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Method for preparing inert aluminum oxide chemical filler from activated aluminum oxide ball industrial solid waste hazardous waste

A technology of activated alumina and ball industry, applied in the field of ceramic fillers, can solve the problems of high raw material price and cost, affecting product performance, single source of raw material, etc., achieve good mechanical properties, improve thermal conductivity and thermal shock resistance, and source of raw materials wide effect

Active Publication Date: 2020-05-26
山东中和金石科技集团股份有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] In the prior art, there are many methods for preparing inert alumina chemical fillers, but the source of raw materials is single and the price of raw materials is high. If some solid waste and hazardous waste alumina powder is used to prepare fillers, the sintering temperature is high, the cost is high and the obtained The purity of the product is low, which affects the performance of the product

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  • Method for preparing inert aluminum oxide chemical filler from activated aluminum oxide ball industrial solid waste hazardous waste

Examples

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Comparison scheme
Effect test

Embodiment 1

[0027] The method for preparing inert alumina chemical filler by using activated alumina ball industrial solid waste and hazardous waste comprises the following steps:

[0028] (1) 10 parts of α-alumina powder, 10 parts of kaolin, 3 parts of barium carbonate, 3 parts of dolomite, 10 parts of calcium bicarbonate, 3 parts of calcined talc, 8 parts of clay Put them into a ball mill respectively, carry out wet ultra-fine grinding, and then sieve to remove iron to obtain nano-ceramic slurry;

[0029] (2) the nano-ceramic mud that step (1) is obtained and the water of 300% of nano-ceramic mud quality and the graphite of 10% of nano-ceramic mud quality are mixed, stir, then be placed in the water vapor environment of 100 ℃ and keep warm for 1 hour, keep warm At the same time, continue to feed carbon dioxide gas into it and stir at the same time, add acid to control the pH value to 3, and form aluminum sol;

[0030] (3) adding zirconium sol accounting for 5% of the mass of the alumin...

Embodiment 2

[0035] The method for preparing inert alumina chemical filler by using activated alumina ball industrial solid waste and hazardous waste comprises the following steps:

[0036] (1) 40 parts of α-alumina powder, 3 parts of kaolin, 1 part of barium carbonate, 1 part of dolomite, 6 parts of calcium bicarbonate, 1 part of calcined talc, and 20 parts of clay were mixed with activated alumina ball industrial solid waste and hazardous waste raw material α-alumina powder Put them into a ball mill respectively, carry out wet ultra-fine grinding, and then sieve to remove iron to obtain nano-ceramic slurry;

[0037] (2) the nano-ceramic mud that step (1) obtains and the graphite of 500% water of nano-ceramic mud quality and nano-ceramic mud quality 5% are mixed, stir, then be placed in the water vapor environment of 110 ℃ and be incubated 2 hours, heat preservation At the same time, continue to feed carbon dioxide gas into it and stir at the same time, add acid to control the pH value to...

Embodiment 3

[0043] The method for preparing inert alumina chemical filler by using activated alumina ball industrial solid waste and hazardous waste comprises the following steps:

[0044] (1) 25 parts of α-alumina powder, 8 parts of kaolin, 2 parts of barium carbonate, 2 parts of dolomite, 7 parts of calcium bicarbonate, 2 parts of calcined talc, and 15 parts of clay were mixed with activated alumina ball industrial solid waste and hazardous waste raw material α-alumina powder Put them into a ball mill respectively, carry out wet ultra-fine grinding, and then sieve to remove iron to obtain nano-ceramic slurry;

[0045] (2) the nano-ceramic mud that step (1) is obtained and the water of 400% of nano-ceramic mud quality and the graphite of nano-ceramic mud quality 8% are mixed, stir, then be placed in the water vapor environment of 100 ℃ and be incubated 2 hours, heat preservation At the same time, continue to feed carbon dioxide gas into it and stir at the same time, add acid to control t...

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Abstract

The invention relates to a method for preparing inert aluminum oxide chemical filler from activated aluminum oxide ball industrial solid waste hazardous waste, which belongs to the technical field ofceramic filler. The preparation method comprises the following steps of: (1) respectively putting raw materials into a ball mill, carrying out wet ultrafine grinding, and then sieving to remove iron,so as to obtain nano ceramic slurry, (2) mixing and stirring the nano ceramic slurry, water and graphite, then placing the mixture in a water vapor environment for heat preservation, and adding acid to control the pH value to form alumina sol, (3) adding zirconium sol into the aluminum sol, and then drying to obtain xerogel, (4) granulating the xerogel, and pressing into a green body, and (5) drying the green body, and adding a mineralizing agent for firing to obtain the inert aluminum oxide chemical filler. According to the method, the industrial solid waste hazardous waste activated aluminumoxide balls are fully utilized, the raw material source is wide, the cost is low, the sintering temperature is low, the purity of the prepared product is high, the performance of the product is improved, and the method has wide applicability.

Description

technical field [0001] The invention relates to a method for preparing an inert alumina chemical packing by using activated alumina ball industrial solid waste and hazardous waste, and belongs to the technical field of ceramic packing. Background technique [0002] Chemical packing is the basic component of gas-liquid contact in packed towers. It is widely used in many industries. It has excellent acid and heat resistance, and can resist the corrosion of various inorganic acids, organic acids and organic solvents except hydrofluoric acid. Its application The range is very wide, and it can be used in various high and low occasions. Its performance is the main factor that determines the operation performance of the packed tower. [0003] Chemical fillers can be divided into three categories according to materials: ceramic fillers, plastic fillers, and metal fillers. Ceramic packing has excellent acid and heat resistance, and can resist the corrosion of various acids and alkal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/10C04B35/624
CPCC04B35/10C04B35/62204C04B35/624C04B2235/425C04B2235/3244C04B2235/349C04B2235/442C04B2235/6562C04B2235/6567C04B2235/6565C04B2235/96C04B2235/9692C04B2235/9607C04B2235/77
Inventor 王超齐志利
Owner 山东中和金石科技集团股份有限公司