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Method for recovering Ni-Co-Cu from Ni polymetallic ores

A polymetallic ore, nickel-cobalt technology, applied to the improvement of process efficiency, solid separation, flotation, etc., can solve the problems of treatment process that needs to be improved, waste of resources, little attention to the recovery of associated valuable element cobalt, etc., to achieve Utilization of resources and the effect of improving the economic benefits of enterprises

Active Publication Date: 2020-03-27
CHINA ENFI ENGINEERING CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nickel polymetallic ores generally contain associated valuable elements such as cobalt. However, the current process mainly considers the recovery of nickel and copper, and little attention is paid to the recovery of associated valuable elements cobalt, resulting in a waste of resources.
[0003] Therefore, the processing technology of existing nickel polymetallic ore needs to be improved

Method used

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  • Method for recovering Ni-Co-Cu from Ni polymetallic ores
  • Method for recovering Ni-Co-Cu from Ni polymetallic ores
  • Method for recovering Ni-Co-Cu from Ni polymetallic ores

Examples

Experimental program
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Effect test

Embodiment 1

[0051] see Figure 4 A process flow chart of nickel-cobalt-copper recovery from nickel polymetallic ore. The nickel grade in a nickel polymetallic mine is 0.85wt%, the copper grade is 0.18wt%, and the cobalt grade is 0.032wt%.

[0052] (1) Grinding the nickel polymetallic ore with a ball mill, the obtained grinding fines have a particle size not higher than 0.074mm and account for 70%;

[0053] (2) Mix the grinding fines with sodium carboxymethyl cellulose, sodium carbonate, sodium octadecyl toluene sulfonate, diethylenetriamine, butyl xanthate and terpineol oil for one-stage flotation to obtain one-stage flotation Concentrate and one-stage flotation tailings, wherein, based on 1t of nickel polymetallic ore, the amount of sodium carboxymethyl cellulose is 600g, the amount of sodium carbonate is 1000g, and the amount of sodium octadecyltoluenesulfonate is 800g, The consumption of diethylenetriamine is 100g, the consumption of butyl xanthate is 80g, the consumption of pinitol ...

Embodiment 2

[0062] see Figure 4 A process flow chart of nickel-cobalt-copper recovery from nickel polymetallic ore. The nickel grade in a nickel polymetallic mine is 0.80wt%, the copper grade is 0.15wt%, and the cobalt grade is 0.029wt%.

[0063] (1) Grinding the nickel polymetallic ore with a ball mill, the obtained grinding fines have a particle size not higher than 0.074mm and account for 70%;

[0064] (2) Mix the grinding fines with sodium carboxymethyl cellulose, sodium carbonate, sodium octadecyl toluene sulfonate, diethylenetriamine, butyl xanthate and terpineol oil for one-stage flotation to obtain one-stage flotation Concentrate and one-stage flotation tailings, wherein, based on 1t of nickel polymetallic ore, the amount of sodium carboxymethyl cellulose is 600g, the amount of sodium carbonate is 1000g, and the amount of sodium octadecyltoluenesulfonate is 800g, The consumption of diethylenetriamine is 100g, the consumption of butyl xanthate is 80g, the consumption of terpineo...

Embodiment 3

[0073] see Figure 4 A process flow chart of nickel-cobalt-copper recovery from nickel polymetallic ore. The nickel grade in a nickel polymetallic mine is 0.92wt%, the copper grade is 0.21wt%, and the cobalt grade is 0.036wt%.

[0074] (1) Grinding the nickel polymetallic ore with a ball mill, the obtained grinding fines have a particle size not higher than 0.074mm and account for 70%;

[0075] (2) Mix the grinding fines with sodium carboxymethyl cellulose, sodium carbonate, sodium octadecyl toluene sulfonate, diethylenetriamine, butyl xanthate and terpineol oil for one-stage flotation to obtain one-stage flotation Concentrate and one-stage flotation tailings, wherein, based on 1t of nickel polymetallic ore, the amount of sodium carboxymethyl cellulose is 600g, the amount of sodium carbonate is 1000g, and the amount of sodium octadecyltoluenesulfonate is 800g, The consumption of diethylenetriamine is 100g, the consumption of butyl xanthate is 80g, the consumption of pinitol ...

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Abstract

The invention discloses a method for recovering Ni-Co-Cu from Ni polymetallic ores. The method comprises the steps of (1) conducting ore grinding treatment on the Ni polymetallic ores to obtain ore grinding fines; (2) mixing the ore grinding fines with sodium carboxymethyl cellulose, sodium carbonate, sodium p-octadecyl toluene sulfonate, diethylenetria, sodium n-butylxanthate and terpenic oil, and conducting first-stage flotation to obtain first-stage flotation concentrates and first-stage flotation tailings; (3) mixing the first-stage flotation tailings with sodium carboxymethyl cellulose, sodium p-octadecyl toluene sulfonate, diethylenetria, sodium n-butylxanthate and terpenic oil, and conducting second-stage flotation to obtain second-stage flotation concentrates and second-stage flotation tailings; (4) mixing the first-stage flotation concentrates and the second-stage flotation concentrates with sodium carboxymethyl cellulose, sodium carbonate, sodium p-octadecyl toluene sulfonateand diethylenetria, and conducting first-stage cleaning to obtain first-stage cleaned concentrates and first-stage cleaned tailings; and (5) conducting second-stage cleaning on the first-stage cleaned concentrates to obtain second-stage cleaned concentrates and second-stage cleaned tailings.

Description

technical field [0001] The invention belongs to the field of mineral processing, in particular to a method for recovering nickel-cobalt-copper from nickel polymetallic ore. Background technique [0002] Cobalt is a very important strategic element, known as "industrial monosodium glutamate", has the advantages of high melting point, good wear resistance, high mechanical strength, strong magnetism, etc., and is widely used in aviation, aerospace, machinery manufacturing, chemical industry and other industries department. With the rapid development of my country's economy, the demand for cobalt is increasing. Cobalt is mainly present in other minerals in the form of isomorphism. Nickel polymetallic ores generally contain associated valuable elements such as cobalt. However, the current process mainly considers the recovery of nickel and copper, and little attention is paid to the recovery of associated valuable elements cobalt, resulting in a waste of resources. [0003] Th...

Claims

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Application Information

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IPC IPC(8): B03B9/00B03D1/02
CPCB03B9/00B03D1/02Y02P10/20
Inventor 王亚运郭素红王传龙刘志国于传兵宋磊王鑫康金星
Owner CHINA ENFI ENGINEERING CORPORATION
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