An environment-friendly high temperature and salt resistant calcium modified natural polymer fluid loss reducer

A technology of natural polymer and fluid loss reducer, which is applied in the direction of chemical instruments and methods, drilling compositions, etc. It can solve the problems of low temperature resistance, reduced mud cake bound water content, poor salt and calcium resistance, etc. , to achieve the effect of reducing fluid loss, good compatibility, and strong wall-building effect

Active Publication Date: 2022-06-03
CHINA UNIV OF PETROLEUM (EAST CHINA) +1
View PDF0 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Under the conditions of high temperature and high salinity in drilling fluid, the hydration effect of fluid loss control agent in drilling fluid is greatly weakened, the solubility is reduced, and then the adsorption effect on the surface of clay particles is weakened, and the dehydration effect on the surface of clay particles is consequently reduced. The hydration layer on the surface of clay particles becomes thinner, which leads to a decrease in the irreducible water content of the mud cake, and a weakening of the compressibility of the mud cake, which eventually makes the compactness of the mud cake worse, the fluid loss increases, and the drilling fluid fluid loss creates a wall. deterioration, affecting the normal progress of drilling construction
[0003] At present, high temperature resistant fluid loss reducers (such as lignite resin products) have poor resistance to salt and calcium, while salt and calcium resistant fluid loss reducers (such as conventional modified starch products) have low temperature resistance; Fluid loss reducers (such as modified asphalt products) that are resistant to salt and calcium at high temperatures have high toxicity and poor environmental protection performance, which seriously restricts the normal operation of drilling operations in high-temperature deep wells and high-salt conditions

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] An environment-friendly, high-temperature-resistant, salt-resistant, calcium-modified natural polymer fluid loss reducer mentioned in the present invention is composed of: 25% of pregelatinized starch, 5% of partially hydrolyzed polyacrylamide, 4% of aluminum citrate, ultrafine Calcium carbonate 15%, the balance is deionized water; wherein,

[0025] The partially hydrolyzed polyacrylamide is a commercially available tackifier for polyacrylamide drilling fluid, the relative molecular mass is 3 million, and the degree of hydrolysis is within the range of 20%; the aluminum citrate is a commercially available crosslinking agent product; The superfine calcium carbonate is a commercially available oil and gas reservoir protective agent for drilling fluids, with a particle size range of 400 meshes.

[0026] The preparation method of the present invention comprises the following steps:

[0027] (1) First, dissolve the partially hydrolyzed polyacrylamide in a kneader with an ap...

Embodiment 2

[0036] The environment-friendly, high-temperature, salt-resistant, calcium-modified natural polymer fluid loss reducer mentioned in the present invention is composed of: 20% of carboxymethyl starch, 7% of partially hydrolyzed polyacrylamide, 6% of aluminum citrate, ultrafine Calcium carbonate 20%, the balance is distilled water;

[0037] The partially hydrolyzed polyacrylamide is a commercially available tackifier for polyacrylamide drilling fluid, the relative molecular mass is 5 million, and the degree of hydrolysis is within the range of 40%; the aluminum citrate is a commercially available crosslinking agent product; The superfine calcium carbonate is a commercially available oil and gas layer protective agent for drilling fluids, and the particle size range is in the range of 1200 meshes.

[0038] According to the production steps of Example 1, product 2 was prepared.

Embodiment 3

[0040] An environment-friendly, high-temperature, salt-resistant, calcium-modified natural polymer fluid loss reducer mentioned in the present invention is composed of: cationic starch starch 30%, partially hydrolyzed polyacrylamide 5%, aluminum citrate 3%, ultrafine carbonic acid Calcium 10%, the balance is drinking tap water;

[0041] The partially hydrolyzed polyacrylamide is a commercially available flocculant for polyacrylamide drilling fluid, the relative molecular mass is 4 million, and the degree of hydrolysis is within the range of 30%; the aluminum citrate is a commercially available crosslinking agent product; the Ultrafine calcium carbonate is a commercially available oil and gas reservoir protective agent for drilling fluids, with a particle size range of 800 mesh.

[0042] According to the preparation steps of Example 1, product three was prepared.

[0043] According to the API experimental procedure, 2% of the three examples of products were added to the satura...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle size (mesh)aaaaaaaaaa
particle sizeaaaaaaaaaa
particle size (mesh)aaaaaaaaaa
Login to view more

Abstract

The invention relates to an environment-friendly high temperature and salt resistant calcium modified natural polymer fluid loss reducer. Its technical solution is: it is made of the following components, by mass percentage: 20%-30% of modified starch, 3%-8% of partially hydrolyzed polyacrylamide, 3%-5% of aluminum citrate, and 10% of superfine calcium carbonate %‑20%, the balance is water. Beneficial effects are: the present invention is aimed at the downhole complex situation of high-temperature deep well drilling, especially the brine layer, salt rock layer, salt-gypsum layer, and gypsum-mud layer. High temperature and salt-resistant calcium fluid loss reducer is the key to improving the wall-building ability of drilling fluid; the product prepared by the present invention has outstanding fluid loss reducing effect, strong wall-building, temperature resistance up to 150°C and above, salt resistance to saturation, Resistant to 0.5% CaCl 2 . The product has good compatibility with other treatment agents, is non-toxic and environmentally friendly, and can also be used as a protection material for drilling fluid oil and gas layers.

Description

technical field [0001] The invention relates to a fluid loss reducer for drilling fluid and completion fluid, in particular to an environment-friendly, high temperature, salt and calcium modified natural polymer fluid loss reducer. Background technique [0002] Drilling fluid is the working fluid in the oil drilling process. Fluid loss and wall-building is one of the most basic properties of drilling fluids. The main factor affecting the wall-building performance of fluid loss is the quality of the drilling fluid filter cake. A high-quality filter cake has the characteristics of thin thickness, good density, high toughness and good lubricity. The compressibility of the filter cake is the key to determining the quality of the filter cake. important factor in compressibility. Therefore, the key to the control of drilling fluid filtration and wall-building is to maintain a certain amount of fine particles that can be fully hydrated in the drilling fluid. In water-based drill...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/035
CPCC09K8/035C09K8/032
Inventor 王富华孙希腾王路一张卫东王志遵于敦源鞠加銮
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products