Preparation method of polyalcohol anti-collapse inhibitor for environment-friendly drilling fluid salt slurry system
A technology of inhibitors and polyalcohols, which is applied in the direction of drilling compositions, chemical instruments and methods, etc., to achieve the effects of system stability, reduced investment, and reduced requirements for synthetic reactions
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Embodiment 1
[0027] Weigh ethylene oxide and ethylene glycol respectively according to the mass ratio of 1:2, the total of the two is 100g, stir it evenly at room temperature, slowly pour it into a stainless steel high-pressure reaction tank, and add 0.1% KOH aqueous solution as a catalyst , the amount of catalyst is 0.5g, nitrogen protection is continuously introduced, the reaction temperature is controlled at 120-125°C, the pressure is constant at 0.3Mpa, and stirring is continued. After 60 minutes of reaction, the safety pressure relief valve is opened to remove the residual pressure in the high-pressure reactor, and the synthetic The product was poured out, and the by-product and excess unreacted ethylene glycol were washed with distilled water. After removing the water, 50 g of triethylene glycol was added and mixed to obtain 130 g of polyalcohol anti-slump inhibitor 1#, with a synthesis rate of 80%.
[0028] Using the drilling fluid fluid loss meter GGS42-2A that conforms to the perfo...
Embodiment 2
[0030] Weigh propylene oxide and triethylene glycol respectively according to the mass ratio of 1:2. The total of the two is 100g. After stirring at room temperature, slowly pour it into a stainless steel high-pressure reaction tank, and add 0.1% mass fraction of chloroplatinic acid-KOH Catalyst, the amount of catalyst is 0.5g, nitrogen protection is continuously introduced, the reaction temperature is controlled at 100-115°C, the pressure is constant at 0.25Mpa, after uniform stirring for 1 hour, the safety relief valve is opened to remove the residual pressure in the high-pressure reactor, and the synthetic product Pour it out, wash by-products and excess unreacted triethylene glycol with distilled water, and obtain 70 g of polyalcohol anti-slump inhibitor 2# after water removal, with a synthesis rate of 70%.
[0031] Using the drilling fluid fluid loss meter GGS42-2A that conforms to the performance indicators in SY / T5380, the fluid loss of API freshwater slurry is 15ml, the...
Embodiment 3
[0033]Weigh ethylene oxide, propylene oxide and triethylene glycol respectively according to the mass ratio of 1:1:1. The total of the three is 100g. After stirring at room temperature, slowly pour it into a stainless steel high-pressure reaction tank, and add 0.1% Fractional chloroplatinic acid-NaOH catalyst, the amount of catalyst is 0.5g, nitrogen protection is continuously introduced, the reaction temperature is controlled at 115°C, the pressure is constant at 0.25Mpa, after uniform stirring for 1 hour, the safety pressure relief valve is opened to remove the residual gas in the high-pressure reactor. Press down, pour out the synthetic product, use distilled water and 0.1% concentration of hydrochloric acid solution and NaOH solution to wash by-products and excess unreacted triethylene glycol to neutral pH value, obtain 85g of polymeric alcohol anti-slump inhibitor 3 after removing water #, the synthesis rate is 85%.
[0034] Using the drilling fluid fluid loss meter GGS42...
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