Method for recovering iron by utilizing high-iron red mud, and method for extracting aluminum by utilizing high-iron red mud

A technology of high-iron red mud and iron recovery, applied in chemical instruments and methods, improvement of process efficiency, solid separation, etc., can solve the problems of difficult separation of iron-containing components of iron minerals, coating phenomenon, etc., and achieve improvement Reduction conversion efficiency, low cost, and the effect of improving recovery rate

Inactive Publication Date: 2020-03-06
NORTHEASTERN UNIV LIAONING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the small particle size of red mud particles and the coating phenomenon between them, it is difficult to separate iron-containing components such as iron minerals by conventional physical separation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] The chemical composition of the high iron red mud used includes: 33.56% Fe 2 o 3 , 18.09% Al 2 o 3 .

[0041] Step S1. Put 1000g of high-speed iron red mud in a closed shaft furnace, and pass in flare gas from the lower part of the shaft furnace, and reduce at 1150°C for 150 minutes. After the reduction, continue to pass in flare gas until the temperature in the shaft furnace drops to room temperature to obtain the reducing material.

[0042] Step S2. Grinding the reduced raw materials to below 200 meshes, performing magnetic separation under a magnetic field strength of 20KA / m to obtain magnetic separation concentrates and magnetic separation tailings; the magnetic separation concentrates are iron concentrates, and the magnetic separation tailings are Alumina enrichment ore.

[0043] Step S3. According to the molar ratio of alumina and ammonium sulfate in the magnetic separation tailings is 1:6, the magnetic separation tailings and ammonium sulfate are uniformly m...

Embodiment 2

[0047] The chemical composition of the high iron red mud used includes: 32.52% Fe 2 o 3 , 18.42% Al 2 o 3 .

[0048] Step S1. Put 1000g of high-speed iron red mud in a closed shaft furnace, and pass in flare gas from the lower part of the shaft furnace, and reduce at 1200°C for 180 minutes. After the reduction, continue to pass in flare gas until the temperature in the shaft furnace drops to room temperature to obtain the reducing material.

[0049] Step S2. Grinding the reduced raw materials to below 200 meshes, performing magnetic separation under a magnetic field strength of 20KA / m to obtain magnetic separation concentrates and magnetic separation tailings; the magnetic separation concentrates are iron concentrates, and the magnetic separation tailings are Alumina enrichment ore.

[0050] Step S3. According to the molar ratio of alumina and ammonium sulfate in the magnetic separation tailings is 1:6, the magnetic separation tailings and ammonium sulfate are uniformly m...

Embodiment 3

[0054] The chemical composition of the high iron red mud used includes: 35.5% Fe 2 o 3 , 17.8% Al 2 o 3 .

[0055] Step S1. Put 1000g of high-speed iron red mud in a closed shaft furnace, and pass in flare gas from the lower part of the shaft furnace, and reduce at 1100°C for 120 minutes. After the reduction, continue to pass in flare gas until the temperature in the shaft furnace drops to room temperature to obtain the reducing material.

[0056] Step S2. Grinding the reduced raw materials to below 200 meshes, performing magnetic separation under a magnetic field strength of 20KA / m to obtain magnetic separation concentrates and magnetic separation tailings; the magnetic separation concentrates are iron concentrates, and the magnetic separation tailings are Alumina enrichment ore.

[0057] Step S3. According to the molar ratio of alumina and ammonium sulfate in the magnetic separation tailings is 1:6, the magnetic separation tailings and ammonium sulfate are uniformly mix...

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PUM

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Abstract

The invention provides a method for recovering iron by utilizing high-iron red mud. The method for recovering the iron by utilizing the high-iron red mud comprises the following steps of S1, placing the high-iron red mud in an airtight reduction furnace, feeding flare gas into the reduction furnace, and carrying out heating reduction so as to obtain a reduced material; and S2, after grinding the reduced material, carrying out magnetic separation so as to obtain magnetic separation concentrates and magnetic separation tailings, wherein the magnetic separation concentrates are iron ore concentrates; and the magnetic separation tailings are aluminum oxide enriched ores. The iron therein can be recovered, the flare gas can be utilized at the same time, and the atmospheric pollution produced byflare gas combustion of the petrochemical enterprise is avoided. The invention further provides a method for extracting aluminum by utilizing the high-iron red mud. The method for extracting the aluminum by utilizing the high-iron red mud comprises the steps of A1, treating the high-iron red mud by adopting the method so as to obtain magnetic separation concentrates and magnetic separation tailings; A2, after uniformly mixing the magnetic separation tailings, ammonium sulfate and water, roasting to obtain a roasted clinker; and A3, dissolving out the roasted clinker, and separating to obtainan aluminum-containing solution and residues after extracting the aluminum. The iron, the aluminum and silicon in the magnetic separation tailings are separated, so that the aim on comprehensively utilizing the high-iron red mud is achieved.

Description

technical field [0001] The invention belongs to the technical field of mineral processing and metallurgy, and in particular relates to a method for recovering iron by using high-iron red mud and a method for extracting aluminum by using high-iron red mud. Background technique [0002] Red mud is the waste residue produced during the production of alumina. The output of red mud varies with ore grade, production method and technical level. Every time 1 ton of alumina is produced in my country, 1.0-1.7 tons of red mud will be produced along with it. At present, the cumulative stockpiled red mud exceeds 400 million tons. A large amount of red mud cannot be effectively used and can only be stacked in a large area, which not only takes up a lot of land, but also causes serious pollution to the environment due to the high alkalinity of red mud, which has become a major environmental hazard. [0003] Red mud is rich in rare metal elements such as iron, titanium, aluminum, sodium, r...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B7/04C22B1/00C22B1/02C22B3/04C22B21/00B03C1/00
CPCB03C1/00C22B1/005C22B1/02C22B3/04C22B7/001C22B7/006C22B7/04C22B21/0007C22B21/0023Y02P10/20
Inventor 吴艳白皓何东昌刘梦李在元
Owner NORTHEASTERN UNIV LIAONING
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