A preparation method of a large amount of wet-grinding phosphorus solid waste ultra-retarded gelling material

Abstract

The invention discloses a method for preparing a large-volume wet-grinding phosphorus solid waste super-slow gelling material. Phosphorus slag and desulfurization ash are added to a wet mill and mixed with water to obtain a mixed slurry A; alkali slag, Grind phosphogypsum and fly ash with a dry mill to obtain mixed powder B; mix mixed slurry A and mixed powder B to obtain mixed material C, and add cement, water reducer, retarder, Tailings sand and crushed stone were stirred for 4 minutes to obtain ultra-retarded concrete. The invention utilizes phosphorus slag, desulfurization ash, alkali slag, phosphogypsum, fly ash, tailings and other wastes to prepare concrete, turns waste into treasure, and can reduce the amount of cement; the mixed wet grinding method of phosphorus slag and desulfurization ash promotes The dissolution of medium phosphorus can greatly prolong the initial setting time and final setting time of concrete, reduce the early heat of hydration, reduce the generation of cracks, and ensure the later strength, so as to realize the high-efficiency application of large amount of phosphorus slag; the prepared ultra-retarded concrete It can be used for mass concrete, drilled occlusal piles, etc.

Description

technical field

[0001] The invention relates to the field of building materials, in particular to a method for preparing a large-volume wet-grinding phosphorus solid waste ultra-retarding gelling material. Background technique

[0002] There are a lot of phosphate rock resources in nature, which can be used to produce phosphoric acid by wet method. In the process of phosphoric acid production by wet method, industrial waste residues such as phosphorus slag and phosphogypsum will be discharged; on the other hand, mineral processing will also produce a large amount of phosphorus tailings. Most phosphorus solid wastes are stacked in the open air, which not only occupies a large amount of land resources, but also contains phosphorus, fluorine and organic matter, which are washed by rainwater and seriously pollute nearby soil and water resources. Therefore, the effective utilization of phosphorus solid waste has extremely important environmental protection significance. [0003...

Examples

Embodiment 1

[0038] 1) Take 200 parts by weight of phosphorus slag and send 20 parts of desulfurization ash into a wet ball mill, add water according to the ratio of water to material mass ratio of 0.4, and obtain mixed slurry A;

[0039] The average particle size of the mixed slurry A is 4 μm;

[0040] 2) Take 5 parts by weight of alkali slag, 2 parts of phosphogypsum, and 4 parts of fly ash and grind them with a dry mill to obtain a mixed powder material B;

[0041] The average particle size of the mixed powder material B is 9 μm;

[0042] 3) Mix the mixed slurry A with the mixed powder material B to obtain the mixed material C, add 5 parts of cement, 0.5 parts of water-soluble resin sulfonate water reducing agent, 0.5 parts of sodium pyrophosphate, 150 1 part of tailings sand, 300 parts of gravel, stirred for 4 minutes to obtain super retarded concrete;

[0043] The phosphorus slag P 2 o 5 The content of F is 2.5%, and the content of F is 1.9%.

Embodiment 2

[0045] 1) Take 230 parts by weight of phosphorus slag and 25 parts of desulfurized ash and send them into a wet ball mill, add water according to the ratio of water to material mass ratio of 0.4, and obtain mixed slurry A;

[0046] The average particle size of the mixed slurry A is 3.2 μm;

[0047] 2) Take 7 parts by weight of alkali slag, 8 parts of phosphogypsum, and 10 parts of fly ash and grind them with a dry mill to obtain a mixed powder material B;

[0048] The average particle size of the mixed powder material B is 8.5 μm;

[0049] 3) Mix the mixed slurry A with the mixed powder material B to obtain the mixed material C, add 10 parts of cement, 0.5 parts of water-soluble resin sulfonate water reducing agent, 0.5 parts of sodium pyrophosphate, 0.5 parts of 1 part of phosphate, 100 parts of tailings sand, 250 parts of gravel, and stirred for 4 minutes to obtain super retarded concrete.

[0050] The phosphorus slag P 2 o 5 The content of F is 3%, and the content of F ...

