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Concentration method of copper-containing wastewater from production process of printed circuit boards

A technology for printed circuit boards and production processes, applied in chemical instruments and methods, water pollutants, water treatment parameter control, etc. High copper recovery rate and cost saving effect

Inactive Publication Date: 2019-08-20
埃姆媞(无锡)分离技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, a large amount of copper-containing wastewater will be produced in the PCB production process, and the water quality is complex. The main pollutants in the wastewater include: acid and alkali, suspended solids, copper, nickel, ammonia nitrogen, and comprehensive agent NH 4 OH, EDTA and other organic substances are harmful to the environment; and PCB copper-containing wastewater has a large amount of water, which leads to problems in actual engineering that are difficult to deal with and high in treatment costs, thus limiting the development of components in the electronic industry
Using traditional chemical precipitation method, ion exchange method, chemical oxidation method, activated carbon adsorption and other methods to treat PCB copper-containing wastewater, it is difficult to meet the total copper discharge standard of effluent, and the treatment cost is high, and secondary pollution is easy to occur.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Embodiment 1 proposes a method for concentrating copper-containing wastewater in the production process of printed circuit boards, comprising the steps of:

[0016] (1) Pass copper-containing waste water from the production process of printed circuit boards into the raw water tank of the separation equipment, and then start the cooling cycle of the separation equipment. Concentrate through a primary separation membrane under MPa to obtain the first concentrated solution and the first dialyzate, then pass the first concentrated liquid into the raw water tank for recovery, and pass the first dialyzate into the into the collection box, and then take the first permeate and the first concentrate of different concentration times for analysis and detection, and record the operating temperature, time, first permeate flow and first concentrate flow of the separation device at the same time, And detect the copper ion content, COD content and ammonia nitrogen content in the water ...

Embodiment 2

[0019] Embodiment 2 proposes a method for concentrating copper-containing wastewater in the production process of printed circuit boards. The components of PCB copper-containing wastewater are as follows: copper content 250 mg / L, pH 2.94, COD value 1083 mg / L, ammonia nitrogen content 412.8 mg / L, With a conductivity of 9892us / cm, the copper-containing wastewater is added to the 2540 special separation equipment for concentration treatment of the first-level MagicSep special separation membrane. The concentrated liquid is recovered as a product, and the permeate from the primary membrane enters the secondary purification; the permeate from the secondary MagicSep special separation membrane is discharged, and the secondary concentrated liquid is mixed with the raw liquid into the primary membrane.

[0020] During operation, record the sampling time, temperature of feed liquid, flow rate of raw liquid, permeate and concentrated liquid, etc., and detect copper ion content, COD conte...

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Abstract

The invention relates to a concentration method of copper-containing wastewater from the production process of printed circuit boards, comprising the following steps: copper-containing wastewater fromthe production process of printed circuit boards is introduced into a raw water tank of separation equipment, and undergoes concentration treatment through a first-stage separation membrane so as toobtain a first concentrate and a first dialysate; then, the first concentrate is introduced into the raw water tank to be recycled, and the first dialysate is introduced into a collecting box; the first dialysate undergoes concentration treatment through a second-stage separation membrane so as to obtain a second concentrate and a second dialysate; and finally, the second concentrate is introducedinto the raw water tank to be recycled, and the second dialysate is discharged. By the concentration method of copper-containing wastewater from the production process of printed circuit boards, useof extractants, etc. is reduced, discharge of pollutants is decreased, copper recovery rate is high, and recycled acid can be repeatedly used or emission-free. The method of the invention is energy-saving, low-consuming and cost-saving.

Description

technical field [0001] The invention relates to a method for concentrating copper-containing wastewater in the production process of printed circuit boards. Background technique [0002] With the rapid development of the electronics industry, the current printed circuit board (PCB) market has greatly increased, and the production of printed circuit boards has become an important basic industry in the electronics industry. However, a large amount of copper-containing wastewater will be produced in the PCB production process, and the water quality is complex. The main pollutants in the wastewater include: acid and alkali, suspended solids, copper, nickel, ammonia nitrogen, and comprehensive agent NH 4 OH, EDTA and other organic substances are harmful to the environment; and PCB copper-containing wastewater has a large amount of water, which leads to difficult and high processing costs in actual engineering, thus limiting the development of components in the electronic industry...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/44C02F101/16C02F101/20
CPCC02F1/44C02F2101/16C02F2101/20C02F2209/08
Inventor 姜艳
Owner 埃姆媞(无锡)分离技术有限公司
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