Aqueous dispersant based on polyacrylate structure
A technology of acrylate and wetting and dispersing agent, which is applied in application, coating, ink, etc., can solve problems such as poor fluidity, poor compatibility, and poor dispersibility, so as to prevent flocculation, excellent comprehensive dispersion performance, The effect of improving wetting ability and hydrophilic ability
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Embodiment 1
[0041] Add 600 parts of butyl acetate to a four-neck flask equipped with a thermometer, top stirrer, gas inlet and condenser, set the stirring speed to 200rpm, start stirring, and feed nitrogen, turn on the heating device, and set the reaction temperature to 126°C . At the same time, add 800 parts of polyethylene glycol monomethyl ether (400) of methacrylic acid in the beaker, 344 parts of Daicel FA2D monomer, 31.4 parts of dimethylaminoethyl methacrylate and 17.63 parts of benzene peroxide Formyl, and stir to mix well, set aside. When the temperature of the material in the flask is stable to 126°C, start to drop the mixed solution through the peristaltic pump. After the uniform dropwise addition within 3 hours, keep the temperature at 126°C for 2 hours, then cool down to 110°C, and depressurize at this temperature The solvent butyl acetate was pumped off. The temperature was lowered to room temperature, whereby Dispersion Agent 1 was obtained.
Embodiment 2
[0043] In a four-neck flask equipped with a thermometer, top stirrer, gas inlet and condenser, add 1040 parts of butyl acetate, set the stirring speed to 200rpm, start stirring, and feed nitrogen, turn on the heating device, and set the reaction temperature to 126°C . At the same time, add 1500 parts of polyethylene glycol monomethyl ether (750) of methacrylic acid in the beaker, 458 parts of Daicel FA3 monomer, 31.4 parts of dimethylaminoethyl methacrylate and 29.84 parts of benzene peroxide Formyl, and stir to mix well, set aside. When the temperature of the material in the flask is stable to 126°C, start to drop the mixed solution through the peristaltic pump. After the uniform dropwise addition within 3 hours, keep the temperature at 126°C for 2 hours, then cool down to 110°C, and depressurize at this temperature The solvent butyl acetate was pumped off. The temperature was lowered to room temperature, whereby Dispersion Agent 2 was obtained.
Embodiment 3
[0045] In a four-neck flask equipped with a thermometer, top stirrer, gas inlet and condenser, add 1310 parts of butyl acetate, set the stirring speed to 200rpm, start stirring, and feed nitrogen, turn on the heating device, and set the reaction temperature to 126°C . At the same time, add 2000 parts of methacrylic acid polyethylene glycol monomethyl ether (1000) in the beaker, 537 parts of Daicel FM2D monomer, 42 parts of 2-vinylpyridine and 38.68 parts of benzoyl peroxide, And stir to mix well, set aside. When the temperature of the material in the flask is stable to 126°C, start to drop the mixed solution through the peristaltic pump. After the uniform dropwise addition within 3 hours, keep the temperature at 126°C for 2 hours, then cool down to 110°C, and depressurize at this temperature The solvent butyl acetate was pumped off. The temperature was lowered to room temperature, whereby Dispersion 3 was obtained.
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