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121results about How to "Fast desulfurization" patented technology

Rapid desulfurization refining method for ladle furnace

InactiveCN102002554AFast desulfurizationAchieve economies of scaleAlloyPowder Spray
The invention discloses a rapid desulfurization refining method for a ladle furnace (LF). The method comprises the following steps of: 1) performing desulfurization refining in the LF, wherein the LF treatment starting temperature is between 1,570 and 1,605 DEG C; 2) after a ladle argon blowing device of the LF is turned on, blowing argon from the bottom of the ladle; 3) after finishing adjusting the temperature, inserting a desulfurization powder spraying gun into a molten steel liquid for spraying a desulfurizing agent; 4) after finishing spraying powder, switching the spraying gun to a functional stage of blowing the argon, blowing the argon from the top, simultaneously blowing the argon from the bottom of the ladle, and performing strong stirring desulfurization operation; 5) alloying, namely after desulfurization is finished, lifting the desulfurization powder spraying gun, adjusting a ladle bottom blowing flow, and performing alloy configuration to meet a target requirement on final components of a steel grade; and 6) after finishing adjusting components, performing soft stirring operation, measuring the temperature, sampling, and turning off the ladle argon blowing device to finish treating. The method realizes rapid desulfurization of the LF, and can shorten an overall melting cycle and improve the number of continuous casting furnaces and production efficiency.
Owner:BAOSHAN IRON & STEEL CO LTD

KR (knotted reactor) powder spraying, stirring and desulfurizing device and method

InactiveCN102676741AThe desulfurization cycle is shortenedReduced desulfurization working timeGranularityEngineering
The invention relates to a KR (knotted reactor) powder spraying, stirring and desulfurizing device. The KR powder spraying, stirring and desulfurizing device comprises a stirring head and a driving device for controlling the stirring head to act, wherein the driving device comprises a connecting rod linked with the stirring head, a lifting device for driving the connecting rod to move up and down and a stirring motor for driving the connecting rod to rotate. The KR powder spraying, stirring and desulfurizing device is characterized by further comprising a feeding system and a high-pressure gas source, wherein a through hole for introducing high-pressure inert gas and desulfurizing agents is formed on the stirring head, and an inlet of the through hole is communicated with a desulfurizing agent outlet and a high-pressure gas source outlet of the feeding system. The invention further relates to a method for desulfurizing molten iron by using the KR powder spraying, stirring and desulfurizing device. By using the device, efficient, fast and precise desulfurization can be realized, and the effects of reducing the requirements for granularity of desulfurizing agents, reducing the temperature drop and reducing the loss of the stirring head can be achieved.
Owner:ZENITH STEEL GROUP CORP

Refined-smelting ladle furnace carbon control deep desulphurization method for ultra-low-carbon steel production

ActiveCN101323896ASolve the problem of adding CShorten desulfurization treatment timeProcess efficiency improvementAlkalinitySulfur
The invention discloses a method for controlling carbon and deep desulphurization by a refined-smelting ladle furnace in the production of extreme low carbon steel, pertaining to the technical field of ladle refining. The technology of the invention is that the amount of roughing slag of a converter is controlled and the thickness of the slag is 30 mm to 60mm; the temperature of molten steel in an LF furnace ranges from 1590 DEG C to 1640 DEG C and the content of Al in the steel is equal to 0.05 percent to 0.09 percent; 6 to 12 kg/ton of refining slag with high basicity and 0.4 to 1.0 kg/ton of Al granules are added; the flow of bottom-blowing argon gas is controlled during the rapid deep desulphurization refining process. On the condition that no electrode is available, argon gas with mass flow of 6 to 8NL/ (min question mark t) is adopted for melting slag. After slag melting, the electrode is arranged to control the flow of argon gas to 4.8-6NL/ (min question mark t) and carbon pickup of the molten steel occurs; when the refining is completed, the oxidizability of steel slag (FeO+MnO) is required to be less than or equal to 1.0 percent and the weight percentage of alkalinity of (CaO)/(SiO2) is equal to 5.5 to 8.0. The method of the invention has the advantages of solving the problem of carbon pickup during the refining in the LF furnace and controlling the weight percentage of carbon increment within 0.015 percent, thereby realizing rapid deep desulphurization with the content of sulfur[S] which is less than or equal to 0.0010 percent after desulphurization, and shortening the smelting time of the LF furnace.
Owner:SHOUGANG CORPORATION

Method for activating high-sulfur bauxite by means of low-temperature roasting desulfurization method