Embodiment 3

[0052] 1) Take 260 parts by weight of phosphorus slag and 25 parts of desulfurization ash and send them into a wet ball mill, add water according to the ratio of water to material mass ratio of 0.45, and obtain mixed slurry A;

[0053] The average particle size of the mixed slurry A is 2.4 μm;

[0054] 2) Take 10 parts by weight of alkali slag, 8 parts of phosphogypsum, and 8 parts of fly ash and grind them with a dry mill to obtain a mixed powder material B;

[0055] The average particle size of the mixed powder material B is 7 μm;

[0056] 3) Mix the mixed slurry A with the mixed powder material B to obtain the mixed material C, add 15 parts of cement, 0.5 parts of water-soluble resin sulfonate water reducing agent, 0.7 parts of phosphate, 200 parts of Tailings sand, 400 parts of gravel, stirred for 4 minutes to obtain super retarded concrete.

[0057] The phosphorus slag P 2 o 5 The content of F is 3.5%, and the content of F is 2.9%;

technical field

[0001] The invention relates to the field of building materials, in particular to a method for preparing a large-volume wet-grinding phosphorus solid waste ultra-retarding gelling material. Background technique

[0002] There are a lot of phosphate rock resources in nature, which can be used to produce phosphoric acid by wet method. In the process of phosphoric acid production by wet method, industrial waste residues such as phosphorus slag and phosphogypsum will be discharged; on the other hand, mineral processing will also produce a large amount of phosphorus tailings. Most phosphorus solid wastes are stacked in the open air, which not only occupies a large amount of land resources, but also contains phosphorus, fluorine and organic matter, which are washed by rainwater and seriously pollute nearby soil and water resources. Therefore, the effective utilization of phosphorus solid waste has extremely important environmental protection significance. [0003...

Examples

Embodiment 1

[0038] 1) Take 200 parts by weight of phosphorus slag and send 20 parts of desulfurization ash into a wet ball mill, add water according to the ratio of water to material mass ratio of 0.4, and obtain mixed slurry A;

[0039] The average particle size of the mixed slurry A is 4 μm;

[0040] 2) Take 5 parts by weight of alkali slag, 2 parts of phosphogypsum, and 4 parts of fly ash and grind them with a dry mill to obtain a mixed powder material B;

[0041] The average particle size of the mixed powder material B is 9 μm;

[0042] 3) Mix the mixed slurry A with the mixed powder material B to obtain the mixed material C, add 5 parts of cement, 0.5 parts of water-soluble resin sulfonate water reducing agent, 0.5 parts of sodium pyrophosphate, 150 1 part of tailings sand, 300 parts of gravel, stirred for 4 minutes to obtain super retarded concrete;

[0043] The phosphorus slag P 2 o 5 The content of F is 2.5%, and the content of F is 1.9%.

Embodiment 2

[0045] 1) Take 230 parts by weight of phosphorus slag and 25 parts of desulfurized ash and send them into a wet ball mill, add water according to the ratio of water to material mass ratio of 0.4, and obtain mixed slurry A;

[0046] The average particle size of the mixed slurry A is 3.2 μm;

[0047] 2) Take 7 parts by weight of alkali slag, 8 parts of phosphogypsum, and 10 parts of fly ash and grind them with a dry mill to obtain a mixed powder material B;

[0048] The average particle size of the mixed powder material B is 8.5 μm;

[0049] 3) Mix the mixed slurry A with the mixed powder material B to obtain the mixed material C, add 10 parts of cement, 0.5 parts of water-soluble resin sulfonate water reducing agent, 0.5 parts of sodium pyrophosphate, 0.5 parts of 1 part of phosphate, 100 parts of tailings sand, 250 parts of gravel, and stirred for 4 minutes to obtain super retarded concrete.

[0050] The phosphorus slag P 2 o 5 The content of F is 3%, and the content of F ...

Embodiment 3

[0052] 1) Take 260 parts by weight of phosphorus slag and 25 parts of desulfurization ash and send them into a wet ball mill, add water according to the ratio of water to material mass ratio of 0.45, and obtain mixed slurry A;

[0053] The average particle size of the mixed slurry A is 2.4 μm;

[0054] 2) Take 10 parts by weight of alkali slag, 8 parts of phosphogypsum, and 8 parts of fly ash and grind them with a dry mill to obtain a mixed powder material B;

[0055] The average particle size of the mixed powder material B is 7 μm;

[0056] 3) Mix the mixed slurry A with the mixed powder material B to obtain the mixed material C, add 15 parts of cement, 0.5 parts of water-soluble resin sulfonate water reducing agent, 0.7 parts of phosphate, 200 parts of Tailings sand, 400 parts of gravel, stirred for 4 minutes to obtain super retarded concrete.

[0057] The phosphorus slag P 2 o 5 The content of F is 3.5%, and the content of F is 2.9%;

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