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Treatment method of high-salt degradation-resistant wastewater

A treatment method and a refractory technology, which is applied in the field of high-salt refractory wastewater treatment, can solve the problems of large-scale treatment, and achieve the effects of promoting the formation of aggregate structure, improving physical and chemical properties, and improving salt tolerance

Pending Publication Date: 2020-06-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this method needs to build multiple separate structures to cooperate, and the processing scale is relatively large

Method used

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  • Treatment method of high-salt degradation-resistant wastewater

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The high-salt refractory wastewater produced by a chemical plant has a salt content of 2.5wt%, a COD of 2000mg / L, a total nitrogen of 300mg / L, a B / C ratio of 0.16, a treatment temperature of 25-30°C, and a pH of 7.0 -7.5, the dissolved oxygen concentration is 2.0-3.0mg / L. During the long-term operation of the system, the removal rate of COD and total nitrogen became significantly worse, and the effluent could not meet the standard.

[0021] Using the treatment method of the present invention, 0.8% of the waste water treatment volume is added to the system every day according to 0.8% of the wastewater treatment volume 1#-8# bacterial agent in Example 1 of CN201510737425.5, and propylene glycol is added at the same time, and the dosage is 0.8 mg / L. After running for 10 days, the treatment effect is shown in Table 1.

[0022] Table 1

[0023]

Embodiment 2

[0025] The high-salt refractory wastewater produced by a chemical plant has a salt content of 5.0wt%, a COD of 1000mg / L, a total nitrogen of 300mg / L, and a B / C ratio of 0.12. The treatment temperature is 25-30°C, the pH is 7.0-7.5, and the dissolved oxygen is 2-3mg / L. During the long-term operation of the system, the removal rate of COD and total nitrogen became significantly worse, and the effluent could not meet the standard.

[0026] Using the treatment method of the present invention, 5% of the wastewater treatment volume is added to the system every day according to the 8# bacterial agent in CN201510737425.5 Example 1, and propylene glycol is added at the same time, and the dosage is 1.0mg / L. After 10 days of operation, it was tested that the effluent COD was lower than 60mg / L, and the total nitrogen was lower than 30mg / L.

Embodiment 3

[0028] The high-salt refractory wastewater produced by a chemical plant has a salt content of 1.5wt%, a COD of 5000mg / L, a total nitrogen of 500mg / L, and a B / C ratio of 0.19. The treatment temperature is 25-30°C, the pH is 7.0-7.5, and the dissolved oxygen is 2-3mg / L. During the long-term operation of the system, the removal rate of COD and total nitrogen became significantly worse, and the effluent could not meet the standard.

[0029] Using the treatment method of the present invention, 0.5% of the waste water treatment volume is added to the system every day according to 0.5% of the wastewater treatment volume 1# bacterial agent in Example 1 of CN201510737425.5, and propylene glycol is added at the same time, and the dosage is 0.5mg / L. After 10 days of operation, it was tested that the effluent COD was lower than 60mg / L, and the total nitrogen was lower than 30mg / L.

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Abstract

The invention relates to a treatment method of high-salt degradation-resistant wastewater. The method comprises the following steps: in a biochemical treatment unit for treating high-salt degradation-resistant wastewater, adding a salt-tolerant COD removal denitrification microbial agent, and simultaneously adding a salt-tolerant enhancer, wherein the salt-tolerant enhancer is at least one of propylene glycol, valine, methionine and the like. According to the method, the salt resistance of microorganisms in a high-salt degradation-resistant wastewater treatment system can be enhanced, the overall total nitrogen and COD removal rate of the process is increased, and a good treatment effect is achieved.

Description

technical field [0001] The invention belongs to the technical field of environmental protection wastewater treatment, and in particular relates to a treatment method for high-salt refractory wastewater. Background technique [0002] High-salt refractory wastewater has high salt content, complex water quality, and poor biodegradability, especially for refractory industrial wastewater. Due to its water quality characteristics and the degradation kinetics of organic matter, it is difficult to further increase the removal rate of organic matter even if the hydraulic retention time is prolonged. Biological treatment of high-salt and refractory organic wastewater has the advantages of low treatment cost, good effect, and no secondary pollution. However, the high salinity of high-salt water makes it easy for microorganisms to be dehydrated and inactivated; and the polymer in sewage has a large molecular weight, complex structure, stable properties, and is difficult to be decomposed...

Claims

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Application Information

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IPC IPC(8): C02F3/34
CPCC02F3/34C02F3/348C02F2305/06C02F2209/08C02F2209/16
Inventor 孙丹凤高会杰郭志华陈明翔王刚李宝忠
Owner CHINA PETROLEUM & CHEM CORP