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Chlorinated paraffin ultraviolet absorber

A chlorinated paraffin and ultraviolet technology, which is applied in the field of chlorinated paraffin ultraviolet absorbers, can solve the problems of affecting the anti-ultraviolet effect, difficult dispersion of nano-materials, limited absorption range and absorption capacity, etc., to achieve excellent ultraviolet absorption range and improve ultraviolet absorption Ability, the effect of excellent absorbency

Active Publication Date: 2019-10-11
ANHUI XINGXIN CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, single-component inorganic nanomaterials have limited absorption range and ability to absorb ultraviolet rays, and nanomaterials are not easily dispersed in chlorinated paraffin, which affects their anti-ultraviolet effect.

Method used

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  • Chlorinated paraffin ultraviolet absorber
  • Chlorinated paraffin ultraviolet absorber

Examples

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Effect test

Embodiment 1

[0022] A chlorinated paraffin ultraviolet absorber, its raw materials include modified ZnO@Ag core-shell nanomaterials, modified nano TiO 2 , in which modified ZnO@Ag core-shell nanomaterials, modified nano-TiO 2 The weight ratio is 10:60.

[0023] The modified ZnO@Ag core-shell nanomaterial is obtained by mixing simethicone oil and ZnO@Ag core-shell nanomaterial at a weight ratio of 1:100 and then oscillating evenly at room temperature. Among them, the preparation method of ZnO@Ag core-shell nanomaterials is as follows: mix nano-ZnO with an average particle size of 35nm and ammonium oxalate solution with a mass fraction of 0.5% at a weight ratio of 0.4:10 and disperse evenly, then slowly add the equivalent of nano The mass fraction of 5 times of ZnO weight is 0.1% silver nitrate solution, stirred and reacted for 2h at 60°C, centrifuged, washed and dried, then placed in a mixed solution of ethylene glycol and hexanaphthene equivalent to 10 times of the weight of nanometer ZnO...

Embodiment 2

[0026] A chlorinated paraffin ultraviolet absorber, its raw materials include modified ZnO@Ag core-shell nanomaterials, modified nano TiO 2 , in which modified ZnO@Ag core-shell nanomaterials, modified nano-TiO 2 The weight ratio is 40:90.

[0027] The modified ZnO@Ag core-shell nanomaterial is obtained by mixing simethicone oil and ZnO@Ag core-shell nanomaterial at a weight ratio of 1.5:100 and then shaking uniformly at room temperature. Among them, the preparation method of ZnO@Ag core-shell nanomaterials is as follows: mix nano-ZnO with an average particle size of 50nm and ammonium oxalate solution with a mass fraction of 0.5% at a weight ratio of 0.4:10 and disperse evenly, and then slowly add the equivalent of nano The mass fraction of 5 times of ZnO weight is 0.1% silver nitrate solution, stirred and reacted for 2h at 60°C, centrifuged, washed and dried, then placed in a mixed solution of ethylene glycol and hexanaphthene equivalent to 10 times of the weight of nanomete...

Embodiment 3

[0030] A chlorinated paraffin ultraviolet absorber, its raw materials include modified ZnO@Ag core-shell nanomaterials, modified nano TiO 2 , in which modified ZnO@Ag core-shell nanomaterials, modified nano-TiO 2 The weight ratio is 10:60.

[0031] The raw material also includes 1% modified nano hydrotalcite accounting for the total weight of the raw material.

[0032] The modified ZnO@Ag core-shell nanomaterial is obtained by mixing simethicone oil and ZnO@Ag core-shell nanomaterial at a weight ratio of 1:100 and then oscillating evenly at room temperature. Among them, the preparation method of ZnO@Ag core-shell nanomaterials is as follows: mix nano-ZnO with an average particle size of 35nm and ammonium oxalate solution with a mass fraction of 0.5% at a weight ratio of 0.4:10 and disperse evenly, then slowly add the equivalent of nano The mass fraction of 5 times of ZnO weight is 0.1% silver nitrate solution, stirred and reacted for 2h at 60°C, centrifuged, washed and dried, ...

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Abstract

The invention discloses a chlorinated paraffin ultraviolet absorber which is prepared from raw materials including a modified ZnO@Ag core-shell nano material, modified nano TiO2 and a modified hydrotalcite-mesoporous SiO2 nano composite material. The weight ratio of the modified ZnO@Ag core-shell nano material to the modified nano TiO2 to the modified hydrotalcite-mesoporous SiO2 nano composite material is (10-40) to (60-90) to (1-2). The chlorinated paraffin ultraviolet absorber has high-efficiency ultraviolet absorption capacity, can be stably dispersed in chlorinated paraffin, and effectively improves the long-acting ultraviolet aging resistance of the chlorinated paraffin.

Description

technical field [0001] The invention relates to the technical field of ultraviolet absorbers, in particular to a chlorinated paraffin ultraviolet absorber Background technique [0002] Chlorinated paraffin is a light yellow viscous liquid. It is a chlorinated product of normal alkanes. It has the advantages of non-toxic, odorless, flame retardant, chemical corrosion resistance, and low volatility. It is mainly used as a plasticizer for PVC, and Additives for synthetic rubber, coatings, inks and mechanical lubricants, etc., have a wide range of applications. Chlorinated paraffin is sensitive to sunlight and easily absorbs the energy of ultraviolet light, so that the unstable chlorine atoms in its structure and the adjacent hydrogen atoms are detached from the carbon chain at the same time, releasing hydrogen chloride, which can further promote the decomposition of chlorinated paraffin. Therefore, chlorinated paraffin is very easy to change color under sunlight, which affects...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L91/06C08K3/22C08K3/08C08K7/26C08K9/06C08K9/04C08K9/12
CPCC08K3/08C08K3/22C08K7/26C08K9/04C08K9/06C08K9/12C08K2003/0806C08K2003/2241C08K2003/2296C08K2201/003C08K2201/011C08L2201/08C08L91/06
Inventor 王西弱刘岗王中立王文本王西宇
Owner ANHUI XINGXIN CHEM TECH