embodiment 2

[0041] Method is with embodiment 1, and difference is:

[0042] (1) The main components of vanadium-titanium magnetite are: TFe 62.77%, FeO 10.03%, V 2 o 5 0.87%, TiO 2 6.24%, SiO 2 2.14%, Al 2 o 3 1.20%, CaO 2.12%, MgO 1.02%, P 0.13%, S<0.004%;

[0043] (2) In the mixed powder, the mass ratio of vanadium-titanium magnetite ore powder and reducing agent powder is 1:0.5, and the mass ratio of vanadium-titanium magnetite ore powder and limestone powder is 1:0.3; Reductant is anthracite;

[0044] (3) The mixed powder is discharged after staying in the rotary kiln for 40 minutes to obtain a preheated pre-reduced material with a temperature of 870° C.; the iron metallization rate in the discharged pre-reduced material is 70%;

[0045] (4) The injection rate of pulverized coal is 0.7 times of the total mass of vanadium-titanium-magnetite powder;

[0046] (5) In the process of deep reduction and smelting, the temperature in the melting furnace is controlled at 1400°C, the res...

Embodiment 3

[0049] Method is with embodiment 1, and difference is:

[0050] (1) The main components of vanadium-titanium magnetite are: TFe 47.76%, FeO 9.81%, V 2 o 5 1.47%, TiO 2 20.01%, SiO 2 4.17%, Al 2 o 3 3.35%, CaO 1.08%, MgO 1.52%, P 0.13%, S<0.004%;

[0051] (2) In the mixed powder, the mass ratio of vanadium-titanium magnetite ore powder and reducing agent powder is 1:0.3, and the mass ratio of vanadium-titanium magnetite ore powder and limestone powder is 1:0.26; Reductant is anthracite;

[0052] (3) The mixed powder is discharged after staying in the rotary kiln for 25 minutes to obtain a preheated pre-reduced material with a temperature of 650° C., and the iron metallization rate in the reduced material is 40%;

[0053] (4) The injection amount of pulverized coal is 0.6 times of the total mass of vanadium-titanium-magnetite powder;

[0054] (5) In the process of deep reduction and smelting, the temperature in the melting furnace is controlled at 1700°C, the residence...

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Abstract

A method for comprehensive utilization of vanadium-titanium magnetite through deep reduction and short-flow smelting, which is carried out according to the following steps: (1) crush vanadium-titanium magnetite to make vanadium-titanium magnetite powder; crush the reducing agent to obtain reducing agent powder; solvent Limestone crushing limestone powder; (2) Mix vanadium titanium magnetite powder, reducing agent powder and limestone powder evenly to make a mixed powder; (3) Place it in a rotary kiln and use reducing fumes with a temperature of 1000 to 1500°C. Gas preheating and prereduction; (4) Preheating and prereduction materials directly enter the smelting furnace connected to the rotary kiln, and the melt is deeply reduced. The vanadium-containing molten iron and slag phases are released from the smelting furnace respectively. The method of the invention realizes efficient utilization of valuable elements in vanadium titanium magnetite and can greatly reduce costs.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, in particular to a method for comprehensive utilization of vanadium-titanium magnetite by deep reduction short-flow smelting. Background technique [0002] Vanadium-titanium magnetite is an iron ore resource with iron, vanadium, and titanium as the main valuable elements. It has abundant resource reserves and high comprehensive utilization value. The resource reserves of vanadium-titanium magnetite in my country alone exceed 9.8 billion tons, and Vanadium resources are mainly produced in rock-type vanadium-titanium magnetite deposits in the form of associated ore. If the resources of vanadium-titanium magnetite can be efficiently and comprehensively utilized, huge social and economic benefits will be produced; at present, the blast furnace method is mainly used to utilize vanadium in the world. Titanium-magnetite resources, blast furnace technology is mature, easy to operate, and large-scale pro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21B13/14
CPCC21B13/14
Inventor 孙永升韩跃新王勋李艳军余建文
Owner NORTHEASTERN UNIV LIAONING