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Application of copper pollution prevention synergist to improvement of copper pollution prevention performance of nylon flame-retardant material

A technology for flame retardant materials and copper pollution, which is applied in the fields of improving the anti-copper pollution performance of nylon flame retardant materials and anti-copper pollution synergists, can solve problems to be improved, and achieve easy industrialized large-scale production, slowing down the formation of copper ions, Prepare simple effects

Active Publication Date: 2020-05-01
中广核俊尔(浙江)新材料有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The nylon materials of the above patented technologies all have a certain resistance to metal corrosion, but there is still room for improvement

Method used

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  • Application of copper pollution prevention synergist to improvement of copper pollution prevention performance of nylon flame-retardant material
  • Application of copper pollution prevention synergist to improvement of copper pollution prevention performance of nylon flame-retardant material
  • Application of copper pollution prevention synergist to improvement of copper pollution prevention performance of nylon flame-retardant material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Use the following weights of ingredients:

[0046]

[0047] Mix polyamide, reinforcing / filling components and processing aids evenly, and feed them into the twin-screw extruder from the main feed, and then mix the flame retardant, anti-copper pollution agent and anti-copper pollution synergist evenly, and feed them from the side Add the twin-screw extruder, and after extruding, drawing, cooling, pelletizing and drying, the nylon flame-retardant material that prevents copper pollution can be obtained. Among them, the aspect ratio of the twin-screw extruder is 36:1, and the temperature of each section of the screw is: the temperature of each working section from the first barrel to the eighth barrel is 265±5°C, 265±5°C, 265°C ±5℃, 265±5℃, 245±5℃, 245±5℃, 245±5℃, 225±5℃, the temperature of the head is 255±5℃.

Embodiment 2

[0049] Use the following weights of ingredients:

[0050]

[0051] The preparation method of the nylon flame-retardant material that prevents copper pollution is the same as in Example 1. The temperature of each section of the screw is: the temperature of each working section from the first barrel to the eighth barrel is 260±5°C, 260±5°C, 260±5°C, 250±5°C, 230±5°C, 230±5°C 5°C, 230±5°C, 230±5°C, the temperature of the machine head is 260±5°C.

Embodiment 3

[0053] Use the following weights of ingredients:

[0054]

[0055]

[0056] The preparation method of the nylon flame-retardant material that prevents copper pollution is the same as in Example 1. The temperature of each section of the screw is: the temperature of each working section from the first barrel to the eighth barrel is 240±5°C, 240±5°C, 240±5°C, 230±5°C, 230±5°C, 230±5°C 5°C, 230±5°C, 230±5°C, the temperature of the machine head is 230±5°C.

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Abstract

The invention discloses application of a copper pollution prevention synergist to improvement of the copper pollution prevention performance of a nylon flame-retardant material. The raw materials of the nylon flame-retardant material comprise polyamide, a flame retardant and a copper pollution prevention agent, wherein the copper pollution prevention agent is at least one selected from the group consisting of an antioxidant anti-copper inhibitor ST-697 and an antioxidant anti-copper inhibitor 1024. The copper pollution prevention synergist is also used a raw material composition of the nylon flame-retardant material and comprises a component A, wherein the component A is at least one selected from the group consisting of ethylenediamine tetraacetic acid and disodium ethylenediamine tetraacetate. The nylon flame-retardant material is prepared from the following raw materials in percentage by weight: 20%-75% of polyamide, 0.5%-5% of the copper pollution prevention agent, 0.5%-5% of the copper pollution prevention synergist, 10%-20% of the flame retardant, 10%-45% of a reinforcing / filling component and 0.5%-5% of a processing aid.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to the use of an anti-copper pollution synergist for improving the anti-copper pollution performance of nylon flame-retardant materials. Background technique [0002] Polyamide (commonly known as nylon) materials are widely used in all walks of life after flame retardant and enhanced modification, especially in industrial electrical appliances and household appliances, most of which contain copper-based components. [0003] Nylon materials are easy to absorb water, and some flame retardants, such as brominated flame retardants, red phosphorus flame retardants, organic phosphine flame After high and low temperature and high humidity, some acids will come into contact with copper and copper oxides, and copper ions will appear on the surface of copper metal or plastic. Copper ions are easy to form variegated substances with other substances, such as copper sulfide (black), A...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08L77/02C08K13/04C08K7/14C08K5/3492C08K5/00C08K5/526C08K5/17C08K3/22C08K3/02C08K5/03
CPCC08L77/06C08K13/04C08K7/14C08K5/03C08K5/005C08K5/526C08K5/175C08K3/22C08K3/2279C08L2201/02C08L2201/08C08L2205/02C08K2003/2296C08K2003/026C08K2003/2206C08L77/02C08K5/34928C08K3/02
Inventor 田际波陈晓敏陈佰全郑友明李俊王金松
Owner 中广核俊尔(浙江)新材料有限公司
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