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Composition of high-temperature corrosion-resistant transparent primer for automobile wheel hub and preparation method thereof

A technology for transparent primers and automotive wheels, applied in the direction of anti-corrosion coatings, coatings, polyester coatings, etc., can solve problems such as poor corrosion resistance, yellowing of paint films, affecting product performance and aesthetics, etc., without affecting appearance, Good adhesion and simple preparation process

Active Publication Date: 2022-02-08
LANGFANG NIPPON PAINT +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But there are still many defects in the existing transparent varnish use process
For example, due to the poor corrosion resistance of the single-coat liquid transparent varnish, it is impossible to meet the requirement that the aluminum alloy wheel hub is not corroded. It is necessary to add a layer of powder varnish on the liquid transparent varnish film to meet the corrosion resistance requirements.
The powder varnish needs to be baked at a high temperature above 180°C before it can be cured. Such a high temperature can directly lead to the decrease of the adhesion of the liquid transparent varnish coating and the yellowing of the paint film, which seriously affects the performance and appearance of the product.

Method used

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  • Composition of high-temperature corrosion-resistant transparent primer for automobile wheel hub and preparation method thereof
  • Composition of high-temperature corrosion-resistant transparent primer for automobile wheel hub and preparation method thereof
  • Composition of high-temperature corrosion-resistant transparent primer for automobile wheel hub and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment approach

[0044] The present invention also provides a preparation method of the above-mentioned high-temperature corrosion-resistant transparent primer for automobile wheels, a possible implementation mode, including the following steps:

[0045] (1) Under stirring conditions, add 15.0-30.0 parts of diluent and 12-16 parts of hyperbranched polymer to the reactor successively, and continue stirring for 8-15 minutes;

[0046] (2) Add 0.5-5 parts of blocked isocyanate resin, 25.0-35.0 parts of modified polyester resin, 3.0-8.0 parts of amino resin, 5.0-8.0 parts of epoxy resin, 0.1-2 parts of phosphate polymerization material, 3.0-4.0 parts of paint additives and 10.0-30.0 parts of diluent, stirred for 20-40 minutes, and then filtered to obtain a high-temperature corrosion-resistant transparent primer for automobile wheels.

[0047] Preferably, in step (1), the stirring speed is 200-250r / min; in step (2), the stirring speed is 300-350r / min.

[0048] The purpose of adding diluent and hype...

Embodiment 1

[0073] The raw materials used for the high-temperature corrosion-resistant transparent primer for automobile wheel hubs in embodiment 1 are as shown in table 1, and the preparation process is as follows:

[0074]Add 8 parts of butyl acetate, 6 parts of methyl isobutyl ketone, 2 parts of butanol and 5 parts of ethylene glycol butyl ether into the stirring tank, slowly add 12.7 parts of CyGLAZ BB 900, BB 900 at a stirring speed of 200r / min The hydroxyl content of the solid resin in the medium is 8.45%. After stirring for 10 minutes, slowly add 0.6 parts of BL 3175, 33.5 parts of SETAL 1715 VX-74, 4 parts of CYMEL 303, 5 parts of 1001-X-75, and 1 part of AD- 210, 0.3 parts of TINUVIN-1130, 0.3 parts of TINUVIN-292, 0.5 parts of BYK-306, 0.8 parts of KBM 403, 2.5 parts of BYK-450, 0.8 parts of BYK-392, 4 parts of methylisobutyl Butyl ketone, 3 parts of n-butanol, 3 parts of ethylene glycol butyl ether and 7 parts of butyl acetate. After feeding, the stirring speed is raised to 380...

Embodiment 2-10

[0101] The raw material composition of the high-temperature corrosion-resistant transparent primer for automobile wheels in Examples 2-10 is shown in Table 4, and the preparation method of the primer is similar to that of Example 1.

[0102] Raw material composition in the embodiment 2-10 of table 4

[0103]

[0104]

[0105]

[0106] The adhesion, water resistance and CASS corrosion resistance of the high-temperature corrosion-resistant transparent primer for automobile wheels in Examples 2-10 were detected, and the results are shown in Table 5.

[0107] Paint film adhesion, water resistance and CASS corrosion resistance of table 5 embodiment 2-10

[0108]

[0109] The results in Table 5 show that the paint film provided by the present invention has excellent adhesion, water resistance and CASS corrosion resistance.

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Abstract

The invention discloses a composition of a high-temperature corrosion-resistant transparent primer for automobile wheel hubs. The raw materials include, in parts by weight, 25-35 parts of modified polyester resin, 12-16 parts of hyperbranched polymer, and 0.5-5 parts Blocked isocyanate resin, 3-8 parts amino resin. Numerous terminal hydroxyl functional groups in the hyperbranched polymer in the transparent primer composition react with blocked isocyanate to produce a polyurethane polymer network with high crosslink density, combined with excellent polyester resin and amino resin, it has high temperature resistance and Corrosion performance; the paint film after coating and baking at high temperature has good adhesion, and does not cause yellowing and does not affect the appearance; at the same time, the preparation process is simple and suitable for industrial production.

Description

technical field [0001] The invention relates to the technical field of coatings. More specifically, it relates to a composition of a high-temperature corrosion-resistant transparent primer for automobile wheels. Background technique [0002] In the automotive wheel hub industry, in order to meet the customer's pursuit of beauty and individuality, it is necessary to do a fine-turning treatment on the surface of the wheel hub to expose the bright surface of the aluminum alloy wheel hub itself. In order to ensure that the appearance of the finish car bright surface is not affected, and it must be protected from oxidation and corrosion, therefore, it is necessary to coat the surface of the wheel hub after finish car with a liquid transparent varnish. But there are still many defects in the existing transparent varnish in use. For example, due to the poor corrosion resistance of the single-coat liquid transparent varnish, it is impossible to meet the requirement that the alumin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D167/00C09D175/04C09D161/20C09D5/08
CPCC09D167/00C09D5/08C09D5/18C08L2201/10C08L2201/08C08L2205/035C08L75/04C08L61/20C08L63/00C08L85/02
Inventor 刘永辉齐见凯马永强李青吴志宇
Owner LANGFANG NIPPON PAINT