Preparation and application of a sulfur autotrophic and heterotrophic denitrification biofiller
A technology of heterotrophic denitrification and biological filler, which is applied in the field of advanced wastewater treatment and reuse, can solve the problems of difficult further improvement of treatment efficiency, uneven distribution of biofilm, long time of biofilm formation, etc., and achieve denitrification and operation effect Stabilize, enhance the population richness, and facilitate the effect of attachment growth
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Embodiment 1
[0057] like figure 2 As shown, this embodiment provides a sulfur autotrophic and heterotrophic denitrification and denitrification biological filler, which is a sulfur-modified ceramsite with sulfur loaded on the surface, and the sulfur combines with Si and O elements on the surface of the ceramsite to form Si -O-S, the Si-O-S are cross-linked with each other to form a grid structure. In the present embodiment, the preparation method of sulfur-modified sulfur autotrophic and heterotrophic denitrification and denitrification biological fillers is as follows:
[0058] (1) Alkali modification:
[0059] The primary ceramsite is soaked with potassium hydroxide solution, and washed with water after soaking to obtain alkali-modified ceramsite;
[0060] (2) Sulfur load:
[0061] Disperse the alkali-modified ceramsite in the petroleum ether solvent, slowly add disulfide dichloride, heat and stir, after the reaction is completed, the sulfur-loaded sulfur-modified ceramsite is obtain...
Embodiment 2
[0063] This embodiment provides a sulfur autotrophic and heterotrophic denitrification and denitrification biological filler, and the biological filler is a sulfur-modified ceramsite that has been sequentially treated with alkali modification and sulfur loading.
[0064] In the present embodiment, the preparation methods of sulfur autotrophic and heterotrophic denitrification and denitrification biological fillers are as follows:
[0065] (1) Firing:
[0066] Add the binder calcium-based bentonite to the dewatered sludge and clay of the ceramsite raw materials to prepare raw meal powder, make the raw meal powder into raw meal balls, and roast the raw meal balls at high temperature to obtain primary ceramsite; The mass ratio of raw material to binder is 20:1.
[0067] (2) Alkali modification:
[0068] The primary ceramsite was soaked with potassium hydroxide solution with a mass concentration of 2%, and washed with water after soaking to obtain alkali-modified ceramsite;
[...
Embodiment 3
[0074] This embodiment provides a biological filler, and the biological filler is a sulfur-modified ceramsite that has been sequentially treated with alkali modification and sulfur loading.
[0075] In the present embodiment, the preparation methods of sulfur autotrophic and heterotrophic denitrification and denitrification biological fillers are as follows:
[0076] (1) Firing:
[0077] The binder sodium bentonite is added to the ceramsite raw material fly ash and garbage residue to prepare raw meal powder, the raw meal powder is made into raw meal balls, and the raw meal balls are calcined at high temperature to obtain primary ceramsite; The mass ratio of raw material to binder is 25:1.
[0078] (2) Alkali modification:
[0079] The primary ceramsite was soaked with potassium hydroxide solution with a mass concentration of 3%, and washed with water after soaking to obtain alkali-modified ceramsite;
[0080] (3) Sulfur load:
[0081] Disperse the alkali-modified ceramsite...
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Abstract
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