Polypeptide RS-17 with anti-CD47 immune checkpoint antagonistic activity and application thereof
An immune checkpoint, RS-17 technology, applied in the field of peptides that block the binding of CD47 on the surface of tumor cells and its corresponding ligands, can solve the problems of no research reports on small molecule drugs or peptide drugs, and achieve the inhibition of CD47/SIRPα pathway , Eliminate immunosuppression, weak effects of toxic and side effects
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Embodiment 1
[0049] Embodiment 1RS-17 synthetic product quality detection
[0050] Synthetic RS-17 polypeptide, its sequence is: RRYKQDGGWSHWSPWSS-NH 2 . Its relative molecular mass, yield and purity and other property information were measured by mass spectrometry (Mass Spectrometry, MS) and high performance liquid chromatography (High Performance Liquid Chromatography\HPLC).
[0051] The specific chromatographic conditions are:
[0052] Analytical chromatographic column: SinoChrom ODS-BP, 250mm×4.6mm (5μm filler);
[0053] Mobile phase: Phase A is water (100%), phase B is acetonitrile (100%);
[0054] Loading volume: 20μL;
[0055] Flow rate: 1mL / min;
[0056] Detection wavelength: 220nm;
[0057] Elution gradient: see Table 1.
[0058] Table 1 The elution gradient for detecting the modification yield
[0059]
[0060] Its MS report is identical to the HPLC report such as figure 1 , figure 2 show. The results showed that the relative molecular mass of RS-17 was 2120.29g / mo...
Embodiment 2
[0061] Example 2 MST intermolecular interaction analysis between polypeptide RS-17 and CD47 protein
[0062] Microthermophoresis (MST) is a technique for the analysis of biomolecules. Microscale thermophoresis is the directional movement of particles in a microscopic temperature gradient. Relative changes in motion along temperature gradients due to changes in hydration layers caused by changes in biomolecular structure / conformation can be used to determine affinity (K d value).
[0063] In this part of the examples, the polypeptide RS-17 (RRYKQDGGGWSHWSPWSS-NH 2 ) as an object to study the interaction between it and CD47 extracellular segment recombinant protein (Ala18-Glu141) in vitro.
[0064] 1.1 Experimental materials
[0065] Polypeptide RS-17 (RRYKQDGGWSHWSPWSS-NH 2 ); human recombinant protein CD47 (Ala18~Glu141, Cloud-Clone, USA)
[0066] 1.2 Experimental Instruments
[0067] Monolith NT.115MST micro-thermophoresis instrument (German nanotemper company); Capill...
Embodiment 3
[0079] Western blot detected tumor cell lines with high expression of CD47 and lymphocyte cell lines with high expression of SIRPα as positive cells, which were subsequently used to detect the blocking effect of polypeptides on the CD47 / SIRPα pathway.
[0080] 1.1 Experimental materials
[0081] Human liver cancer cell HepG2: Shanghai Chunmai Biotechnology Co., Ltd.; human epidermal squamous cell carcinoma cell SCC-13: human mononuclear lymphoma cell THP-1: Shanghai Chunmai Biotechnology Co., Ltd.; mouse macrophage lymphoma cell RAW264.7: cell culture Bottle of American Thermo Company; cell culture medium: Gibco Company of the United States; rabbit anti-human / mouse CD47 antibody: BioXcell Company of the United States; rabbit anti-human / mouse SIRPα antibody: Wanlei Biotechnology Co., Ltd.; rabbit anti-human / mouse GAPDH antibody: Linktech bio ltd. HRP Goatanti-Rabbit IgG: Lianke Biological Co., Ltd.
[0082] 1.2 Experimental Instruments
[0083] Inverted microscope (Japan OLY...
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