The invention relates to a method for activating high-sulfur bauxite by means of a low-temperature roasting desulfurization method. The method which carries out oxidative desulfurization roasting on bauxite with 1 to 5 wt percent of sulfur content so that the bauxite can become material applicable to the Bayer process production of alumina is characterized in that the oxidative desulfurization temperature is controlled between 500 DEG C and 600 DEG C. More specifically, in a fluidized bed roaster or a rotary kiln, hot air which is 650 DEG C to 900 DEG C is utilized to heat dry-ground mineral powder. Not only is the sulfur content in the processed mineral powder decreased to be less than 0.5 percent, but also the organic matters in the mineral are completely oxidized to be decomposed, and meanwhile, because the roasting temperature is low, activated alumina can be prevented from being transformed to become over-stable. When the roasted bauxite is used in Bayer digestion, the digestion performance is improved, and the digestion rate of alumina is higher than 93 percent. After limestone suspension is cyclically sprayed or red mud suspension is sprayed to desulfurize the tail gas containing SO2 produced by oxidative desulfurization, the SO2 content can be decreased to be less than 300mg/m3, and thereby the tail gas comes up to the emission standard.
Owner:BEIJING UNIV OF CHEM TECH

High-efficiency deep desulfurization active carbon and preparation method thereof

The invention discloses high-efficiency deep desulfurization active carbon and a preparation method thereof, belonging to the field of modified active carbon materials. The high-efficiency deep desulfurization active carbon is prepared through the steps of by adopting coal or a coconut shell as raw materials, crushing, screening, then adding a coal tar adhesive for extrusion forming, and calcining at 750-950 DEG C to form primary active carbon; carrying out dipping treatment on the primary active carbon, uniformly loading a hydroxide active agent and a cyclodextrin assistant active agent, carrying out secondary high-temperature calcination in the presence of excessive heat water vapors to obtain a high-efficiency desulfurization active carbon product. The active carbon prepared through the method disclosed by the invention has the advantages of high sulphur capacity, high desulfurization speed, long usage period, high strength, good abrasion resistance, good material permeability, no dust and the like, can not only be used for the large-scale deep desulfurization and purification of petrochemical products such as fuel oil, natural gas, gas, liquid hydrocarbon and synthetic ammonia, but also be used for the fields of pharmaceutical gas sterilization, solution filtration and purification, solvent recovery, water purification, gas purification and the like.
Owner:JIANGSU ZHUHAI ACTIVATED CARBON CO LTD

Rapid desulfurizing method for smelting ultrapure steel with vacuum induction furnace

The invention discloses a rapid desulfurizing method for smelting ultrapure steel with a vacuum induction furnace, which comprises the following steps of: calculating the weights of a needed steel scrap raw material, various alloys, carbon granules used as an deoxidizing agent and rare earth wires used as a desulfurizing agent according to the component requirement of steel, and weighing the raw materials; then closing a vacuum chamber, and vacuumizing for 3-8 minutes until the vacuum degree of the vacuum chamber reaches 0.05-0.1 Pa; carrying out power transmission on the vacuum induction furnace for melting steel, and adding the carbon granules in a chute to molten steel by batches during the steel melting process; maintaining the vacuum degree of the vacuum chamber at 0.05-0.1 Pa after steel melting, and continuing vacuumizing for 15-20 minutes; stopping vacuumizing, and introducing argon gas to the vacuum chamber until the pressure in the vacuum chamber reaches 500-700 Pa; adding the various alloys to the molten steel for alloying treatment; adding the desulfurizing agent to the molten steel, stirring, oscillating and standing; and pouring to an ingot mold in a vacuum environment while retaining 2-10% of molten steel. Practice proves that the desulfurizing method provided by the invention employs a precipitation method to desulfurize without slag addition or slag generation, generated desulfurized products are removed through precipitation, rapid desulfurization can be realized, the operation is simple and feasible and the cost is low.
Owner:武钢集团有限公司

Method for preparing biomass fuel mainly from fresh chicken manure

ActiveCN106244278AWith water absorption and heat releaseReduce moisture contentBiofuelsSolid fuelsMicroorganismMushroom
The invention belongs to the technical field of environmental protection, and particularly relates to a method for preparing a biomass fuel mainly from fresh chicken manure. The method comprises the following steps: 1) pretreating raw materials; 2) fermentation: mixing fresh chicken manure, mushroom sticks and calcined shell powder, inoculating deodorizing composite microbes and nitrogen fixation-desulfurization composite microbes, and carrying out pile fermentation; 3) naturally drying the fermentation material; and 4) adding tea stems, and carrying out extrusion granulation. The fresh chicken manure is used as the main raw material, the waste mushroom sticks, calcined shell powder and tea stems are used as the auxiliary raw materials, the deodorizing composite microbes and nitrogen fixation-desulfurization composite microbes are added, and the flammability and comprehensive combustion characteristics of the reinforcing material of the composite microbes are fully utilized, thereby preparing the biomass granular fuel which has the advantages of low ignition point, high combustion heat value and high combustion rate. The method can greatly consume chicken manure, and solves the problem of environmental pollution caused by chicken manure. The method provides direction for the recycling of the waste mushroom sticks, shells and tea stems.
Owner:INST OF AGRI ENG TECH FUJIAN ACAD OF AGRI SCI

