Heat shrinkable film and preparation method and application thereof

A heat-shrinkable film and masterbatch technology, used in applications, other household appliances, chemical instruments and methods, etc., can solve the problems of inability to scan the product label, poor toughness of POF shrink film, slow shrinkage speed, etc., to achieve shrinkage speed. Fast, reduce the rate of breakage, the effect of low shrinkage temperature

Active Publication Date: 2020-04-10
江门市华龙膜材股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still many problems in the use of these two types of shrink films. For example, POF shrink film has poor toughness and is easy to break the package; ordinary PE shrink film has high shrinkage temperature, slow shrinkage speed, and low efficiency. If the outer layer of the package is PE The film is easy to melt and stick when passing through the drying tunnel, and its transparency is poor. It is impossible to scan and identify the packaged product label. It needs to be labeled on the outside of the film, which increases the process and reduces the efficiency.

Method used

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  • Heat shrinkable film and preparation method and application thereof
  • Heat shrinkable film and preparation method and application thereof
  • Heat shrinkable film and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 33% for the outer layer, 34% for the middle layer, and 33% for the inner layer; The components are shown in Table 1 below:

[0059] Table 1

[0060]

[0061] The melt index of the high-pressure low-density polyethylene in the outer layer component is 0.25g / 10min, and the density is 0.924g / cm 3 , specifically preferred 2420D produced by China Sea Shell Petrochemical Co., Ltd.; the melt index of the ethylene-vinyl acetate copolymer is 0.25g / 10min, and the density is 0.930g / cm 3 , the vinyl acetate (VA) content is 12%, specifically the 3135 that the preferred U.S. DuPont company produces.

[0062] The melt index of the ethylene-vinyl acetate copolymer described in the middle layer component is 1.5g / 10min, and the density is 0.930g / cm 3 , the ...

Embodiment 2

[0075] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 33% for the outer layer, 45% for the middle layer, and 22% for the inner layer; The components are shown in Table 3 below:

[0076] table 3

[0077]

[0078] Except that the anti-adhesive masterbatch is natural silica, the melt index, density and manufacturer of the components of each layer of the heat shrinkable film in this example are the same as in Example 1. The preparation method of the heat-shrinkable film of this embodiment is the same as that of Example 1, and the process parameters of the extruder are as shown in Table 4:

[0079] Table 4

[0080] temperature zone 1 Zone 2 District 3 District 4 District 5 pressure (bar) outer layer 141 145 147 143 142 182-238 Middle 135 138 143 141 137 16...

Embodiment 3

[0082] The heat-shrinkable film of this embodiment has a three-layer structure, which is an outer layer, a middle layer and an inner layer respectively. The weight percentages between the materials of the three layers are respectively: 25% for the outer layer, 50% for the middle layer, and 25% for the inner layer; The composition components are shown in Table 5 below:

[0083] table 5

[0084]

[0085]

[0086] Except that the anti-adhesive masterbatch is synthetic silica, the melt index, density and manufacturer of the components of each layer of the heat shrinkable film in this example are the same as those in Example 1. The preparation method of the heat-shrinkable film of this embodiment is the same as that of Example 1, and the process parameters of the extruder are as shown in Table 6:

[0087] Table 6

[0088] temperature zone 1 Zone 2 District 3 District 4 District 5 pressure (bar) outer layer 141 145 147 143 142 172-218 Mid...

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Abstract

The invention provides a high-performance heat shrinkable film which has the advantages of low shrinkage temperature, high shrinkage speed, low water vapor transmission rate, high transparency and thelike. The heat shrinkable film is prepared by adopting a three-layer co-extrusion film blowing method and comprises an outer layer, a middle layer and an inner layer. The mass ratio of the outer layer to the middle layer to the inner layer is (1-3): (1-3): (1-3); the outer layer comprises high-pressure low-density polyethylene, an ethylene-vinyl acetate copolymer, an anti-sticking master batch, asmooth master batch and an antistatic master batch; the middle layer comprises an ethylene-vinyl acetate copolymer and a propenyl elastomer; and the inner layer comprises high-pressure low-density polyethylene, metallocene low-density polyethylene, a propenyl elastomer, an anti-sticking master batch, a smooth master batch and an antistatic master batch. According to the heat shrinkable film, thetensile strength and the elasticity modulus are improved and the bag breaking rate is effectively reduced; the heat shrinkage rate reaches up to 75% after treatment at 130 DEG C for 20 seconds, the light transmittance is greater than 90% and the haze and glossiness are greatly improved.

Description

technical field [0001] The invention belongs to the technical field of polymer materials for packaging, and relates to a heat-shrinkable film, in particular to a heat-shrinkable film with good shrinkage efficiency and high transparency, a preparation method and an application thereof. Background technique [0002] With the increase of national environmental protection and energy saving efforts, some products packed in cartons are increasingly replaced by plastic packaging, and the increase in the consumption of plastic packaging products will definitely promote the technological progress and rapid development of the plastic packaging machinery industry. The economic macro and micro conditions are getting better, and social demand will show a steady growth, which is expected to stimulate the growth of plastic product consumption. In order to meet the requirements of the new era, plastic packaging materials are also required to meet the increasing packaging quality and efficie...

Claims

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Application Information

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IPC IPC(8): B32B27/32B32B27/08B32B27/30B32B27/18B32B33/00C08L23/06C08L23/08C08L101/02C08J5/18B29D7/01B65D65/02
CPCB32B27/32B32B27/08B32B27/306B32B27/18B32B27/327B32B33/00B29D7/01C08J5/18B65D65/02C08J2323/06C08J2423/08C08J2323/08C08J2400/10B32B2307/558B32B2307/54B32B2307/406B32B2250/246B32B2250/03
Inventor 文斌森魏洪媚
Owner 江门市华龙膜材股份有限公司
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