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Method for improving capacity of cornstalk carbon-based super-electric material by using ammonium salt

A technology of corn stalk carbon and electric materials, which is applied in the manufacture of hybrid capacitor electrodes and hybrid/electric double layer capacitors, etc., achieves the effects of low temperature, simple operation and high output

Active Publication Date: 2019-10-29
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The key is to prepare it as an advanced and efficient energy storage material. However, plant carbon materials contain a large amount of non-conductive materials, which limits their wide application as electrode materials in the energy field. It is urgent to find a simple and effective method to remove these non-conductive materials. It can be effectively applied in lithium batteries and supercapacitors to meet the needs of advanced and efficient energy storage materials in the rural science and technology agriculture policy and in the energy field

Method used

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  • Method for improving capacity of cornstalk carbon-based super-electric material by using ammonium salt
  • Method for improving capacity of cornstalk carbon-based super-electric material by using ammonium salt
  • Method for improving capacity of cornstalk carbon-based super-electric material by using ammonium salt

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The method for improving the capacity of corn stalk carbon-based superelectric materials by using ammonium salts comprises the following steps:

[0042] (1) Pretreatment: Cut 1g of straw into sections, add 0.1g of ammonium chloride, add 25ml of pure water to the container, then place the container in an autoclave and seal it, then conduct a hydrothermal reaction at 120°C, and then remove it by suction filtration Get a sample. Dry in a drying oven (60° C.) for 24 hours to obtain the product carbon;

[0043] (2) Roasting and carbonization: put the product carbon in (1) directly in a tube furnace, under the protection of nitrogen atmosphere, the heating rate is 5°C / min, rise to 1000°C, hold for 2h, and carbonize;

[0044] (3) Coating: Weigh the carbonized material in (2) and mix and grind the polytetrafluoroethylene according to the commercial mass ratio (80:10:10), so that it is crushed into smaller particles, and the ground Add isopropanol to the medicine to dissolve i...

Embodiment 2

[0047] The difference between this embodiment and embodiment 1 is that the quality of the stalk in step (1) is 5g, and the rest is the same as embodiment 1.

Embodiment 3

[0049] The difference between this embodiment and embodiment 1 is that ammonium fluoride is added in step (1), and the rest are the same as embodiment 1.

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Abstract

The invention belongs to the technical field of energy materials, and particularly relates to a method for improving the capacity of a cornstalk carbon-based super-electric material by using ammoniumsalt. The method provided by the invention comprises the steps that (1) pretreatment: a straw is cut, added with ammonium salt and pure water, sealed in an autoclave, and then subjected to hydrothermal reaction to acquire a preliminary product; suction filtration is carried out to acquire a sample; sample is dried in a dry box to acquire product carbon; (2) calcination carbonization: the product carbon in (1) is placed in a tube furnace, and heating, heat preservation, carbonizing are carried out under gas protection to acquire a carbonized sample; (3) coating: the carbonized sample is weighedand mixed and ground with polytetrafluoroethylene until the carbonized sample is pulverized into tiny particles; isopropanol is added into the ground material to dissolve the material; the material is evenly coated on clean carbon cloth; and (4) electrochemistry performance testing is carried out. The method provided by the invention has the advantages of simple operation, recyclability, being non-poisonous to the environment, low required temperature, high output and high commercial application value, and is free of complicated and expensive instruments and equipment.

Description

technical field [0001] The invention belongs to the technical field of energy materials, and in particular relates to a method for removing carbon and calcium impurities in corn stalks by using ammonium salts so as to increase the capacity of corn stalk carbon-based superelectric materials. Background technique [0002] The new supercapacitor has the characteristics of higher energy density and more environmental protection and safety, and it has gradually come into people's sight. Most of its negative electrode materials are carbon electrode materials. However, mineral carbon resources are decreasing day by day, requiring us to find better carbon sources to replace traditional carbon materials, as natural polymers, biomass is an excellent carbon precursor in terms of sustainability, cost and performance [4] , abundant, easy-to-obtain and low-cost renewable biomass resources have therefore become a research hotspot in the field of energy. The key is to prepare it as an adva...

Claims

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Application Information

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IPC IPC(8): H01G11/32H01G11/34H01G11/44H01G11/86
CPCH01G11/32H01G11/34H01G11/44H01G11/86Y02E60/13
Inventor 赵刚徐锡金赵宏程艳玲郝树华马文萱王小珂
Owner UNIV OF JINAN
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