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Preparation and Application of Ultra-low Water Content Ceramic Slurry for Lithium-ion Batteries

A lithium-ion battery, ceramic slurry technology, applied in battery pack parts, circuits, electrical components, etc., can solve the problems of battery capacity decline, impact on battery performance, battery pressure increase, etc., to improve electrical performance and improve finished products. rate and electrical properties of the product, the effect of reducing water content

Active Publication Date: 2021-08-31
广东卓高新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is a more fatal problem with the ceramic coated separator, that is, the surface of the ceramic is easy to absorb moisture, and the moisture will cause the battery to generate gas, increase the internal pressure of the battery, decrease the battery capacity, and affect the performance of the battery.

Method used

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  • Preparation and Application of Ultra-low Water Content Ceramic Slurry for Lithium-ion Batteries
  • Preparation and Application of Ultra-low Water Content Ceramic Slurry for Lithium-ion Batteries
  • Preparation and Application of Ultra-low Water Content Ceramic Slurry for Lithium-ion Batteries

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of ultra-low water content ceramic slurry for lithium ion battery, comprises the raw material of following weight percent:

[0031]

[0032]

[0033] The ceramic powder is composed of a specific surface area of ​​2m 2 / g of alumina, the specific surface area is 3m 2 / g of magnesium oxide and a specific surface area of ​​2.5m 2 / g of boehmite is a mixture composed of 0.8:1.0:0.8 by weight.

[0034] The specific surface area is 2m 2 / g of alumina is prepared by the following steps:

[0035] 1) Using a wet ball milling process to grind conventional α-crystal form calcined alumina into alumina powder with a particle size of less than 1 μm, and set aside;

[0036] 2) Using spray drying to dry the alumina powder obtained in step 1) under the condition of 170° C., remove moisture, and set aside;

[0037] 3) The alumina powder dried in step 2) is placed under the condition of 1200° C. for calcination for 60 minutes, and finally the calcined alumina powder is gro...

Embodiment 2

[0047] A kind of ultra-low water content ceramic slurry for lithium ion battery, comprises the raw material of following weight percent:

[0048]

[0049] The ceramic powder is composed of a specific surface area of ​​4m 2 / g of alumina, the specific surface area is 4m 2 / g of magnesium oxide and a specific surface area of ​​3m 2 / g of boehmite is a mixture composed of 0.9:1.0:0.9 by weight.

[0050] The specific surface area is 4m 2 / g of alumina is prepared by the following steps:

[0051] 1) Using a wet ball milling process to grind conventional α-crystal form calcined alumina into alumina powder with a particle size of less than 1 μm, and set aside;

[0052] 2) Use spray drying to dry the alumina powder obtained in step 1) under the condition of 175° C., remove moisture, and set aside;

[0053] 3) The alumina powder dried in step 2) is placed under the condition of 1250° C. for calcination for 75 minutes, and finally the calcined alumina powder is ground by a dry b...

Embodiment 3

[0063] A kind of ultra-low water content ceramic slurry for lithium ion battery, comprises the raw material of following weight percent:

[0064]

[0065] The ceramic powder is composed of a specific surface area of ​​6m 2 / g of alumina, the specific surface area is 5m 2 / g of magnesium oxide and a specific surface area of ​​3.5m 2 / g of boehmite is a mixture composed of a weight ratio of 1.0:1.0:1.0.

[0066] The specific surface area is 6m 2 / g of alumina is prepared by the following steps:

[0067] 1) Using a wet ball milling process to grind conventional α-crystal form calcined alumina into alumina powder with a particle size of less than 1 μm, and set aside;

[0068] 2) Using spray drying to dry the alumina powder obtained in step 1) under the condition of 180° C., remove moisture, and set aside;

[0069] 3) The alumina powder dried in step 2) is placed at 1300° C. for calcination for 90 minutes, and finally the calcined alumina powder is ground by a dry ball mill...

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Abstract

The present invention relates to the technical field of lithium-ion battery diaphragm coating, in particular to the preparation and application of an ultra-low water content ceramic slurry for lithium-ion batteries, comprising the following raw materials in weight percentage: ceramic powder 35-45%, stabilizer 4 ‑8%, binder 3‑6%, dispersant 0.001‑0.3%, organopolysiloxane 0.001‑0.2%, polymethacrylate 0.01‑3% and the balance is deionized water. The present invention mainly starts from raw materials to control the adsorption of water by the ceramic diaphragm, and uses ceramic powder with a low specific surface to reduce the adsorption of ceramic powder to free water in the air and the binding ability to bound water. The hydrophobic principle of oxane makes the dispersant and the surface of the ceramic powder superhydrophobic, which synergistically reduces the ability of the surface of the ceramic powder to absorb water, thereby reducing the water content of the ceramic diaphragm as a whole.

Description

technical field [0001] The invention relates to the technical field of lithium-ion battery diaphragm coating, in particular to the preparation and application of ultra-low water content ceramic slurry for lithium-ion batteries. Background technique [0002] With the increasing tension of market energy and the deterioration of environmental pollution, clean and environmentally friendly energy has attracted more and more attention. Lithium-ion batteries have the advantages of high energy density, light weight, long cycle life, low self-discharge rate, no memory effect, and environmental protection, so they are widely used in portable electronic devices, power tools, and electric vehicles. [0003] As one of the key materials in the battery, the lithium-ion battery separator plays a role in blocking the contact between the positive and negative electrodes of the battery, preventing electrons from passing through the battery, providing lithium-ion transport channels, and closed-...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D1/00C09D7/65C09D7/43C04B35/10C04B35/626H01M50/417H01M50/434H01M50/403
CPCC04B35/10C04B35/62605C04B35/62675C04B2235/5409C09D1/00C09D7/43C09D7/65H01M50/403H01M50/446Y02E60/10
Inventor 李雪王晓明杨浩田王志彬
Owner 广东卓高新材料科技有限公司