Essential oil carrying cationic polymer modified porous silicon dioxide material and preparation method and application thereof
A technology of porous silica and mesoporous silica, applied in the fields of botanical equipment and methods, chemical instruments and methods, and applications, can solve the problems of insufficient release control force and hinder the slow release of essential oils, so as to improve the slow and slow release of essential oils. release and antibacterial properties, sustained antibacterial effect, thermal stability improvement effect
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Embodiment 1
[0038] An embodiment of the cationic polymer-modified porous silica material loaded with essential oil of the present invention, the polyethyleneimine (PEI) modified mesoporous silica material loaded with tea tree essential oil (TTO) of this embodiment The preparation method comprises the following steps:
[0039] (1) Add 1.5g CTAB, 105mL ammonia water (25wt%), and 150mL deionized water into a round bottom flask, dissolve completely at 60°C, stir magnetically at 250r / min for 1h; then add 7.5g TEOS dropwise Put it into a round bottom flask, stir for 6 hours, crystallize at 33°C for 24 hours, wash, filter, dry, and calcinate at 550°C for 5 hours to obtain MCM-41 powder;
[0040](2) Add 0.5g MCM-41 and 10mL tea tree essential oil into a beaker, oscillate ultrasonically for 20 minutes, filter, and dry at room temperature to obtain TTO / MCM-41;
[0041] (3) Add 0.5g TTO / MCM-41 and 125mL deionized water into a round bottom flask, disperse uniformly by ultrasonic for 5min, stir magne...
Embodiment 2
[0058] An embodiment of the cationic polymer-modified porous silica material loaded with essential oil of the present invention, the preparation method of the polyethyleneimine-modified mesoporous silica material loaded with tea tree essential oil in this embodiment comprises the following step:
[0059] (1) Add 1g of P123, 100mL of ammonia water (25wt%), and 100mL of deionized water into a round bottom flask, dissolve completely at 60°C, and stir magnetically at a speed of 250r / min for 1h; then add 2.5g of TEOS dropwise into In a round bottom flask, after stirring for 3 hours, crystallize at a constant temperature of 33°C for 12 hours, wash, filter with suction, dry, and calcinate at 550°C for 5 hours to obtain SBA-15 powder;
[0060] (2) Add 0.1g SBA-15 and 0.1mL tea tree essential oil into a beaker, oscillate ultrasonically for 20min, filter, and dry at room temperature to obtain TTO / SBA-15;
[0061] (3) Add 0.1g TTO / SBA-15 and 125mL deionized water into a round bottom fla...
Embodiment 3
[0065] An embodiment of the cationic polymer-modified porous silica material loaded with essential oil of the present invention, the preparation method of the polyurethane (PU) modified mesoporous silica material loaded with eucalyptus essential oil (ETO) in this embodiment , including the following steps:
[0066] (1) Add 3g of P123, 200mL of ammonia water (25wt%) and 200mL of deionized water into a round bottom flask, dissolve completely at 60°C, and stir magnetically at a speed of 250r / min for 1h; then add 8g of TEOS dropwise into the round bottom flask In a bottom flask, after stirring for 6 hours, crystallize at a constant temperature of 33°C for 24 hours, wash, filter with suction, dry, and calcinate at 550°C for 5 hours to obtain SBA-15 powder;
[0067] (2) Add 0.5g of SBA-15 and 10mL of eucalyptus essential oil into a beaker, ultrasonically shake for 20min, filter, and dry at room temperature to obtain ETO / SBA-15;
[0068] (3) Add 0.5g of ETO / SBA-15 and 125mL of deion...
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