Underground water remediation method for pesticide contaminated site

A technology for groundwater remediation and pesticide pollution, which is applied in the field of water treatment, can solve the problems of low removal efficiency, long cycle, and inability to fully decompose organic pollutants, and achieves reduced investment and operating costs, simple operation, and high treatment efficiency. good effect

Inactive Publication Date: 2020-06-19
中建生态环境集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there are mainly two remediation technologies for contaminated groundwater: in-situ remediation and ex-situ remediation. Among them, in-situ remediation mainly uses an adsorption medium with a high permeability coefficient to treat organic pollutants in groundwater by chemical or physical means. Known treatment media such as zeolite, activated carbon, and composite fillers have low treatment effects, and cannot fully decompose organic pollutants, especially refractory organic pollutants, and the removal efficiency is low, and in-situ repair also faces low repair efficiency and long cycle , prone to the risk of secondary pollution; ectopic remediation technology is also called extraction treatment technology, in the process of treatment, the polluted groundwater is pumped out from the aquifer, and then treated and purified on the ground, so that the pollutants dissolved in the water can be recovered Removal, this technology has a wide range of applications, a short treatment cycle, and a flexible and convenient treatment process, but specific treatment processes are required for different pollutants
[0004] The research on the remediation technology of contaminated sites in my country started relatively late, especially for the remediation of groundwater in pesticide-contaminated sites. It is still in its infancy, the technology is in the research and development stage, and the engineering cases are also in the initial demonstration stage.

Method used

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  • Underground water remediation method for pesticide contaminated site

Examples

Experimental program
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Effect test

Embodiment 1

[0050] Homogenize the groundwater in the pesticide-contaminated site for 12 hours; coagulate polyacrylamide and magnetic seeds for 45 minutes; then discharge it into a supermagnetic separator to separate the magnetic seeds and coagulation sediments, and the speed of the supermagnetic separator is 0.1r / min; adjust the pH of the water treated by the ultra-magnetic separator to 3, then pump it into the micro-electrolysis reaction tower, and add iron filings and carbon particles for micro-electrolysis treatment for 50 minutes; adjust the pH of the water after the micro-electrolysis treatment to 5, and then pump into the heterogeneous reaction tower, and add Al-Mn catalyst and Fenton's reagent to carry out the heterogeneous catalytic oxidation reaction for 1 h; pump the effluent into the degassing tower, and remove the gas generated in the reaction through air aeration, and the aeration time is 2.5h; adjust the pH of the effluent from the degassing tower to 10.5, and then drain it ...

Embodiment 2

[0052] Homogenize the groundwater in the pesticide-contaminated site for 15 hours; coagulate polyacrylamide and magnetic seeds for 60 minutes; then discharge it into a supermagnetic separator to separate the magnetic seeds and coagulation sediments, and the speed of the supermagnetic separator is 1.0r / min; adjust the pH of the water treated by the ultra-magnetic separator to 4, then pump it into the micro-electrolysis reaction tower, and add iron filings and carbon particles for micro-electrolysis treatment for 110 minutes; adjust the pH of the water after the micro-electrolysis treatment to 6, and then pump into the heterogeneous reaction tower, and add aluminum manganese catalyst and Fenton reagent to carry out the heterogeneous catalytic oxidation reaction for 2 hours; pump the effluent into the degassing tower, and remove the gas generated in the reaction through air aeration, and the aeration time is 3h; adjust the pH of the effluent from the degassing tower to 11.5, and ...

Embodiment 3

[0054] Homogenize the groundwater in the pesticide-contaminated site for 14 hours; coagulate polyacrylamide and magnetic seeds for 50 minutes; then discharge it into a supermagnetic separator to separate the magnetic seeds and coagulation sediments, and the speed of the supermagnetic separator is 0.5r / min; adjust the pH of the water treated by the ultra-magnetic separator to 3.5, then pump it into the micro-electrolysis reaction tower, and add iron filings and carbon particles for micro-electrolysis treatment for 50 minutes; adjust the pH of the water treated by the micro-electrolysis to 5.5, and then pump into the heterogeneous reaction tower, and add aluminum manganese catalyst and Fenton's reagent to carry out the heterogeneous catalytic oxidation reaction for 1.5h; pump the effluent into the degassing tower, and remove the gas generated in the reaction through air aeration, and the aeration time 2.5h; adjust the pH of the effluent from the degassing tower to 11, and then d...

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Abstract

The invention relates to the technical field of water treatment, in particular to an underground water remediation method for a pesticide contaminated site, which comprises the following steps: homogenizing and regulating underground water of a pesticide contaminated site; carrying out magnetic coagulation treatment on the homogenized and regulated water body; adjusting the water body subjected tothe magnetic coagulation treatment to be acidic and carrying out micro-electrolysis treatment; adjusting the water body subjected to micro-electrolysis treatment to be acidic and carrying out heterogeneous catalytic oxidation treatment; adjusting the water body subjected to heterogeneous catalytic oxidation treatment to be alkaline, and sequentially carrying out flocculation and precipitation toobtain supernatant; pumping the supernatant into an activated carbon adsorption tank for adsorption treatment, and discharging the supernatant after the supernatant reaches the standard. The method has pertinence and specificity for underground water pollutants in a pesticide field, can efficiently degrade pesticides in underground water in a short time, is good in treatment effect, high in removal efficiency and free of secondary pollution to the environment, and is simple and easy to operate, and investment and operation costs are greatly reduced compared with a conventional treatment method.

Description

technical field [0001] The invention relates to the technical field of water treatment, in particular to a groundwater restoration method for pesticide-contaminated sites. Background technique [0002] With the acceleration of urbanization and the adjustment of industrial structure and industrial layout, factories and enterprises in the main urban area of ​​the city will be relocated, and the replaced industrial land will become commercial and residential land. However, many years of industrial activities have caused serious environmental pollution of the soil and groundwater in the factory area, especially the damage to the soil and groundwater caused by pesticide companies, which needs to be repaired urgently to ensure ecological security. Therefore, how to deal with relocation and pollution of abandoned sites; how to rationally develop and utilize its land value have become important environmental challenges faced by countries all over the world. [0003] At present, the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/12C02F103/06C02F101/30C02F101/20
CPCC02F9/00C02F2101/306C02F2103/06C02F1/488C02F1/467C02F1/46176C02F1/66C02F1/725C02F1/283C02F1/5236C02F1/722C02F2101/30C02F2101/20C02F2001/007
Inventor 马文明吴迪聂雪彪金涛刘晓静张云富岑刚杨航郭春辉管梓含王宗葳严明明陈永胜施鹏
Owner 中建生态环境集团有限公司
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