The invention discloses a preparation method and a sealing process of an explosion-proof primary
lithium battery cover group and sealing glass. A
glass material which is resistant to
electrolyte corrosion, excellent in electrochemical performance, controllable in
mechanical strength and used for sealing the primary
lithium battery cover group is provided, and the
compressive strength of the glass is controlled by designing glass components and the sealing thickness. The explosion-proof principle is that when the
internal pressure of the battery is greater than the designed pressure in the use process, namely the pressure of the battery is overloaded, the pressure-bearing strength of the
glass material is just reached, so that the glass is cracked, the
internal pressure of the battery is slowly released, and the battery does not have dangerous situations such as violent explosion. The shell is made of stainless steel series and
carbon steel series, the stainless steel series comprises 304L, 316L and the like, and the core column is made of series iron-
nickel alloys such as alloys 4J28, 4J50, 4J52 and the like. A SiO2-B2O3-BaO-Na2O3 glass
system is selected as a main body, and various
metal oxides are added to adjust the
thermal expansion coefficient, the glass
softening temperature, the
chemical stability and the mechanical properties of the glass.