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Method for producing photocatalyst material, method for producing material for photoelectric conversion elements, method for producing wear-resistant member, method for producing member for preventing deterioration of edible oils, photocatalyst material, material for photoelectric conversion elements, wear-resistant member, and member for preventing deterioration of edible oils

A manufacturing method and titanium oxide technology, applied in the field of metal titanium materials or titanium alloy materials, can solve problems such as high-cost cooling devices

Inactive Publication Date: 2020-05-01
가부시키가이샤에스오더블유
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, in this method, in order to suppress the heat generation of the electrolytic solution accompanying spark discharge, an expensive cooling device is required.

Method used

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  • Method for producing photocatalyst material, method for producing material for photoelectric conversion elements, method for producing wear-resistant member, method for producing member for preventing deterioration of edible oils, photocatalyst material, material for photoelectric conversion elements, wear-resistant member, and member for preventing deterioration of edible oils
  • Method for producing photocatalyst material, method for producing material for photoelectric conversion elements, method for producing wear-resistant member, method for producing member for preventing deterioration of edible oils, photocatalyst material, material for photoelectric conversion elements, wear-resistant member, and member for preventing deterioration of edible oils
  • Method for producing photocatalyst material, method for producing material for photoelectric conversion elements, method for producing wear-resistant member, method for producing member for preventing deterioration of edible oils, photocatalyst material, material for photoelectric conversion elements, wear-resistant member, and member for preventing deterioration of edible oils

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0190] Average surface roughness (Ra) of titanium material with crystalline titanium oxide coating formed on the surface

[0191] (1-1) Step 1: Preparation of roughened titanium material

[0192] In order to compare the formation amount of anatase-type titanium oxide, materials were prepared under two conditions: the case of performing shot peening and the case of not performing shot peening.

[0193] In the case of the material subjected to shot blasting, the surface of the substrate was roughened on a metal titanium plate (titanium material, photoelectrode substrate) using a shot blasting apparatus (BA-1: direct pressure type, manufactured by Thick Bottom Iron Works).

[0194] First, a metal titanium plate and an abrasive (abrasive material) (alumina #150 manufactured by Nippon Lagoonite, alumina particle size 63 μm to 74 μm) were installed in the apparatus. Next, air was sucked in by the compressor, and the pressure was adjusted to 0.5 MPa.

[0195] Sandblasting was p...

Embodiment 2

[0224] Amount of crystalline titanium oxide film formed on the surface of titanium material

[0225] (2-1) Manufacture of anodized titanium material

[0226] In order to compare the formation amount of anatase-type titanium oxide (crystalline titanium oxide film), materials were prepared under two conditions: the case of performing shot peening and the case of not performing shot peening.

[0227] In the case of a material subjected to shot blasting, the surface of the substrate was roughened on a metal titanium plate (titanium material, photoelectrode substrate) using a blasting treatment device (BA-1: direct pressure type, manufactured by Atsushiki Works).

[0228] First, a metal titanium plate and an abrasive (abrasive material) (alumina #150 manufactured by Nippon Lagoonite, alumina particle size 63 μm to 74 μm) were installed in the apparatus. Next, air was sucked in by the compressor, and the pressure was adjusted to 0.5 MPa.

[0229] Abrasives (sweeping materials)...

Embodiment 3

[0247] Photocatalytic activity of titanium material with crystalline titanium oxide coating on its surface

[0248] (3-1) Manufacture of anodized titanium material

[0249] The surface of the substrate was roughened on the metal titanium plate (titanium material, photoelectrode substrate) using a sand blasting treatment device (BA-1 direct pressure type, manufactured by Atsushiki).

[0250] First, a metal titanium plate and an abrasive (abrasive material) (alumina #150 manufactured by Nippon Lagoonite, alumina particle size 63 μm to 74 μm) were installed in the apparatus. Next, air was sucked in by the compressor, and the pressure was adjusted to 0.5 MPa.

[0251] Abrasives (sweeping materials) are fired toward the substrate by direct pressure, and shot blasting is performed on one side for 30 seconds. Shot blasting is performed on both sides of the substrate.

[0252] Next, after degreasing the shot-peened titanium metal plate with trichlorethylene, a nitriding furnace...

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Abstract

The purpose of the present invention is to produce a titanium material, on the surface of which a crystalline titanium oxide film is formed. This titanium material, on the surface of which a crystalline titanium oxide film is formed, is useful as a photocatalyst material that exhibits a high function, a material for photoelectric conversion elements, a wear-resistant member, a member for preventing deterioration of edible oils, and the like. A method for producing a titanium material, on the surface of which a crystalline titanium oxide film is formed, according to the present invention is characterized by comprising: (1) a step for forming a surface roughened material by subjecting the surface of a titanium material to a surface roughening treatment; (2) a step for forming a titanium compound on the surface of the surface roughened material; (3) a step for forming an amorphous titanium oxide film by subjecting the material, on the surface of which a titanium compound is formed, to anodic oxidation; and (4) a step for forming a crystalline titanium oxide film by heating the material, on the surface of which an amorphous titanium oxide film is formed, at a temperature of 300 DEG C or higher in the atmosphere.

Description

technical field [0001] The present invention relates to a method for producing a titanium metal material or a titanium alloy material having a crystalline titanium oxide coating on its surface, and a titanium metal material or titanium alloy material having a crystalline titanium oxide coating on its surface obtained by the production method. Background technique [0002] Since titanium oxide is a photocatalyst material that decomposes various harmful substances and can be produced by a simple method, it is expected to be applied to dye-sensitized solar cells that are attracting attention as next-generation solar cells. As the crystal structure of titanium oxide, there are three types of rutile type, brookite type and anatase type. Among the above three crystal structures, it is known that anatase-type titanium oxide is excellent in photocatalytic properties and photoelectric conversion properties of dye-sensitized solar cells. [0003] Patent Document 1 is to (i) form tita...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C28/04B01J27/24B01J35/02C01G23/04B01J35/00
CPCC01G23/04C23C28/04C25D11/26B01J37/348B01J37/08B01J37/06B01J37/347B01J37/0238B01J37/349B01J37/0217B01J37/0225B01J37/0232B01J35/39B01J35/70B01J35/38B01J35/54B01J2235/15C23C28/042C23C8/02C23C8/24C25D11/34B01J27/24B01J35/50B01J27/22B01J37/0226
Inventor 高桥大辅高安辉树
Owner 가부시키가이샤에스오더블유