Graphene modified ink and preparation method thereof

A graphene modification and graphene technology, applied in ink, household utensils, applications, etc., can solve the problems of phenol harm to human body, fragrance volatilization, loss of ink flavor, etc., and achieve good antibacterial performance

Inactive Publication Date: 2020-07-17
同曦集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the main components of ink on the market are smoke ink and perishable animal glue as the main raw materials, so it is necessary to add spices and phenol, but the spices and phenol themselves have obvious disadvantages: 1. The spice itself will volatilize after a long time, The fragrance will gradually fade until it disappears; 2. The spice itself has a certain toxicity, and there is a requirement for a blending ratio when used; 3. The cost of the spice is generally relatively high; 4. The toxicity of phenol will cause harm to the human body and the environment. Serious hazard, can cause pollution to water and air
However, on the one hand, the antibacterial functional ink has a large amount of antibacterial materials and high cost, and the writing performance of the ink prepared by this patent is not good; The dispersibility of the pigment smoke ink is affected, changing its original composition and losing the charm of the ink itself
[0004] CN 106967332 A discloses a cerium and gelatin modified antibacterial ink and its preparation method. The antibacterial ink uses gelatin instead of bone glue. Although the antibacterial effect of the ink is improved, the improvement is limited, and the price of cerium and gelatin is relatively high. Increase the preparation cost of ink, and cerium is a heavy metal, its addition will cause irritation to the skin
[0005] CN110982343A discloses an antibacterial and antimold ink and its preparation method and application. In terms of mass percentage, the raw materials of the antibacterial and antimold ink include: water-based acrylic resin 12-18%, smoke ink 18-28%, dispersant 3-5%, wetting agent 3-6%, stabilizer 12-18% and antibacterial and antifungal agent 0.01-0.04%, the balance is water, the invention adds a variety of organic or inorganic antibacterial and antifungal agents to achieve antibacterial effect , high economical and practical, good antibacterial and antifungal effects, but these antibacterial agents may have some impact on writing performance

Method used

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  • Graphene modified ink and preparation method thereof
  • Graphene modified ink and preparation method thereof
  • Graphene modified ink and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0058] This embodiment provides a kind of graphene modified ink, the preparation raw material of described graphene modified ink comprises the following components by mass percentage:

[0059]

[0060] The preparation method of graphene modified ink described in the present embodiment comprises the following steps:

[0061] (1) The above resin (acrylic resin and phenolic resin), pine smoke ink, dispersant (sodium lauryl sulfate and polyvinylpyrrolidone), wetting agent (glycerin), graphene oxide, bone glue and After mixing with water for 35 minutes, place it in a ball mill and grind for 40 minutes to obtain a mixed slurry;

[0062] (2) After mixing the mixed slurry obtained in step (1) with a stabilizer (calcium-zinc composite stabilizer) for 15 minutes, sieve with a 200-mesh sieve with an aperture to obtain the graphene-modified ink.

Embodiment 2

[0064] This embodiment provides a kind of graphene modified ink, the preparation raw material of described graphene modified ink comprises the following components by mass percentage:

[0065]

[0066] The preparation method of graphene modified ink described in the present embodiment comprises the following steps:

[0067] (1) The above-mentioned resin (acrylic resin and phenolic resin), lampblack ink, dispersant (polycarboxylate ammonium salt and alkylphenol polyoxyethylene ether), wetting agent (glycerin and polyethylene glycol), After graphene oxide, bone glue and water were mixed for 30 minutes, they were placed in a ball mill and ground for 60 minutes to obtain a mixed slurry;

[0068] (2) After mixing the mixed slurry obtained in step (1) with a stabilizer (calcium-zinc composite stabilizer) for 10 minutes, sieve it through a sieve with an aperture of 500 mesh to obtain the graphene-modified ink.

Embodiment 3

[0070] This embodiment provides a kind of graphene modified ink, the preparation raw material of described graphene modified ink comprises the following components by mass percentage:

[0071]

[0072] The preparation method of graphene modified ink described in the present embodiment comprises the following steps:

[0073] (1) The above-mentioned resin (acrylic resin and phenolic resin), pine smoke ink, dispersant (sodium dodecylbenzenesulfonate, polyoxyethylene sorbitan monooleate), wetting agent ( Glycerin and polyethylene glycol), graphene oxide, auxiliary materials (musk, hide glue) are mixed with water for 40 minutes, and placed in a ball mill to grind for 30 minutes to obtain a mixed slurry;

[0074] (2) After mixing the mixed slurry obtained in step (1) with a stabilizer (calcium-zinc composite stabilizer) for 20 minutes, sieve it through a 100-mesh sieve with an aperture to obtain the graphene-modified ink.

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Abstract

The invention provides graphene modified ink and a preparation method thereof. The graphene modified ink is composed of the following raw materials: resin, pine-soot ink or soot ink, a dispersing agent, a wetting agent, a stabilizer, graphene and water. The graphene modified ink has good antibacterial, mildew-proof and antiviral properties and good smooth writing hand feeling, and the wetting ductility and binding power of the ink are well balanced.

Description

technical field [0001] The invention belongs to the field of ink production for calligraphy and painting, and in particular relates to a graphene-modified ink and a preparation method thereof. Background technique [0002] At present, the main components of ink on the market are smoke ink and perishable animal glue as the main raw materials, so it is necessary to add spices and phenol, but the spices and phenol themselves have obvious disadvantages: 1. The spice itself will volatilize after a long time, The fragrance will gradually fade until it disappears; 2. The spice itself has a certain toxicity, and there is a requirement for a blending ratio when used; 3. The cost of the spice is generally relatively high; 4. The toxicity of phenol will cause harm to the human body and the environment. Serious hazard, can cause pollution to water and air. [0003] CN107266977 A discloses a kind of antibacterial functional ink and its preparation method and application. It is formed by...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/16
CPCC09D11/16
Inventor 陈广川于红光尹珊珊
Owner 同曦集团有限公司
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