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A kind of emulsified asphalt for degrading waste gas

A technology of emulsified asphalt and exhaust gas, which is applied in the processing of tar pitch/petroleum pitch/natural asphalt, chemical instruments and methods, chemical/physical processes, etc. It can solve problems such as low catalytic efficiency, neglect of exhaust gas, and insufficient utilization of titanium dioxide. Achieve the effect of saving cost and fully purifying exhaust gas

Active Publication Date: 2020-09-08
HUNAN COMM POLYTECHNIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the following technical problems exist in the above-mentioned prior art: (1) titanium dioxide is a photocatalyst, and after mixing with asphalt, most of the titanium dioxide is in the bulk phase of the pitch, and only part of the titanium dioxide is exposed on the surface, which leads to insufficient utilization of the titanium dioxide ; (2) Although titanium dioxide is a photocatalytic material, for ordinary titanium dioxide, ultraviolet light is usually required to excite it for photocatalysis, which leads to low catalytic efficiency of titanium dioxide under visible light; (3) The focus of most researches It lies in the removal of automobile exhaust. However, asphalt pavement also produces volatile gases in special circumstances such as summer. While paying attention to the purification of automobile exhaust, the exhaust gas produced by pavement materials is ignored, resulting in the inability to coordinate governance
[0003] Regarding the above technical problems, although it is possible to spray a liquid containing titanium dioxide on the road surface to make it act on the asphalt surface to improve the utilization rate of the photocatalyst, and to modify the titanium dioxide to achieve photocatalysis under visible light, none of the above methods can Better response to asphalt volatilized gas

Method used

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  • A kind of emulsified asphalt for degrading waste gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Disperse 5g of the modified catalyst and 5g of the slow-release capsules in 10g of water to obtain an additive mixture;

[0026] Add the additive mixture to 80g of basic emulsified asphalt (solid content 60%), and mix evenly to obtain emulsified asphalt for degrading waste gas;

[0027] Among them, 85g molecular sieve (MCM-41) is impregnated in the dispersion containing 10g (calculated as titanium dioxide) titanium tetrachloride, 1g (calculated as ferric oxide) ferric chloride and stirred for 30min, adding sodium hydroxide to make the dispersion When the pH value reaches 12, continue stirring for 1 hour, filter, dry at 100° C. for 3 hours, and air calcinate at 550° C. for 3 hours to obtain the first catalyst. The first catalyst is immersed in a dispersion containing 4 g (calculated as manganese dioxide) of manganese acetate. After impregnation, filter, dry at 100°C for 3 hours, and air calcinate at 550°C for 3 hours to obtain the modified catalyst.

[0028] Among them,...

Embodiment 2

[0030] Disperse 10g of the modified catalyst and 1g of the sustained-release capsule in 15g of water to obtain an additive mixture;

[0031] Add the additive mixture to 74g of basic emulsified asphalt (solid content 60%), and mix evenly to obtain emulsified asphalt for degrading waste gas;

[0032] Among them, 73g molecular sieve (MCM-41) was impregnated in the dispersion containing 20g (calculated as titanium dioxide) titanium tetrachloride, 4g (calculated as ferric oxide) ferric chloride and stirred for 30min, adding sodium hydroxide to make the dispersion When the pH value reaches 12, continue stirring for 1 hour, filter, dry at 100° C. for 3 hours, and air calcinate at 550° C. for 3 hours to obtain the first catalyst. The first catalyst is immersed in a dispersion containing 3 g (calculated as manganese dioxide) of manganese acetate. After impregnation, filter, dry at 100°C for 3 hours, and air calcinate at 550°C for 3 hours to obtain the modified catalyst.

[0033] Among...

Embodiment 3

[0035] Disperse 1g of the modified catalyst and 10g of sustained-release capsules in 20g of water to obtain an additive mixture;

[0036] Add the additive mixture to 69g of basic emulsified asphalt (70% solid content), and mix evenly to obtain emulsified asphalt for degrading waste gas;

[0037] Among them, 84.5g molecular sieve (MCM-41) was impregnated in the dispersion containing 5g (calculated as titanium dioxide) titanium tetrachloride, 0.5g (calculated as ferric oxide) ferric chloride and stirred for 30min, adding sodium hydroxide to make When the pH value of the dispersion reaches 12, continue stirring for 1 hour, filter, dry at 100°C for 3 hours, and air calcinate at 550°C for 3 hours to obtain the first catalyst. , impregnated, filtered, dried at 100°C for 3h, and air calcined at 550°C for 3h to obtain the modified catalyst.

[0038]Among them, 15g of sodium alginate was dissolved in 1L of 10% hydrogen peroxide solution to obtain a mixed solution, and the mixed soluti...

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PUM

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Abstract

The invention discloses emulsified asphalt capable of degrading exhaust gas. The emulsified asphalt capable of degrading the exhaust gas is obtained by dispersing a modification catalyst and a sustained release capsule in water to obtain an additive mixed solution, and adding the additive mixed solution to base emulsified asphalt for uniform mixing. By the adding of the catalyst with specific components and the sustained release capsule capable of slowly releasing an oxidant, an effect that one catalyst can purify exhaust gas of automobiles and volatile gas of the asphalt. The catalyst can beused as a photocatalyst on the surface of the asphalt, and can also be used as an oxidation catalyst in an asphalt bulk phase, thus reducing the catalyst cost and achieving synergistic removal of theexhaust gas.

Description

technical field [0001] The present application relates to an emulsified asphalt for degrading waste gas, in particular to an emulsified asphalt capable of reducing vehicle exhaust and volatile gas of the asphalt itself. Background technique [0002] With the rapid development of the national economy, the number of automobiles in my country continues to increase, and the emission of automobile exhaust is becoming more and more serious, making air pollution a social problem that the public focuses on. For this reason, many technologies for purifying automobile exhaust have emerged as the times require. Among them, adding photocatalysts to pavement materials to remove automobile exhaust has attracted widespread attention. For example, many studies such as Chinese patents CN1482178A, CN1970639A, CN103252225A, CN103102700A have disclosed that titanium dioxide is added to asphalt materials to make it contact with automobile exhaust to purify the harmful gas. However, the followi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/94
CPCB01D53/007B01D53/02B01D53/72B01D53/94B01J23/34B01J35/004C10C3/00
Inventor 陈小薇胡贵华杨侣珍
Owner HUNAN COMM POLYTECHNIC
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