Core-shell structure casting tungsten carbide particle welding wire and preparation method thereof
A technology of tungsten carbide particles and casting tungsten carbide, applied in welding equipment, welding media, manufacturing tools, etc., can solve the problems affecting the wear resistance of the surfacing layer, poor high temperature oxidation resistance, serious particle decomposition, etc. Good performance, good wear resistance and low cost of raw materials
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[0031] A preparation process for casting tungsten carbide particle welding wire with a core-shell structure, comprising the following steps:
[0032] 1) The main component of cast tungsten carbide is WC / W 2 C p , the cast tungsten carbide particles are subjected to the surface carburizing process, the cast tungsten carbide, alloy powder, mechanical binder and carbon black are mixed, heated to 1500-1900°C under vacuum, kept for 2-3 hours, and modified to form a core-shell structure , after modification, a single-layer sintered tungsten carbide shell will be formed outside the cast tungsten carbide particles, with an average thickness of 3-12 μm, and a core-shell structure cast tungsten carbide particle welding core will be obtained;
[0033] 2) In step 1), the core-shell structure cast tungsten carbide particle welding core is covered with seam coating or seamless coating, and the welding wire skin is prepared by drawing or extrusion, and the final diameter range is 1.0~ 2.0m...
Embodiment 1
[0037] The outer skin is made of copper alloy, and the composition of the drug core is: cast tungsten carbide particles, according to the particle size, the proportion is 50-80 mesh, accounting for 30%, and the proportion of 80-200 mesh is 70%. The cast tungsten carbide accounts for 70%, the mixture of ferromanganese powder, nickel powder, niobium powder and silicon iron powder accounts for 28%, organic resin accounts for 2%, and the flux core accounts for 70-80% by weight of the welding wire. Among them, the effect is the best when spherical nickel powder is used as the binder. The result of the three-body wear test of SiC particles in this embodiment shows that the wear resistance of the clad wear-resistant layer is 30-40% higher than that of the existing similar welding wire.
Embodiment 2
[0039] The outer skin is made of cobalt alloy, and the composition of the drug core is: cast tungsten carbide particles, according to the particle size, the proportion is 35% for 50-80 mesh, and 65% for 80-200 mesh. The cast tungsten carbide accounted for 80%, the mixture of ferromanganese powder, nickel powder, niobium powder and silicon iron powder was 19%, and organic resin was 1%. ~80%. Among them, the effect is the best when spherical nickel powder is used as the binder. The result of the three-body wear test of SiC particles in this embodiment shows that the wear resistance of the clad wear-resistant layer is 10-30% higher than that of the existing similar welding wire.
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