A kind of waterproof grade pvb film and preparation method thereof

Abstract

The invention belongs to the technical field of laminated glass, and particularly relates to a waterproof PVB film and a preparation method thereof. The waterproof PVB film prepared in the invention comprises the following raw materials: PVB resin powder, triethylene glycol di-2-ethylhexoate, an antioxidant, an ultraviolet absorbent, a silane coupling agent, a binding power regulator and SGP. Thewaterproof PVB film has good adhesion to glass, presents good waterproof performance, can be widely applied to automobiles, and has remarkable economic and social benefits.

Description

technical field

[0001] The invention belongs to the technical field of laminated glass, and in particular relates to a waterproof grade PVB film and a preparation method thereof. Background technique

[0002] In recent years, with the rapid development of construction and automobile industries, PVB film is also called PVB film or PVB interlayer. It is the best material for making laminated safety glass in the world today. PVB film is made of PVB resin, which is non-toxic, odorless, non-corrosive, non-flammable, and has good light transmission, insulation, weather resistance, wear resistance, water resistance, oil resistance, and aging resistance. Plexiglass has special adhesion and light transmission properties. Therefore, PVB films with high strength and moisture resistance can be widely used in automobiles, buildings, various bulletproof glasses, aerospace vehicles, military instruments, solar cells, composite shock-absorbing steel plates for industry, etc., and the mark...

Examples

Embodiment 1

[0037] A waterproof grade PVB film, in parts by weight, comprising the following raw materials:

[0038] 65 parts of PVB resin powder, 28 parts of 3GO plasticizer, 0.01 part of antioxidant, 0.01 part of ultraviolet absorber UV-326, 0.01 part of silane coupling agent, 0.001 part of adhesion modifier, 8 parts of SGP;

[0039] Wherein, the hydroxyl content of the resin powder used is 20%, the viscosity of the resin powder is 200cp (20°C), and the melt index is 1.2g / 10min;

[0040] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168; the mass ratio of antioxidant 1010 and antioxidant 168 is 1:1;

[0041] The cohesion regulator is a mixture of magnesium acetate and potassium formate, and the mass ratio of the two is 4:3;

[0042] Described silane coupling agent is the mixture of γ-glycidyl ether oxypropyltriethoxysilane, β-(3,4, epoxycyclohexyl)-ethyltrimethoxysilane, and the consumption ratio of the two is 1:3;

[0043] The preparation method of described water...

Embodiment 2

[0047] A waterproof grade PVB film, in parts by weight, comprising the following raw materials:

[0048] 72 parts of PVB resin powder, 35 parts of 3GO plasticizer, 0.03 part of antioxidant, 0.02 part of ultraviolet absorber UV-326, 0.001 part of silane coupling agent, 0.01 part of adhesion regulator, 0.8 part of SGP;

[0049] Wherein, the hydroxyl content of the resin powder used is 17%, the viscosity of the resin powder is 300cp (20°C), and the melt index is 0.8g / 10min.

[0050] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168; the mass ratio of antioxidant 1010 to antioxidant 168 is 1:4.

[0051] The cohesion modifier is a mixture of magnesium acetate and potassium formate, and the mass ratio of the two is 1:1;

[0052] Described silane coupling agent is the mixture of γ-glycidyl ether oxypropyltriethoxysilane, β-(3,4, epoxycyclohexyl)-ethyltrimethoxysilane, and the consumption ratio of the two is 1:1;

[0053] The preparation method of described water...

Embodiment 3

[0057] A waterproof grade PVB film, in parts by weight, the waterproof grade PVB film comprises the following raw materials: 65 parts of PVB resin powder, 28 parts of 3GO plasticizer, 0.01 part of antioxidant, 0.01 part of ultraviolet absorber UV-326 0.01 part of silane coupling agent, 0.001 part of cohesion regulator, 8 parts of SGP, 2 parts of cresyl butyl phthalate, and 8 parts of triphenyl phosphate.

