Novel compound and applications thereof, and organic electroluminescent device using compound

A technology of organic compounds and general formula compounds, which is applied in the field of new compounds, can solve problems such as unresolved lifespan problems of blue light materials, large singlet and triplet state energy ranges, device efficiency roll-off, etc., to achieve reduced vibration relaxation and low start-up The effect of voltage and optimal service life

Active Publication Date: 2019-11-05
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In the selection of OLED materials, singlet light-emitting fluorescent materials have a long life and low price, but low efficiency; triplet light-emitting phosphorescent materials have high efficiency, but are expensive, and the life of blue light materials has not been solved.
[0005] In the prior art, the "multiple resonance-induced thermally activated delayed fluorescence (MR-TADF)" strategy is used to design new structural compounds, such as patent applications CN107851724, CN108431984, etc., which design a single boron atom and nitrogen atom to combine multiple

Method used

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  • Novel compound and applications thereof, and organic electroluminescent device using compound
  • Novel compound and applications thereof, and organic electroluminescent device using compound
  • Novel compound and applications thereof, and organic electroluminescent device using compound

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preparation example Construction

[0122] Specifically, the preparation method of the organic electroluminescent device of the present invention comprises the following steps:

[0123] 1. Ultrasonically treat the glass plate coated with the anode material in a commercial cleaning agent, rinse in deionized water, ultrasonically degrease in acetone: ethanol mixed solvent, bake in a clean environment until the water is completely removed, and use ultraviolet light Light and ozone cleaning, and bombardment of the surface with a beam of low-energy cations;

[0124] 2. Put the above-mentioned glass plate with anode in the vacuum chamber, and evacuate to 1×10 -5 ~9×10 -3 Pa, vacuum evaporating a hole injection material on the anode layer film to form a hole injection layer, and the evaporation rate is 0.1-0.5nm / s;

[0125] 3. Vacuum evaporate the hole transport material on the hole injection layer to form the hole transport layer, the evaporation rate is 0.1-0.5nm / s,

[0126] 4. Vacuum-deposit the organic light-emi...

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Abstract

The present invention relates to a novel organic compound and applications thereof, and an organic electroluminescent device using the compound, wherein the compound has a structure represented by thefollowing formula defined in the specification, wherein Y<1>, Y<2> and Y<3> are respectively and independently selected from H and B, at most one of Y<1>, Y<2> and Y<3> is H, X<1>, X<2> and X<3> arerespectively and independently selected from N and H, at most one of X<1>, X<2> and X<3> is H, X<4>, X<5> and X<6> are respectively and independently selected from H, a single bond, O, S and CR, R<1>-R<18> are respectively and independently selected from hydrogen, deuterium, substituted or unsubstituted C1-C36 alkyl, substituted or unsubstituted C6-C48 monocyclic aromatic hydrocarbon or fused ringaromatic hydrocarbon, and substituted or unsubstituted C3-C48 monocyclic heteroaromatic hydrocarbon or fused ring heteroaromatic hydrocarbon, and the two adjacent groups in R<1>-R<18> can be bonded to form C1-C10 cycloalkane, C6-C30 aromatic hydrocarbon or C5-C30 heteroaromatic hydrocarbon. According to the present invention, with the application of the compound as the light emitting layer material in an OLED device, the compound exhibits excellent device performance and excellent stability. The present invention further discloses an organic electroluminescent device using the compound represented by the general formula.

Description

technical field [0001] The invention relates to a novel compound, application of the compound, and an organic light-emitting device using the compound. Background technique [0002] Organic electroluminescent devices (OLED: Organic Light Emission Diodes) are a type of device with a sandwich-like structure, including positive and negative electrode film layers and an organic functional material layer sandwiched between the electrode film layers. Due to the advantages of high brightness, fast response, wide viewing angle, simple process, and flexibility, OLED devices have attracted much attention in the field of new display technology and new lighting technology. At present, this technology has been widely used in the display panels of new lighting fixtures, smart phones and tablet computers, and will further expand to the application field of large-size display products such as TVs. It is a new type of display with fast development and high technical requirements. technology...

Claims

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Application Information

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IPC IPC(8): C07F5/02C09K11/06H01L51/50H01L51/54
CPCC07F5/02C09K11/06C09K2211/1007C09K2211/1014C09K2211/1029C09K2211/1033C09K2211/1037C09K2211/104H10K85/636H10K85/633H10K85/631H10K85/657H10K50/12H10K85/6572H10K50/11
Inventor 段炼张跃威张东东
Owner TSINGHUA UNIV
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