Degradable ureteral stent and manufacturing method thereof
A ureteral stent tube and a manufacturing method technology are applied in the field of degradable ureteral stent tube and its manufacture, can solve the problems of loss or even need to remove the kidney, bleeding and tissue damage, poor tissue compatibility, etc., and achieve good mechanical support performance, degradation The effect of prolonging the speed and improving the mechanical properties
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Embodiment 1
[0036] Such as figure 1 As shown, the degradable ureteral stent in the present invention is composed of polycaprolactone adventitia layer 1, polyglycolide fiber and polyglycolide-lactide fiber braiding layer 2, L-lactide-ε- Caprolactone copolymer / graphene inner film layer 3 composition.
[0037] The graphene layer of the inner membrane layer 3 is single-layer graphene with a thickness of 0.3 nm, and the thickness of each L-lactide-ε-caprolactone copolymer layer is 0.1 μm.
[0038] The preparation method of the inner film layer 3 comprises: (1) the L-lactide-ε-caprolactone copolymer solution is attached to the graphene / copper sheet with the graphene side by spin coating method or casting method, and air-dried 10h; then etch the copper sheet in ammonium persulfate solution, etch at room temperature for 8h to obtain L-lactide-ε-caprolactone copolymer / graphene film; (2) L-lactide-ε -Transfer the caprolactone copolymer / graphene film to the surface of the graphene / copper sheet, ma...
Embodiment 2
[0047] The degradable ureteral stent tube in the present invention is composed of polylactic acid outer membrane layer 1, polydioxanone fiber and polytrimethylene carbonate fiber braided layer 2, L-lactide-ε-caprolactone copolymer / The graphene inner film layer 3 is composed.
[0048] The graphene layer of the inner membrane layer 3 is single-layer graphene with a thickness of 0.4 nm, and the thickness of each L-lactide-ε-caprolactone copolymer layer is 1 μm.
[0049] The preparation method of the inner film layer 3 comprises: (1) the L-lactide-ε-caprolactone copolymer solution is attached to the graphene / copper sheet with the graphene side by spin coating method or casting method, and air-dried 10h; then etch the copper sheet in ammonium persulfate solution, etch at room temperature for 8h to obtain L-lactide-ε-caprolactone copolymer / graphene film; (2) L-lactide-ε -Transfer the caprolactone copolymer / graphene film to the surface of the graphene / copper sheet, make the side of...
Embodiment 3
[0058] The degradable ureteral stent tube in the present invention is composed of polyglycolide outer membrane layer 1, polyhydroxyalkanoate fiber and polylactic acid-glycolic acid copolymer fiber braiding layer 2, L-lactide-ε-caprolactone Copolymer / graphene inner film layer 3 composition.
[0059] The graphene layer of the inner membrane layer 3 is single-layer graphene with a thickness of 0.35 nm, and the thickness of each L-lactide-ε-caprolactone copolymer layer is 2 μm.
[0060] The preparation method of the inner film layer 3 comprises: (1) the L-lactide-ε-caprolactone copolymer solution is attached to the graphene / copper sheet with the graphene side by spin coating method or casting method, and air-dried 10h; then etch the copper sheet in ammonium persulfate solution, etch at room temperature for 8h to obtain L-lactide-ε-caprolactone copolymer / graphene film; (2) L-lactide-ε -Transfer the caprolactone copolymer / graphene film to the surface of the graphene / copper sheet, m...
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Abstract
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