Smelting method of low-sulfur and low-boron steel

The invention provides a smelting method of low-sulfur and low-boron steel. The steel comprises, by weight, 0.05%-0.18% of C, 0.10%-0.35% of Si, 1.10%-1.60% of Mn, no more than 0.020% of P, no more than 0.003% of S, 0.010%-0.050% of Nb, 0.008%-0.025% of Ti, no more than 0.30% of Ni, no more than 0.20% of Mo, no more than 0.25% of Cr, no more than 0.0005% of B, and 0.010%-0.050% of Als. The smelting process includes a converter, an LF furnace, an RH furnace and CC. Pretreatment for desulfuration is not needed, the carbon content of steel discharged out of the converter is slightly decreased toreduce molten steel w[B], low-B alloys such as manganese metal and mid-carbon ferromanganese are added, liquid cast waste slag is used, and the quantity of recovered liquid cast slag is controlled, sothat rapid slagging and desulfuration are guaranteed, and the quantity of B dragged into slag is reduced; the LF furnace only adopts aluminum wire deoxidation, and a large quantity of argon is blownfrom the bottom to achieve stirring, so that the probability that boric oxide in the slag is reduced and molten steel enters the slag is lowered while the sulfur content in the molten steel is decreased; and when the sulfur content in the molten steel reaches a required sulfur content, the argon blown from the bottom is regulated to be weak, stirring is conducted to reduce the quantity of added B,and an obtained finished products meets w[S]<=0.003 and w[B]<=0.0005.
Owner:HUNAN VALIN XIANGTAN IRON & STEEL CO LTD

Rapid desulfurizing method for smelting ultrapure steel with vacuum induction furnace

The invention discloses a rapid desulfurizing method for smelting ultrapure steel with a vacuum induction furnace, which comprises the following steps of: calculating the weights of a needed steel scrap raw material, various alloys, carbon granules used as an deoxidizing agent and rare earth wires used as a desulfurizing agent according to the component requirement of steel, and weighing the raw materials; then closing a vacuum chamber, and vacuumizing for 3-8 minutes until the vacuum degree of the vacuum chamber reaches 0.05-0.1 Pa; carrying out power transmission on the vacuum induction furnace for melting steel, and adding the carbon granules in a chute to molten steel by batches during the steel melting process; maintaining the vacuum degree of the vacuum chamber at 0.05-0.1 Pa after steel melting, and continuing vacuumizing for 15-20 minutes; stopping vacuumizing, and introducing argon gas to the vacuum chamber until the pressure in the vacuum chamber reaches 500-700 Pa; adding the various alloys to the molten steel for alloying treatment; adding the desulfurizing agent to the molten steel, stirring, oscillating and standing; and pouring to an ingot mold in a vacuum environment while retaining 2-10% of molten steel. Practice proves that the desulfurizing method provided by the invention employs a precipitation method to desulfurize without slag addition or slag generation, generated desulfurized products are removed through precipitation, rapid desulfurization can be realized, the operation is simple and feasible and the cost is low.
Owner:武钢集团有限公司

Method for improving weather resistance of decorative base paper titanium dioxide

The invention provides a method for improving weather resistance of decorative base paper titanium dioxide, and belongs to the technical field of decorative base paper titanium dioxide. The control is performed through salt treatment and calcination. The method comprises the following steps of A, using bleached slurry as raw materials; adding titanium dioxide sol into the raw materials; controlling the addition to meet the requirement that the proportion of TiO2 in the titanium dioxide sol to TiO2 in metatitanic acid is 2 to 6 percent; performing water washing; diluting the slurry subjected to water washing into 300 to 400g / L TiO2 slurry; B, adding potassium and phosphorus solution with the K2O / P2O5 ratio being 1.3 to 4.0 into the diluted slurry; performing stirring; adding aluminum-containing compound solution according to the Al2O3 to TiO2 proportion being 0.3 to 0.9 percent; performing stirring; C, performing pressurized filtering on the slurry material treated by the step B until the filter cake solid content is 45 to 55 percent; C, roasting the filter cake in the step C for 8 to 10h at the roasting temperature of 200 to 950 DEG C. Through the control on the salt treatment and roasting processes, the primary product weather resistance of the decorative base paper titanium dioxide is improved; the weather resistance of the decorative base paper titanium dioxide is further improved.
Owner:HEBEI MILSON TITANIUM DIOXIDE

