High-low-temperature-resistant emulsion explosive and preparation method thereof

An emulsion explosive, high and low temperature resistant technology, applied in the directions of explosives, non-explosive stabilizers, non-explosive/non-thermal components, etc., can solve the problems of poor stability, high weather temperature, reduced explosive performance, etc. The effect of good safety and high explosive power

Pending Publication Date: 2020-06-26
PANZHIHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, when the existing emulsion explosives are used, there are often problems such as poor stability, especially when the explosive performance varies with the weather and the temperature fluctuates, the explosives are subjected to high and low temperature changes, the detonation sensitivity and detonation performance are reduced, and even the detonator is lost. Sensitivity, loss of explosive performance; in winter, especially in alpine regions, the temperature is very low, the explosive is frozen, ammonium acid crystallizes, demulsifies, and the explosive cannot be used normally
The first reason is the crystallization of nitric acid. The crystallized nitric acid is interlaced according to the crystal, which hinders the relative movement between the explosive particles. At the same time, the nitric acid increases according to the particle size and pierces the oil film. Solidified together, at low temperature, not only loses fluidity and plasticity, but also greatly reduces power and sensitivity; third, explosives are produced in August and September, the weather temperature is high, and in October and November, the weather temperature is low, noon High temperature, repeated changes like this, the explosive will decrease for a limited period of time, or even lose its explosive performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0040] The preparation method of the high and low temperature resistant emulsified explosive of the present invention comprises the following steps:

[0041] (1) Put ammonium nitrate and sodium nitrate in water, dissolve at 100-115°C, then add ammonium perchlorate and ammonium chloride, mix well, then add ethylene glycol and mix well, and finally add surfactant and mix well And keep it warm for 5-20 minutes to obtain the water phase material;

[0042] (2) Melt the compound wax, fully refined paraffin wax, microcrystalline wax, base oil, ethylene glycol, S-80 emulsifier and succinimide emulsifier at 95-120°C and stir to mix evenly, then add stabilizer and mix and keep warm for 5-20min to obtain the oil phase material;

[0043] (3) Add the water-phase material to the oil-phase material, emulsify at 100-150°C for 10-15 minutes to obtain an emulsified matrix, and then add expanded graphite and chemical foaming agent for sensitization to obtain a high-low temperature resistant emu...

Embodiment 1

[0048] Step 1: Put 80 parts of ammonium nitrate and 4 parts of sodium nitrate in 11 parts of water, stir and dissolve at 110°C, then add 4 parts of sodium perchlorate and 1 part of ammonium chloride, stir for 5 minutes, then add ethylene glycol 1 part was stirred for 2 minutes, and finally 1 part of aqueous phase surfactant with a weight ratio of sodium dodecyl sulfonate and acetylene glycol TL65 of 1:1 was added, mixed evenly and kept for 10 min to obtain the aqueous phase material;

[0049] Step 2: Melt the following oil phase materials at 110°C: 10 parts of compound wax, 10 parts of fully refined paraffin wax, 20 parts of microcrystalline wax, 20 parts of base oil, 4 parts of ethylene glycol, 30 parts of S-80 emulsifier, 6 parts of imide emulsifier, stirred for 30 minutes and mixed evenly, then added 1 part of stabilizer (the stabilizer is composed of borax and zinc stearate in a weight ratio of 1:1), mixed to obtain an oil phase material and kept for 10 minutes;

[0050] S...

Embodiment 2

[0055] Step 1: Put 85 parts of ammonium nitrate and 3 parts of sodium nitrate in 9 parts of water, stir and dissolve at 100°C, then add 2 parts of sodium perchlorate and 1 part of ammonium chloride, stir for 5 minutes and then add ethylene glycol 1 part, stirred for 2 minutes, and finally added 1 part of aqueous surfactant with a weight ratio of sodium dodecyl sulfonate and acetylene glycol TL65 of 1:1, mixed well and kept for 5 minutes to obtain the aqueous phase material;

[0056] Step 2: Melt the following oil phase materials at 95°C: 10 parts of compound wax, 10 parts of fully refined paraffin wax, 20 parts of microcrystalline wax, 20 parts of base oil, 4 parts of ethylene glycol, 30 parts of S-80 emulsifier, 6 parts of imide emulsifier, stirred for 5 minutes to mix, then added 1 part of stabilizer (the stabilizer is composed of borax and zinc stearate in a weight ratio of 1:1), mixed to obtain an oil phase material and kept for 10 minutes;

[0057] Step 3: First, 6 parts ...

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Abstract

The invention relates to a high and low temperature resistant emulsion explosive and a preparation method thereof, and belongs to the technical field of emulsion explosives. The technical problem to be solved by the invention is to provide the high and low temperature resistant emulsion explosive. The explosive is prepared from the following components in parts by weight: 93-94 parts of a water-phase material, 6-7 parts of an oil-phase material, 0.8-1.2 parts of expanded graphite and 0.3-0.6 part of a foaming agent, wherein the water-phase material consists of the following components in partsby weight: 76-85 parts of ammonium nitrate, 2-5 parts of sodium nitrate, 1-4 parts of sodium perchlorate, 1-4 parts of ammonium chloride, 0.8-1.2 parts of ethylene glycol, 0.8-1.2 parts of a surfactant and 9-12 parts of water; and a specific stabilizer is added into the oil phase material. Explosive, the explosive is high in explosive power, good in stability, good in safety and resistant to highand low temperature, can be repeatedly used for 30 times at the temperature of-20 DEG C to 45 DEG C, can reach the explosive speed of 3200 m / s or above within the validity period and reach the standard of No. 2 rock emulsion explosives, and is particularly suitable for high-temperature production and storage in summer and explosion in low-temperature and repeated high and low-temperature storageand use environments in winter.

Description

technical field [0001] The invention relates to high and low temperature resistant emulsified explosives and a preparation method thereof, belonging to the technical field of emulsified explosives. Background technique [0002] Emulsion explosive is a new type of industrial explosive developed from the 1970s to the end of the 1980s. Due to its unique physical structure, this kind of explosive has excellent water resistance, more complete explosion reaction, safe manufacture, transportation and use, and good mine blasting effect. [0003] However, when the existing emulsion explosives are used, there are often problems such as poor stability, especially when the explosive performance varies with the weather and the temperature fluctuates, the explosives are subjected to high and low temperature changes, the detonation sensitivity and detonation performance are reduced, and even the detonator is lost. Sensitivity, loss of explosive performance; in winter, especially in alpine...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C06B31/28C06B23/00
CPCC06B23/00C06B23/003C06B23/004C06B23/006C06B23/009C06B31/28
Inventor 黄平
Owner PANZHIHUA UNIV
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