[0058] Wherein, the hydroxyl content of the resin powder used is 20%, the viscosity of the resin powder is 200cp (20°C), and the melt index is 1.2g / 10min;

[0059] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168; the mass ratio of antioxidant 1010 and antioxidant 168 is 1:1;

[0060] The cohesion regulator is a mixture of magnesium acetate and potassium formate, and the mass ratio of the two is 4:3;

[0061] Described silane coupling agent is the mixture of γ-glycidyl ether oxypropyltriethoxysilane, β-(3,4, epoxycyclohexyl)-ethyltrimethoxysilane, and th...

technical field

[0001] The invention belongs to the technical field of laminated glass, and in particular relates to a waterproof grade PVB film and a preparation method thereof. Background technique

[0002] In recent years, with the rapid development of construction and automobile industries, PVB film is also called PVB film or PVB interlayer. It is the best material for making laminated safety glass in the world today. PVB film is made of PVB resin, which is non-toxic, odorless, non-corrosive, non-flammable, and has good light transmission, insulation, weather resistance, wear resistance, water resistance, oil resistance, and aging resistance. Plexiglass has special adhesion and light transmission properties. Therefore, PVB films with high strength and moisture resistance can be widely used in automobiles, buildings, various bulletproof glasses, aerospace vehicles, military instruments, solar cells, composite shock-absorbing steel plates for industry, etc., and the mark...

Examples

Embodiment 1

[0037] A waterproof grade PVB film, in parts by weight, comprising the following raw materials:

[0038] 65 parts of PVB resin powder, 28 parts of 3GO plasticizer, 0.01 part of antioxidant, 0.01 part of ultraviolet absorber UV-326, 0.01 part of silane coupling agent, 0.001 part of adhesion modifier, 8 parts of SGP;

[0039] Wherein, the hydroxyl content of the resin powder used is 20%, the viscosity of the resin powder is 200cp (20°C), and the melt index is 1.2g / 10min;

[0040] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168; the mass ratio of antioxidant 1010 and antioxidant 168 is 1:1;

[0041] The cohesion regulator is a mixture of magnesium acetate and potassium formate, and the mass ratio of the two is 4:3;

[0042] Described silane coupling agent is the mixture of γ-glycidyl ether oxypropyltriethoxysilane, β-(3,4, epoxycyclohexyl)-ethyltrimethoxysilane, and the consumption ratio of the two is 1:3;

[0043] The preparation method of described water...

Embodiment 2

[0047] A waterproof grade PVB film, in parts by weight, comprising the following raw materials:

[0048] 72 parts of PVB resin powder, 35 parts of 3GO plasticizer, 0.03 part of antioxidant, 0.02 part of ultraviolet absorber UV-326, 0.001 part of silane coupling agent, 0.01 part of adhesion regulator, 0.8 part of SGP;

[0049] Wherein, the hydroxyl content of the resin powder used is 17%, the viscosity of the resin powder is 300cp (20°C), and the melt index is 0.8g / 10min.

[0050] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168; the mass ratio of antioxidant 1010 to antioxidant 168 is 1:4.

[0051] The cohesion modifier is a mixture of magnesium acetate and potassium formate, and the mass ratio of the two is 1:1;

[0052] Described silane coupling agent is the mixture of γ-glycidyl ether oxypropyltriethoxysilane, β-(3,4, epoxycyclohexyl)-ethyltrimethoxysilane, and the consumption ratio of the two is 1:1;

[0053] The preparation method of described water...

Embodiment 3

[0057] A waterproof grade PVB film, in parts by weight, the waterproof grade PVB film comprises the following raw materials: 65 parts of PVB resin powder, 28 parts of 3GO plasticizer, 0.01 part of antioxidant, 0.01 part of ultraviolet absorber UV-326 0.01 part of silane coupling agent, 0.001 part of cohesion regulator, 8 parts of SGP, 2 parts of cresyl butyl phthalate, and 8 parts of triphenyl phosphate.

[0058] Wherein, the hydroxyl content of the resin powder used is 20%, the viscosity of the resin powder is 200cp (20°C), and the melt index is 1.2g / 10min;

[0059] The antioxidant is a mixture of antioxidant 1010 and antioxidant 168; the mass ratio of antioxidant 1010 and antioxidant 168 is 1:1;

[0060] The cohesion regulator is a mixture of magnesium acetate and potassium formate, and the mass ratio of the two is 4:3;

[0061] Described silane coupling agent is the mixture of γ-glycidyl ether oxypropyltriethoxysilane, β-(3,4, epoxycyclohexyl)-ethyltrimethoxysilane, and th...

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