A Silicon Carbide Crystal Growth Method with Low Basal Plane Dislocation Density
A technology of basal plane dislocation and crystal growth, applied in the directions of crystal growth, single crystal growth, single crystal growth, etc., can solve problems such as reducing control, and achieve the effect of avoiding temperature regulation
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Embodiment 1
[0037] A piece of 4H-SiC seed crystal with an angle of 4° is used, and the C plane is used as the crystal growth plane, and it is bonded to the lid of the graphite crucible. Fill the bottom of the crucible with sufficient SiC powder raw materials, then place the crucible cover with the seed crystal on the upper part of the crucible, and put it into the single crystal growth furnace after assembly. Vacuumize the single crystal furnace until the pressure is less than 10Pa, and carry out the following processes in sequence: (1) Inflate the growth furnace with the mixed gas of argon and nitrogen until the pressure reaches 30kPa, keep the pressure constant, and use medium frequency induction heating to carry out Raise the temperature, set the temperature at the raw material at 2200-2300°C, and set the temperature at the seed crystal at 150°C lower than the raw material temperature. After reaching the temperature, keep it warm for 3 hours, and then keep the temperature in the furnace...
Embodiment 2
[0039] A piece of 4H-SiC seed crystal with an angle of 8° is bonded to the graphite crucible cover with the C plane as the crystal growth plane. The bottom of the crucible is filled with sufficient vanadium-doped SiC powder raw materials, and then the crucible cover with the seed crystal stuck on the upper part of the crucible is put into the single crystal growth furnace after assembly. Vacuumize the single crystal furnace until the pressure is less than 10Pa, and carry out the following processes in sequence: (1) Inflate the growth furnace with the mixed gas of argon and nitrogen until the pressure reaches 30kPa, keep the pressure constant, and use medium frequency induction heating to carry out Raise the temperature, set the temperature of the raw material at 2200-2300°C, the temperature of the seed crystal is 150°C lower than the raw material temperature, keep the temperature for 5 hours after reaching the temperature, and then keep the temperature in the furnace unchanged;...
Embodiment 3
[0041] A piece of 4H-SiC seed crystal with an angle of 4° is bonded to the graphite crucible cover with the C plane as the crystal growth plane. Fill the bottom of the crucible with sufficient SiC powder raw materials, then place the crucible cover with the seed crystal on the upper part of the crucible, and put it into the single crystal growth furnace after assembly. Vacuumize the single crystal furnace until the pressure is less than 10Pa, and carry out the following processes in sequence: (1) Inflate the growth furnace with a mixture of argon and nitrogen until the pressure reaches 50kPa, keep the pressure constant, and use medium frequency induction heating to carry out Raise the temperature, set the temperature of the raw material at 2200-2300°C, the temperature of the seed crystal is 150°C lower than the raw material temperature, keep the temperature for 5 hours after reaching the temperature, and then keep the temperature in the furnace unchanged; (2) Through the pressu...
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