Smelting method of low-sulfur and low-boron steel

A smelting method and boron steel technology, applied in the field of metallurgy, can solve problems such as unsuitable production mode, increasing boron oxide reduction amount, unsuitable low iron consumption and increasing production mode, etc.

Inactive Publication Date: 2019-11-08
HUNAN VALIN XIANGTAN IRON & STEEL CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Chinese patent application numbers CN201711131983.2 and CN201711176053.9 disclose two smelting methods for low-boron steel, both of which adopt molten iron pretreatment for desulfurization until the sulfur content of molten iron entering the furnace is controlled within 0.01%, which greatly reduces the pressure of desulfurization after tapping from the converter "Return" B with molten s

Method used

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  • Smelting method of low-sulfur and low-boron steel
  • Smelting method of low-sulfur and low-boron steel
  • Smelting method of low-sulfur and low-boron steel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The new standard Q345qE steel with sulfur content S ≤ 0.003 and boron content B ≤ 0.0005 was smelted in 1 furnace. The composition of the steel is shown in Table 1.

[0026] The smelting process is "converter-LF furnace-RH furnace-CC", and the specific steps are as follows:

[0027] 1) Hot metal pretreatment: The hot metal is cleaned of slag, and the sulfur content of the hot metal is 0.042%.

[0028] 2) Converter: 113.9t of molten iron and 43.5t of steel scrap. The carbon content of converter tapping is controlled at 0.063%; lime 2.0Kg / t steel, ferrosilicon 2.0Kg / t steel, medium carbon ferromanganese (w[Mn]: 78%) 17kg / t steel are added during tapping, after furnace Feed aluminum wire 0.32 kg / t steel.

[0029] 3) Recovery of liquid casting slag: Before tapping the converter, pour 6.8Kg / t steel liquid casting slag into the ladle.

[0030] 4) LF furnace: LF blows argon at the station for 42 minutes. Add lime 4.5kg / t steel and fluorite 2.1kg / t steel during the process....

Embodiment 2

[0034] Smelt 1 furnace of API2Y-60 steel with sulfur content S≤0.003 and boron content B≤0.0005. The composition of the steel is shown in Table 1.

[0035] The smelting process is "converter-LF furnace-RH furnace-CC", and the specific steps are as follows:

[0036] 1) Hot metal pretreatment: The molten iron is cleaned of slag, and the sulfur content of the molten iron is 0.030%.

[0037] 2) Converter: 114.7t of molten iron and 43.65t of scrap steel. Carbon content in converter tapping is 0.042%; lime 2.1kg / t steel, ferrosilicon 2.0kg / t steel, metal manganese (w[Mn]:97%) 14.5 kg / t steel are added during tapping, aluminum is fed after furnace Line 0.40 Kg / t steel.

[0038] 3) Liquid casting slag recovery: after the converter is tapped, pour 5.5kg / t steel liquid casting slag into the ladle.

[0039] 4) LF furnace: LF blows argon at the station for 46 minutes. Add lime 6.5kg / t steel and fluorite 2.4kg / t steel during the process. Stir and desulfurize by feeding aluminum wire a...

Embodiment 3

[0043] The new standard Q370qE steel with sulfur content S ≤ 0.003 and boron content B ≤ 0.0005 was smelted in 1 furnace. The composition of the steel is shown in Table 1.

[0044] The smelting process is "converter-LF furnace-RH furnace-CC", and the specific steps are as follows:

[0045] 1) Hot metal pretreatment: The molten iron is cleaned of slag, and the sulfur content of the molten iron is 0.035%.

[0046]2) Converter: 114.8t of molten iron and 44.7t of steel scrap. The carbon content of converter tapping is controlled at 0.058%; lime 2.0kg / t steel, ferrosilicon 2.0kg / t steel, medium carbon ferromanganese (w[Mn]: 78%) 17 kg / t steel are added during the tapping process. Then feed aluminum wire 0.32 Kg / t steel.

[0047] 3) Recovery of liquid casting slag: After tapping out of the converter, pour 7.5Kg / t steel liquid casting slag into the ladle.

[0048] 4) LF furnace: LF blows argon at the station for 43 minutes. Add lime 4.2kg / t steel and fluorite 1.7kg / t steel during...

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Abstract

The invention provides a smelting method of low-sulfur and low-boron steel. The steel comprises, by weight, 0.05%-0.18% of C, 0.10%-0.35% of Si, 1.10%-1.60% of Mn, no more than 0.020% of P, no more than 0.003% of S, 0.010%-0.050% of Nb, 0.008%-0.025% of Ti, no more than 0.30% of Ni, no more than 0.20% of Mo, no more than 0.25% of Cr, no more than 0.0005% of B, and 0.010%-0.050% of Als. The smelting process includes a converter, an LF furnace, an RH furnace and CC. Pretreatment for desulfuration is not needed, the carbon content of steel discharged out of the converter is slightly decreased toreduce molten steel w[B], low-B alloys such as manganese metal and mid-carbon ferromanganese are added, liquid cast waste slag is used, and the quantity of recovered liquid cast slag is controlled, sothat rapid slagging and desulfuration are guaranteed, and the quantity of B dragged into slag is reduced; the LF furnace only adopts aluminum wire deoxidation, and a large quantity of argon is blownfrom the bottom to achieve stirring, so that the probability that boric oxide in the slag is reduced and molten steel enters the slag is lowered while the sulfur content in the molten steel is decreased; and when the sulfur content in the molten steel reaches a required sulfur content, the argon blown from the bottom is regulated to be weak, stirring is conducted to reduce the quantity of added B,and an obtained finished products meets w[S]<=0.003 and w[B]<=0.0005.

Description

technical field [0001] The invention belongs to the technical field of metallurgy and relates to a method for smelting low-sulfur and low-boron steel. Background technique [0002] Boron is known as the "vitamin" of steel. As a trace alloying element, the main function of boron in steel is to increase the hardenability of steel, and a trace amount of boron can greatly improve the hardenability of steel. However, boron-containing steel is prone to cracks on the slab, because boron will segregate during the solidification process, reducing the zero plasticity temperature (ZDT) of the steel, widening the brittle range of the steel and increasing the crack sensitivity. In addition, the precipitation of BN in the prior austenite grain boundary, pinning the grain boundary leads to grain boundary embrittlement, which reduces the plasticity of the slab and increases the probability of crack formation. For Mn-containing steel, when the B content in the steel is high, a brittle eute...

Claims

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Application Information

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IPC IPC(8): C22C38/02C22C38/04C22C38/06C22C38/44C22C38/48C22C38/50C22C38/54C22C38/58C21C7/10C21C7/06
CPCC21C7/06C21C7/10C22C38/002C22C38/02C22C38/04C22C38/06C22C38/44C22C38/48C22C38/50C22C38/54C22C38/58Y02P10/20
Inventor 黄治成刘吉文贾进周禹周凯解林冲李文华
Owner HUNAN VALIN XIANGTAN IRON & STEEL CO LTD
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