Application of compound, non-aqueous electrolyte, and lithium ion secondary battery
A non-aqueous electrolyte and compound technology, used in secondary batteries, secondary battery repair/maintenance, circuits, etc., can solve the problem of insufficient wide temperature performance of lithium-ion batteries, unsatisfactory battery stability research results, and no Research on long-term cycle characteristics of batteries, etc., to achieve the effects of excellent discharge load characteristics, low internal resistance, and inhibition of gas generation
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Embodiment 1
[0078] This embodiment provides a lithium-ion secondary battery, the preparation process of which is as follows:
[0079] (1) Preparation of positive electrode sheet of lithium secondary battery
[0080] The positive electrode active material lithium nickel cobalt manganese oxide (LiNi 0.6 co 0.2 mn 0.2 o 2 ), the conductive agent Super-P, and the binder PVDF are dissolved in the solvent N-methylpyrrolidone at a mass ratio of 96:2.0:2.0 and mixed evenly to make a positive electrode slurry, and then the positive electrode slurry is evenly coated on the current collector aluminum foil , coating amount is 0.018g / cm 2 , followed by drying at 85°C, cold pressing, trimming, cutting, and stripping, and then drying at 85°C for 4 hours under vacuum conditions, welding the tabs, and making a positive electrode sheet of a lithium secondary battery that meets the requirements.
[0081] (2) Preparation of the negative electrode sheet of the lithium secondary battery
[0082] Negative...
Embodiment 2~4
[0089] Embodiments 2 to 4 provide a lithium-ion secondary battery. The preparation method of the positive and negative plates of the lithium-ion secondary battery and the lithium-ion battery is the same as that of Example 1, and the preparation method of the electrolyte is also the same as that of Example 1, except that The difference is that in the electrolyte, the mass of lithium sulfate (I-1) containing hydroxyl lithium has different percentages in the total mass of the electrolyte.
[0090] In Example 2, the mass of lithium sulfate (I-1) containing hydroxyl lithium accounts for 0.1% of the total mass of the electrolyte.
[0091] In Example 3, the mass of lithium sulfate (I-1) containing hydroxyl lithium accounts for 0.3% of the total mass of the electrolyte.
[0092] In Example 4, the mass of lithium sulfate (I-1) containing hydroxyl lithium accounts for 1% of the total mass of the electrolyte.
Embodiment 5
[0094] Embodiment 5 provides a kind of lithium ion secondary battery, the difference with the preparation method of the lithium ion secondary battery of embodiment 1 is that the solvent is cyclic fluoroethylene carbonate (FEC) and ethylene carbonate (EC) Mix with dimethyl carbonate (DMC) in mass ratio FEC:EC:DMC=3:1:2, and the rest of the steps and raw materials are the same as in Example 1.
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