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Regular structure catalyst, preparation method and application thereof, and treatment method of incompletely regenerated flue gas

A technology with a regular structure and a regular structure carrier, applied in the direction of catalyst activation/preparation, gas treatment, chemical instruments and methods, etc., can solve the problem of low catalytic conversion activity, achieve high catalytic conversion activity, reduce NOx emissions, and simple preparation method Effect

Active Publication Date: 2020-06-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] In the regeneration process of the prior art, especially in the incomplete regeneration process, the catalytic conversion activity of reduced nitrogen compounds such as NH3 is relatively low Low defects, the present invention provides a structured catalyst for reducing NOx emissions in flue gas, its preparation method and application, and a treatment method for incompletely regenerated flue gas

Method used

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  • Regular structure catalyst, preparation method and application thereof, and treatment method of incompletely regenerated flue gas
  • Regular structure catalyst, preparation method and application thereof, and treatment method of incompletely regenerated flue gas
  • Regular structure catalyst, preparation method and application thereof, and treatment method of incompletely regenerated flue gas

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Experimental program
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Effect test

Embodiment 1

[0117] (1) 262g of pseudo-boehmite was added into 1.42kg of deionized water for beating and dispersion, then 23.8mL of hydrochloric acid was added for acidification for 15min to obtain the bauxite colloid, and ferric nitrate (calculated as Fe) 2 o 3 Count) 6g, cobalt nitrate (as Co 2 o 3 Count) 6g, KMnO 4 (as MnO) 10g, RuCl with a mass content of 12.5g / L in terms of metal elements 3 Add 9.6mL of the solution into 350mL of water and stir until it is fully dissolved, add bauxite colloid to it, and stir for 15min to obtain the first solution; add 10g of MgO to 30g of water, stir for 10min, then add it to the first solution, and stir for 20min to obtain the active Component coating slurries;

[0118] (2) The active component coating slurry obtained in step (1) is used to coat the cordierite honeycomb carrier (the carrier pore density is 400 holes / square inch, the opening rate of the cross section is 70%, and the shape of the hole is a square), after Dry (100°C, 4h), then tran...

Embodiment 2

[0123] (1) 253g of pseudo-boehmite was added into 1.37kg of deionized water for beating and dispersion, then 22.9mL of hydrochloric acid was added for acidification for 15min to obtain the bauxite colloid, and ferric nitrate (calculated as Fe) 2 o 3 Count) 10g, cobalt nitrate (as Co 2 o 3 Count) 6g, KMnO 4 (as MnO) 6g, RuCl with a mass content of 12.5g / L in terms of metal elements 3 Add 8.8mL of the solution into 350mL of water and stir until it is fully dissolved, add bauxite colloid to it, and stir for 15min to obtain the first solution; add 16g of MgO to 48g of water, stir for 10min, then add it to the first solution, and stir for 20min to obtain the active Component coating slurries;

[0124] (2) The active component coating slurry obtained in step (1) is used to coat the cordierite honeycomb carrier (the carrier pore density is 400 holes / square inch, the opening rate of the cross section is 70%, and the shape of the hole is a square), after Dry (100°C, 4h), then tran...

Embodiment 3

[0128] (1) 209g of pseudo-boehmite is added to 1.13kg of deionized water for beating and dispersion, and then 19.0mL of hydrochloric acid is added for acidification for 15min to obtain the bauxite colloid. 2 o 3 Count) 20g, cobalt nitrate (as Co 2 o 3 Count) 12g, KMnO 4 (as MnO) 10g, RuCl with a mass content of 12.5g / L in terms of metal elements 3 Add 10.4mL of the solution into 350mL of water and stir until it is fully dissolved, add bauxite colloid to it, and stir for 15min to obtain the first solution; add 24g of MgO to 72g of water, stir for 10min, then add it to the first solution, and stir for 20min to obtain the active Component coating slurries;

[0129] (2) The active component coating slurry obtained in step (1) is used to coat the cordierite honeycomb carrier (the carrier pore density is 400 holes / square inch, the opening rate of the cross section is 70%, and the shape of the hole is a square), after Dry (100°C, 4h), then transfer to a tube furnace, and feed CO...

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Abstract

The invention relates to the field of catalytic cracking, and discloses a regular structure catalyst for reducing NOx emission in flue gas, a preparation method and application of the regular structure catalyst, and a treatment method of incompletely regenerated flue gas. The catalyst comprises a regular structure carrier and an active component coating, wherein the active component coating contains an active metal component and a matrix, the active metal components comprise first, second, third and fourth metal elements, the first metal element comprises Fe and Co, the weight ratio of Fe to Co is 1:(0.05-20) based on oxide, the second metal element is selected from Group IA and / or IIA metal elements, the third metal element is selected from Group IB-VIIB non-noble metal elements, and thefourth metal element is selected from noble metal elements. The catalyst provided by the invention has high catalytic conversion activity on reduction-state nitrides, the preparation method is simple,and the catalyst is used in a catalytic cracking process and can effectively reduce NOx emission in catalytic cracking of incompletely regenerated flue gas.

Description

technical field [0001] The invention relates to the field of catalytic cracking, in particular to a catalyst with a regular structure for reducing NOx emissions in flue gas, a preparation method and application thereof, and a treatment method for incompletely regenerated flue gas. Background technique [0002] The continuous rise of crude oil prices has greatly increased the processing costs of refineries. On the one hand, refineries can reduce costs by purchasing low-priced low-quality oil; on the other hand, they can increase economic benefits through deep processing of heavy oil. As an important means of heavy oil processing in refineries, catalytic cracking plays a pivotal role in refineries. It is not only the main means of heavy oil balance and clean fuel production in refineries, but also the focus of energy saving and efficiency enhancement in refineries. Catalyst cracking is a fast catalytic reaction system in which the catalyst is deactivated quickly. Solving the p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/22B01D53/86B01D53/56
CPCB01J27/22B01J23/002B01D53/8628B01D2258/0283B01J2523/00B01J2523/22B01J2523/31B01J2523/842B01J2523/845B01J2523/23B01J23/75B01J23/745B01J23/78B01J23/8913B01J37/0215B01J23/8986B01D2251/2062B01D2255/1026B01D2255/20738B01D2255/20746B01D2255/2073B01D2255/2092B01D2255/2045B01D2255/2047B01D2255/2065B01J2235/15B01J35/57B01J35/70B01J23/89B01J35/30B01J35/56B01D2257/404B01J6/001
Inventor 宋海涛姜秋桥田辉平林伟严加松孙言王鹏张久顺达志坚
Owner CHINA PETROLEUM & CHEM CORP