Catalyst for oxidation sweetening of diesel oil and application thereof

The invention relates to a catalyst for oxidation sweetening of diesel oil and an application thereof. The catalyst has the expression as QrBmHn[AxMyOz](r+m+n)-; in the expression, Q represents quaternary ammonium salt cations and is constituted by R1R2R3R4N+, R1, R2, R3 and R4 represent saturated alkyls of C1-C20 in which at least one carbon chain length is larger than or equal to 4 carbon atoms; B represents metal cations; H represents hydrogen atoms; A represents one of B, P, As, Si and Al elements; M represents the metal elements W and Mo; and O represents oxygen atoms, wherein r+m+n is equal to or less than 14, r is equal to or less than 10 and equal to or larger than 1, m is equal to or larger than 0 and equal to or less than 3, n is equal to or larger than 0 and equal to or less than 3, x is equal to 1 or 2, y is equal to or larger than 0 and equal to or less than 18, and z is equal to or larger than 34 and equal to or less than 62.The catalyst used for preparing low sulphur diesel mainly comprises the following steps: mixing the catalyst QrBmHn[AxMyOz] (r+m+n), aqueous hydrogen peroxide solution and diesel oil, reacting for 10min-5h under the temperature of 30-60 DEG C, standing or centrifugalizing to recovery the catalyst and obtain the oxidized diesel oil, and removing sulphone and/or sulphone sulfocompound from the oxidized diesel oil by an extracting or distilling method to obtain the low sulphur diesel of the sulphur content is less than 10ppm.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Poly (tetramethylguandium acrylate) aqueous solution desulfurization agent and preparation method thereof

The invention relates to a preparation method and an application method of poly (tetramethylguandium acrylate) desulfurization agent. The poly (tetramethylguandium acrylate) desulfurization agent can be used for flue gas desulfurization of a thermal power plant and a metallurgic plant, and has excellent selective absorption for sulfur dioxide as well as good lasting absorption property and multi-time cycle absorption and desorption stability. The desulfurization agent is characterized by comprising the components: poly (tetramethylguandium acrylate), water, antioxidant, corrosion inhibitor and defoaming agent. The preparation method comprises the steps of: adding solvent into a polymerizing pot, then adding initiator into the solvent, slowly heating to 120-140 DEG C when stirring, and dripping acrylic acid within 2-4h at the temperature of 120-140 DEG C; then removing the solvent under pressure reduction, and grinding to obtain polyacrylic acid; adding polyacrylic acid and water into a reaction flask and stirring; controlling the temperature to be 0-5 DEG C by ice-water bath, dripping 1,1,3,3-tetramethyl guanidine, reacting for 1h and then stopping the reaction; and adding right amount of antioxidant, corrosion inhibitor and defoaming agent, and evenly stirring to obtain poly (tetramethylguandium acrylate) aqueous solution, wherein the aqueous solution is the target desulfurization agent product.
Owner:BEIJING UNIV OF CHEM TECH

Ammonia desulfurization process and desulfurization device thereof

The invention provides an ammonia desulfurization process and a desulfurization device. A desulfurizer takes water, ammonia gas and oxygen with the weight ratio being 6:1:0.01 as raw materials, and isconveyed to a desulfurization reaction area in a boiler flue through a power system; the temperature of the desulfurization reaction area is 35 to 150 DEG C; ammonium hydroxide and the oxygen make contact with sulfur dioxide through an atomization nozzle to produce chemical reaction so as to generate ammonium sulfate, and the weight ratio of the ammonium hydroxide and the oxygen to the sulfur dioxide is 1:(1.72 to 1.46); a control system is characterized in that the spray volume of the ammonium hydroxide and the oxygen is automatically controlled by a computer according to collected data; product collection is characterized by adopting a wet process for trapping ammonium sulfate or a dry type gravity method for collecting the ammonium sulfate; the desulfurization device comprises a flue,a liquid storage tank, an oxygen tank, a production collecting device, an online detector, an atomization spray head and the control system. According to the ammonia desulfurization process and the desulfurization device thereof, provided by the invention, desulfurization can be carried out in the boiler flue or a waste gas channel of equipment producing the sulfur dioxide, the desulfurization efficiency and the desulfurization rate are automatically controlled, the reaction speed is fast, a desulfurization effect is good, and the operation cost can be reduced.
Owner:靳新令
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